• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.166-167
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• 2021

The purpose of this study is to evaluate the viscosity and flowability of polymer-cement composites for repairing cracks of RC structures. The viscosity and flowability of the polymer cement composites differed greatly depending on the type of polymer and the polymer cement ratio, and the polymer cement composites could be produced that could repair fine cracks in the RC structure without material separation by adjusting the proper water-cement ratio. In particular, the mixing of high viscosity EVA-modified polymer composites could be adjusted.

• Journal of the Korea Institute of Building Construction
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• v.4 no.3
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• pp.93-100
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• 2004

In recent years, it has widely been studied on the light-weight composites for the purpose of the large space and thermal insulation of building structures. The purpose of this study is to evaluate the properties of light-weight composites made by binders as cement, resin and polymer cement slurry. The concrete composites are prepared with various conditions such as polymer-cement ratio, void-filling ratio, type of resin, filler content and light-weight aggregate content, tested for thermal conductivity. From the test results, the thermal conductivity of concrete composites with the binder of cement tends to decrease with increasing polymer-cement ratio, and to increase with increasing void-filling ratio. The thermal conductivity of concrete composites with the binder of resin are markedly affected by the light-weight aggregate content, type of resin and filler content. The composites made by polymer-modified concrete and polymer cement slurry have a good thermal insulation property. From the this study, we can recommend the proper mix proportions for thermal insulation Panel or concrete. Expecially. the thermal conductivity of concrete composites made by polyurethane resin is almost the same as that of the conventional expanded polystyrene resin.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.6
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• pp.27-34
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• 2005

The purpose of this study is to improve the durability performance of polymer modified cement composites for repair of concrete under combined aging conditions. The experimental procedure was divided into three parts. First, the replacement level of mineral admixtures in polymer modified cement composites were determined in an experimental study based on a Box Behnken design. Second, the flow value, compressive strength and chloride permeability test of sixteen types of mixtures were conducted. Test results show that the polymer modified cement composites were effected on the improvement of the compressive strength and permeability performance. Third, the effects on the replacement level of silica fume mixture was evaluated by the compressive strength, chloride permeability, chemical resistance and repeated freezing and thawing cycles test. They demonstrated that the polymer modified cement composites using mixture of silica fume, fly ash, and blast furnace slag improved the durability performance.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.159-160
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• 2022

The purpose of this study is to evaluate the adhesion in flexure depending on the cement type, polymer type, polymer-cement ratio, and silica fume ratio of the polymer-cement composites(PCCs) for crack repair in RC structures to induce optimal mix proportions. The adhesion in flexure of PCCs for crack repair of RC structure has a significant effect on the polymer type and polymer-cement ratio, and the adhesion in flexure is generally improved with mixing of silica fume as a mixture. The adhesion in flexure according to the type of polymer is slightly higher in the order of SAE, EVA, and SBR, and it is relatively high at the polymer-cement ratio of 60% or 80%. In addition, the adhesion in flexure of PCCs with silica fume ratio of 10% or 20% to the cement weight is higher than that without silica fume. In order to improve the adhesion in flexure of PCCs for repairing cracks in RC structures, the optimal mix design is to properly adjust the cement type, polymer type, polymer-cement ratio, and silica fume ratio.

• Journal of the Korean Ceramic Society
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• v.36 no.5
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• pp.539-546
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• 1999

Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.161-162
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• 2022

The purpose of this study is to determine the viscosity of the polymer-cement composites(PCCs) for crack repair of RC structures and to investigate its compaction. According to the study on the viscosity and compaction property of PCCs for crack repair, the viscosity of PCCs varies greatly depending on the polymer type and polymer cement ratio, and by mixing silica fume into PCCs, appropriate viscosity and excellent flow can be controlled without separation of cement and water. As a result of this study, basic data on the viscosity, fluidity, and compaction properties of PCCs for crack repair of RC structure can be obtained.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.979-984
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• 1997

Test specimens of polymer-cement concrete composites were prepared using styrene-butadiene rubber(SBR) latex, ethylenevinyl acetate(EVA) and polyacrylic ester(PAE) emulsions as polymer dispersions in cement modified system at constant slump($10{\pm}0.5cm$), then compressive and flexural strengths water absorption, pore size distribution, and microstructures were investigated. Compressive and flexural strengths of these composites were remarkably improved with an increase of polymer-cement ratio. These composites had a desirable pore size distribution against frost damage due to a small capillary pore volume. Continuous polymer film was able to form in higher than 15% of polymer cement ratio.

• The Korean Journal of Ceramics
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• v.5 no.3
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• pp.278-283
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• 1999

Formaldehyde has widely been used for the cross-linking of polyvinyl alcohol polyvinyl alcohol polymer. The effects of formaldehyde on the water resistance of MDF cement composites were investigated as a function of types of catalyst, base or acid, and the amount of formaldehyde. The acetalization, reaction of OH group of PVA with aldehyde, was ended incompletely under base atmosphere. However, by addition of citric acid, the cross-linking of PVA polymer could be acheved through acetalization of PVA and formaldehyde. The effects of these different patterne according to the types of catalyst on the water resistance of MDF cement were studied by the preparation of PVA films and MDF composites. Thanks to the cross-linking reaction of PVA polymer chains by formaldehyde, the modified PVA films and MDF composites showed a good water-resistant propety. The modified MDF cement composite to which 3 wt% formaldehyde and 1 wt% cirtic acid were added showed 80% of initial flexural strength and good interfacial state between cement grain and polymer matrix. However, 4 wt% formaldehyde deteriorted the processing conditions, microstructures and eventually the flexural strength, causing sharp increase in the viscosity of sample dough during the mixing process. To study the relatins of flexural strength and interface of cement grain and polymer matrix, SEM and MIP measurement were performed.

• KCI Concrete Journal
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• v.11 no.3
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• pp.65-77
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• 1999

A portland cement was reinforced by incorporating carbon fiber(CF), silica powder, and impregnating the pores with styrene monomers which were polymerized in situ. The effects of type, length, and volume loading of CF, mixing conditions, curing time and, curing conditions on mechanical behavior as well as freeze-thaw resistance and longer term stability of the carbon-fiber reinforced cement composites (CFRC) were investigated. The composite Paste exhibited a decrease in flow values linearly as the CF volume loadings increased. Tensile, compressive, and flexural strengths all generally increased as the CF loadings in the composite increased. Compressive strength decreased at CF loadings above approx. 3% in CFRC having no impregnated polymers due to the increase in porosity caused by the fibers. However, the polymer impregnation of CFRC improved all the strength values as compared with CFRC having no Polymer impregnation. Tensile stress-strain curves showed that polymer impregnation decreased the fracture energy of CFRC. Polymer impregnation clearly showed improvements in freeze-thaw resistance and drying shrinkage when compared with CFRC having no impregnated polymers.

• Journal of the Korea Institute of Building Construction
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• v.22 no.1
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• pp.23-34
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• 2022

The purpose of this study is to evaluate the adhesion properties of polymer cement composites for crack repair of an RC structure. Polymer cement composites are manufactured from cement, three types of polymers and silica fume, and the mixture is designed by adjusting the water cement ratio and AE reducing agent so that the viscosity target of the polymer cement composites is 700mPa·s or less. According to the test results, the Type-A adhesion in tension of the polymer cement composite exceeded the adhesion standard of 1.0MPa of the polymer finishing material, and furthermore, depending on the type of polymer, the adhesion in tension was highest for SAE, followed in descending order by EVA, and SBR. In addition, the adhesion in tension of Type-B is up to 1/4.5 lower than that of Type-A, but the incorporation of silica fume shows a significant improvement in terms of adhesion in tension. Based on this study, the basic mixing design of the polymer cement composites required for viscosity and adhesive performance required for crack repair of the RC structure was completed. It could be proposed as an optimal mixing design under conditions for intermixing polymer type EVA, SAE, and P/C 80%-100%.