• Applied Chemistry for Engineering
• /
• v.25 no.2
• /
• pp.181-187
• /
• 2014

In order to use the spherical atomizing reduction steel slag (ladle furnace slag, LFS) instead of the fine aggregate of polymer concrete composites, various specimens were prepared with various replacement ratios of atomizing reduction steel slag and the addition ratios of polymer binder. Physical properties of these specimens were investigated through the absorption test, the compressive strength test, the flexural strength test, the hot water resistance test, the pore analysis and the micro-structure using scanning electron microscope. Results showed that the compressive strength and flexural strength of specimens with 7.5% of polymer binders increased with the increase of replacement ratios of atomizing reduction steel slag, but those of the specimens with 8.0% or more of polymer binders showed a maximum strength at a certain replacement ratio due to the material segregation causing the increase of fluidity. By hot water resistance tests, the compressive strength, flexural strength, average pore diameter, and bulk density decreased but the total pore volume and pore diameter increased. It was concluded that the amount of polymer binders could be reduced by maximum 23.8%, because the workability of the polymer concrete was remarkably improved by using the atomizing reduction steel slag instead of fine aggregate. However, since the use of atomizing reduction steel slag decreased the resistance of the polymer concrete to hot water, further studies are required.

• Applied Chemistry for Engineering
• /
• v.16 no.3
• /
• pp.317-322
• /
• 2005

Nowadays, recycling of aggregates from the waste concrete is in big demand due to the protection of environment and the shortage of aggregates that are needed for ever expanding construction projects. This study was undertaken to examine the feasibility of recycling waste concrete powder produced in the crushing process of demolished concrete as a filler material for polymer mortar. In this study, polymer mortar specimens were prepared by varying the mix proportion of polymer binder (ranging 9~15 wt%), waste concrete powder (ranging 0~20 wt%) substituted for silica powder, 0.1~0.3 mm fine aggregate (ranging 21~24 wt%) and 0.7~1.2 mm fine aggregate (ranging 44~47 wt%). For the prepared polymer mortar specimens, various physical properties such as strength, water absorption, heat water resistance, acid resistance, pore distribution and SEM observation were investigated in this work. As a result, physical properties of polymer mortar were observed to have remarkably improved with an increase of polymer binder, but greatly deteriorated with an increase of substitution quantity of waste concrete powder.

• Elastomers and Composites
• /
• v.33 no.4
• /
• pp.290-296
• /
• 1998

Recycling of waste tire has been limited and very simple, few applications have been observed. This study introduces a new elastic and permeable pavement made of scrap tire. Experimental results showed that key factors affecting the compressive strength were the size of scrap tire, size of aggregate, amounts and property of binder. Also, the water permeability depended on the size of aggregate and scrap tire. The compressive strength and water permeability of the samples were 1.4 and 116 times higher than those of the conventional porous cement concrete, respectively.

• Advances in concrete construction
• /
• v.15 no.6
• /
• pp.419-430
• /
• 2023

In this study, the effect of two types of aggregates (fly ash aggregate and shale aggregate) on the density, strength, and durability of preplaced lightweight aggregate concrete (PLWAC) was studied. The results showed that the 7 - 28 days strength of concrete prepared with fly ash aggregates (high water absorption rate) significantly increased, which could attribute to the long-term water release of fly ash aggregates by the refined pore structure. In contrast, the strength increase of concrete prepared with shale aggregates (low water absorption rate) is not apparent. Although PLWAC prepared with fly ash aggregates has a lower density and higher strength (56.8 MPa @ 1600 kg/m³), the chloride diffusion coefficient is relatively high, which could attribute to the diffusion paths established by connected porous aggregates and the negative over-curing effect. Compared to the control group, the partial replacement of fly ash aggregates (30%) with asphalt emulsion (20% solid content) coated aggregates can reduce the chloride diffusion coefficient of concrete by 53.6% while increasing the peak load obtained in a three-point bending test by 107.3%, fracture energy by 30.3% and characteristic length by 103.5%. The improvement in concrete performance could be attributed to the reduction in the water absorption rate of aggregates and increased energy absorption by polymer during crack propagation.

• International Journal of Concrete Structures and Materials
• /
• v.2 no.1
• /
• pp.35-39
• /
• 2008

This experimental study examines the applicability of polymer mortar permanent forms using a methyl methacrylate (MMA) solution of waste expanded polystyrene (EPS) to develop effective recycling processes for the EPS, referring to the flexural behavior of a polymer-impregnated mortar permanent form with almost the same performance as commercial products. An MMA solution of EPS is prepared by dissolving EPS in MMA, and unreinforced and steel fiber-reinforced polymer mortars are mixed using the EPS-MMA-based solution as a liquid resin or binder. Polymer mortar permanent forms (PMPFs) using the EPS-MMA-based polymer mortars without and with steel fiber and crimped wire cloth reinforcements and steel fiber-reinforced polymer-impregnated mortar permanent form (PIMPF) are prepared on trial, and tested for flexural behavior under four-point (third-point) loading. The EPS-MMAbased PMPFs are more ductile than the PIMPF, and have a high load-bearing capacity. Consequently, they can replace PIMPF in practical applications.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10a
• /
• pp.356-361
• /
• 1998

Permeable polymer cement concrete in this study is one of the invironment conscious concretes that can be applied at roads, side walks, parking lots, interlocking block and river embankment, etc. In this study, permeable polymer cement concretes using polymer dispersion(St/Ac) with water-cement ratios of 25, 30, 35 and 40%, polymer-cement ratios of 0, 5, 10, 15 and 20%, and a ratio of cement to aggregate (by weight), 1 : 3.5(about 415kg/㎥), 1 : 4.0(about 375 kg/㎥), and 1 : 4.5(about 345kg/㎥) are prepared, and tested for compressive, flexural and tensile strength, and permeability. From the test results, increase in the strengths of permeable polymer cement concrete are clearly observed with increasing polymer-cement ratio, we can obtain the maximum strengths at water-cement ratio of 35%. The optimum permeable polymer cement concrete according to application and location of work can be selected in various mix proportions.

• Bulletin of the Korean Chemical Society
• /
• v.10 no.2
• /
• pp.172-177
• /
• 1989

Stereoselective solvolyses of optically active activated esters in the aggregate system of optically active polymeric surfactants containing imidazole and benzene moieties were performed. The catalyst polymers employed were copolymers of N-methacryloyl-L-histidine methyl ester (MHis) with N,N-dimethyl-N-hexadecyl-N-[10-(p-methacryloylo xyphenoxycarbonyl)-decyl]ammonium bromide(DEMAB). In the solvolyses of N-carbobenzoxy-D- and L-phenylalanine p-nitrophenyl esters (D-NBP and L-NBP) by polymeric catalysts, copoly(MHis-DEMAB) exhibited not only increased catalytic activity but also enhanced enantioselectivity as the mole ${\%}$ of surfactant monomers in the copolymers increased. The polymeric catalysts showed noticeable enantioselective solvolyses toward D- and L-NBP of the substrates employed. As the reaction temperature was lowered for the solvolyses of D- and L-NBP with the catalyst polymer containing 3.5 mole ${\%}$ of MHis, the increased reaction rate and enhanced enantioselectivity were observed. The coaggregative systems of the polymer and monomeric surfactants were also investigated. In the case of coaggregate system consisted of 70 mole ${\%}$ of cetyldimethylethylammonium bromide with polymeric catalyst showed maximum enantioselective catalysis, viz., $k_{cat}(L)/k_{cat}(D)$ = 2.85. The catalyst polymers in the sonicated solvolytic solutions were confirmed to form large aggregate structure by electron microscopic observation.

• Journal of Environmental Science International
• /
• v.20 no.1
• /
• pp.71-79
• /
• 2011

In this study, a series of soil concrete mixtures were tested for the compressive strength according to ratio of aggregate to binder, compaction energy, maximum aggregate size, ratio of silica fume to cement, and ratio of water to binder. The optimum mixing ratio of soil concrete mixtures composed of volcaniclastic, cement, silica fume, concrete polymer and water were analysed. The test results for optimum proportion were as follows ; (1)ratio of aggregate to binder was 4 : 1, (2)compaction energy level was level 2, (3)maximum aggregate size was 13 mm, (4)ratio of silica fume to cement was 10%, (5)ratio of water to binder was 25%. Also, dry type construction techniques were applied using the optimum soil concrete mixture. From the results of this study, the compressive strength of soil concrete and construction techniques were suitable for making eco-friendly soil pavement.

• Bulletin of the Korean Chemical Society
• /
• v.22 no.3
• /
• pp.271-275
• /
• 2001

We investigated H-type molecular aggregation in a simply spin-coated amorphous homopolymer film of polymethacrylate containing push-pull azobenzene moieties. It was found that the aggregate formation was strongly influenced by thermal treatment an d that the aggregate created in the polymer film could be easily disrupted by irradiation of a linearly polarized light. In the first writing cycle of aggregated polymer film, photo-induced birefringence showed a steep increase to the highest value followed by a gradual decrease to the certain asymptotic value under longer irradiation of a linearly polarized light. This unique behavior could be attributed to the cooperative motion and the disruption of the aggregated molecules under continuous irradiation of light.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.04a
• /
• pp.339-342
• /
• 2000

Recently, the importance of the conutermeasures for waste materials has pointed out. Waste glass is also one to waste materials used for the recycling in construction sites. The crushed waste glass has been used to make a glass polymer composite that can be applied for sewer, storm drain pipe and interlocking block, etc. In this study, the crushed waste glass is explored with the possibility of recycling it, as a substitute for fine aggregates. The prepose of this investigation is to improve the strengths and acid resistance of the UP mortars using crushed waste glass. The UP mortars are prepare with blast furnace slag fly ash filler. the UP-fine aggregate ratios the crushed waste glass replacements for fine aggregate are tested strengths before and after immersion(H (아래첨자2)SO(아래첨자4) 10%), weight change and acid resistance are also tested. From the test results, the relative strength or UP mortars using fly ash as filler are found to be somewhat superior to that of the UP mortars using blast furnace as filler, And a UP mortar with fly ash as a filler, a UP-fine aggregate ratio of 15% and a waste glass replacement if 50% for fine aggregate is recommended as optimal mix proportion of UP mortar using crushed waste glass. Accordingly, it is enough to assure the use of the crushed waare glass as an aggregate for the production of UP mortar.