• Title/Summary/Keyword: polyester film

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The Evaluation of Water Vapor Transport and Waterproofness Properties of the Waterproof and Breathable Fabrics (국내 시판 의류용 투습방수소재의 투습방수 성능평가)

  • Shim, Huen Sup
    • The Korean Journal of Community Living Science
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    • v.27 no.2
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    • pp.295-304
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    • 2016
  • This study was conducted to evaluate and compare the waterproofness and water vapor transport properties of 30 waterproof and breathable textiles in the market. MVTR upright cup test with water, MVTR inverted cup test with potassium acetate, and sweating hot plate test method were used for measuring the breathability of fabric samples. The waterproofness of all fabric samples and evaporative resistance of garment ensembles made with 5 selected waterproof and breathable textiles out of 30 samples were tested. The results of this study were as follows. The base fabrics of the most samples were basic weave structure with either polyester or nylon fiber. The waterproofness was over $5000mmH_2O$ for all the samples except densely woven fabrics. The evaporative resistance of garments that were made out of 5 fabric samples with a range of low to high breathability ranged $39.9{\sim}56.7m^2{\cdot}P{\cdot}W^{-1}$. The data of the water vapor transport properties of fabric samples varied with different test methods. Overall the bicomponent film fabrics showed better breathability and less standard deviation regardless of test methods. It is expected the breathability data without the information of test conditions used for marketing would confuse the consumers and the apparel manufacturers.

Study of Single Stage PFC DCM Flyback Power Supply for a LED Lamp (LED 램프를 위한 불연속 모드를 갖는 단일단 PFC 플라이백 파워서플라이의 연구)

  • La, Jae-Du
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.65 no.4
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    • pp.285-291
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    • 2016
  • A light-emitting diode (LED) has been increasingly applied to various industrial fields and general lightings because of its high efficiency, low power consumption, environment-friendly characteristic and long lifetime. To drive the LED lighting, a power converter with the constant output current is needed. Among many power converters, the flyback converter is chosen by many converter designers due to high power density, structural simplicity, and miniaturization. In this converter, an electrolytic capacitor is generally chosen for the stabilization of the DC voltage because of having the large capacitance and the low price. However, the disadvantages are the short expected life time and 120Hz ripple currents on the converter output node. In this paper, a single-stage dimmable PFC DCM flyback converter without the electrolytic capacitor is proposed to prolong the lifetime of the LED driver. For the long lifetime of the converter, the polyester film capacitor with the small capacitance is substituted for the electrolytic capacitor on the output node and an LC resonant filter is added to damp 120Hz ripple current. The proposed converter is verified through the simulation and the experimental works.

Physical Properties and Flame Retardant Effects of Polyurethane Coatings Containing Pyrophosphoric Lactone Modified Polyesters (피로포스포릭 락톤 변성폴리에스테르를 함유한 폴리우레탄 난연도료의 물성 및 난연효과)

  • Jung, Choong-Ho;Choi, Yong-Ho;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.203-211
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    • 2000
  • Pyrophosphoric lactone modified polyester(PATT) that contains two phosphorous functional groups in one unit base resin structure was synthesized to prepare a non-toxic reactive flame retardant coatings. Then the PATT was cured at room temperature with isocyanate, Desmodur IL, to get a two-component polyurethane flame retardant coatings(PIPUC). Comparing the physical properties of the films of PIPUC with the film of non-flame retardant coatings, there was no degradation observed in physical properties by the introduction of a flame-retarding component into the resin. We found that the char lengths measured by $45^{\circ}$Meckel burner method were $3.1{\sim}4.4cm$ and LOI values recorded $27{\sim}30%$. These results indicate that the coatings prepared in this study is good flame retardant one. The surface structure of coatings investigated with SEM does not show any defects and phase separation.

Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephtahalate and its Sizing Efficiency (Part 1) - Manufacture of sizing agent with recycling PET - (재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제1보) - 재활용 PET를 이용한 내수제 제조 -)

  • Park, Jae-Seok;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.27-33
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    • 2008
  • Polyethylene terephtahalate has been used in several areas such as fiber, film, bottle, and disposable products. Production of PET has been rapidly increasing these days. Since PET is a semi-permanent material, it has a non-biodegradable character in itself. Wasted PET products can cause serious environmental problems. Many countries around the world impose environmental legal restrictions over their abandonments. Many researches on the enviromental influence factors and treatment techniques of the wasted PET have been carried out. The main objective of this study is to develop a new sizing agent using recycling PET and improve its internal sizing effect. Dried powder of PET was used to make the modified PET. After extracting water-dispersible PET by subcritical hydrolysis, polyester resins have been extracted and triphenyl phosphate(TPP) has been added to obtain optimal internal sizing agent. It was found that the optimum dosage of TPP was 2% (per PET weight) and the hydrolysis temperature was independent on making the modified PET.

Deformation Behavior and Nucleation Activity of a Thermotropic Liquid­Crystalline Polymer in Poly(butylene terephthalate)-Based Composites

  • Kim Jun Young;Kang Seong Wook;Kim Seong Hun;Kim Byoung Chul;Shim Kwang Bo;Lee Jung Gyu
    • Macromolecular Research
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    • v.13 no.1
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    • pp.19-29
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    • 2005
  • Polymer composites based on a thermotropic liquid-crystalline polymer (TLCP) and poly(butylene terephthalate) (PBT) were prepared using a melt blending process. Polymer composites consisting of bulk cheap polyester with a small quantity of expensive TLCP are of interest from a commercial perspective. The interactions between the PBT chains and the flexible poly(ethylene terephthalate) (PET) units in the TLCP phase resulted in an improvement in the compatibility of PBT/TLCP composites. TLCP droplets deformed and fragmented into smaller droplets in the PBT/TLCP composites, which resulted in TLCP fibrillation through the effective deformation of the TLCP droplets. The nucleation activities of the PBT/TLCP composites increased by adding even a small amount of the TLCP component.

Soil Microorganism Degrading Polycaprolactone (Polycaprolactone을 분해하는 토양미생물)

  • Kim Mal-Nam
    • Korean Journal of Environmental Biology
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    • v.22 no.3
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    • pp.400-404
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    • 2004
  • Polycaprolactone (PCL), a synthetic aliphatic polyester, was buried in activated sludge soil for 66 days at $27^\circ{C}$ and $37^\circ{C}$. The morphology of the surface of PCL film degraded by soil microorganisms was observed. Soil microorganisms degrading PCL were isolated and identified. Soil fungi and soil bacteria utilizing PCL as carbon or energy source were identified as Paecilomyces fumosoroseus KH27, Penicillium digitatum KH28, Fusarium solani KH29, Aspergillus sp. KH30 and Ochrobactrum anthropi KH31, respectively. Biodegradation test of PCL by the isolated strains showed that, P. digitatum KH28 exhibited the most PCL degrading activity at $27^\circ{C}$. However, at $37^\circ{C}$ O. anthropi KH31 showed higher degrading activity than the other soil microorganisms tested.

Toxicological Characterization of Phthalic Acid

  • Bang, Du-Yeon;Lee, In-Kyung;Lee, Byung-Mu
    • Toxicological Research
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    • v.27 no.4
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    • pp.191-203
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    • 2011
  • There has been growing concern about the toxicity of phthalate esters. Phthalate esters are being used widely for the production of perfume, nail varnish, hairsprays and other personal/cosmetic uses. Recently, exposure to phthalates has been assessed by analyzing urine for their metabolites. The parent phthalate is rapidly metabolized to its monoester (the active metabolite) and also glucuronidated, then excreted. The objective of this study is to evaluate the toxicity of phthalic acid (PA), which is the final common metabolic form of phthalic acid esters (PAEs). The individual PA isomers are extensively employed in the synthesis of synthetic agents, for example isophthalic acid (IPA), and terephthalic acid (TPA), which have very broad applications in the preparation of phthalate ester plasticizers and components of polyester fiber, film and fabricated items. There is a broad potential for exposure by industrial workers during the manufacturing process and by the general public (via vehicle exhausts, consumer products, etc). This review suggests that PA shows in vitro and in vivo toxicity (mutagenicity, developmental toxicity, reproductive toxicity, etc.). In addition, PA seems to be a useful biomarker for multiple exposure to PAEs in humans.

Comparison of Properties of Waterborne Polyurethanes Containing Various Polyols (다양한 폴리올을 갖는 수분산 폴리우레탄의 특성 비교)

  • Sur, Suk-Hun;Lee, Young-Hee;Park, Cha-Cheol;Kim, Han-Do
    • Clean Technology
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    • v.24 no.3
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    • pp.190-197
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    • 2018
  • Various waterborne polyurethanes (WPU) with three different types of polyol such as ester type polyol [adipic acid (A)/BD/3-methyl-1,5-pentandiol (MPD) and A/BD]//carbonate type polyol (C/HD/MPD, C/HD, C/BD)//ether type polyol (PTMG) were prepared in this study. This study focused on the effect of polyol type on the properties of WPU. Soft segment Tg (Tgs), 100% elastic modulus and tensile strength were highest when using carbonate polyol, followed by ester polyol and ether polyol, while those of elongation showed the opposite trend. The WPU synthesized with MPD - containing polyol showed lower Tgs, 100% elasticity and strength, and higher elongation than MPD - free WPU. The % transmittance and transparency of the WPU film containing the MPD component was superior to that of the WPU film containing no MPD component, and it was found that the film based on carbonate polyol was slightly better than the film based on ester polyol and ether polyol.

Studios on Processing and Keeping Quality of Retort Pouched Foods (4) Preparation and Keeping Quality of Retort Pouched Seasoned Baby Clam (레토르트파우치 식품의 가공 및 품질안정성에 관한 연구 (4) 레토르트파우치 조미바지락의 제조 및 저장중의 품질안정성)

  • LEE Eung-Ho;KIM Jeong-Gyun;CHA Yong-Jun;OH Kwang-Soo;KOO Jae-Geun;KWON Chil-Sung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.6
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    • pp.499-505
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    • 1984
  • For the purpose of obtaining basic data which can be applied to processing of retort pouched shell-fishes, retort pouched seasoned baby clam was prepared. After sand and mud were removed, and then steamed baby clams were shucked. Baby clam meats were seasoned with the mixed seasoning powder containing $3\%$ of sugar, $2.5\%$ of salt, $12\%$ of sorbitol, $0.5\%$ of monosodium glutamate and $10\%$ of smoke flavor, and then dried at $35-40^{\circ}C$ for 3 hours. After dried, the meats were vacuum packed in plastic film bag (polyester/nylon/unoriented polyproylene; $12{\mu}m/15{\mu}m/50{\mu}m,\;15{\times}17cm$), and sterilized for 12 minutes in a hot water circulating sterilzer at $120^{\circ}C$, The factors such as pH, VBN, moisture content water activity, color value (L, a, b), texture, TBA value and viable bacterial count of products were determined during storage at room temperture ($20{\pm}3^{\circ}C$). The results showed that the product could be preserved in a good condition for 120 days at $20{\pm}3^{\circ}C$. Judging from the scores of sensory evaluation on flavor, the product added smoke flavor as seasoning was the most desirable.

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Synthesis of Fluorine Modified Polyurethane and Surface Modification (불소 변성 폴리우레탄의 합성과 표면 개질)

  • Lim, Chul Hwan;Choi, Hee Sung;Noh, Si Tae
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.913-916
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    • 1999
  • Fluorine modified diisocyanate(FMD) was synthesized from tris(6-isocyanatohexyl)isocyanurate(TIHI) and N-ethyl-N-2-hydroxyethyl-perfluorooctanesulfonamide(HFA). Fluorine modified polyurethane(FMPU) was also synthesized from FMD and poly(tetramethylene) glycol(PTMG). Modified polyurethanes were made by blending FMPU into the polyester type base polyurethane(BPU). Surface and thermal properties of the blended BPU film was measured by contact angle measurement and DSC. As the amounts of FMPU was increased from 0 wt % to 1 wt %, the surface energy was dramatically decreased from 47.82 dyne/cm to 17.64 dyne/cm. But we observed little change of the contact angle with further increase in the amount of the FMPU up to 10 wt %. The data meant that the surface of the blended polyurethanes was hydrophobic due to the surface arrangement of the fluorine containing moiety in FMPU. Phase separation was induced by the incompatibility of FMPU and BPU for the samples having over 5 wt % of FMPU. The thermal analysis data of these samples showed the thermal behavior of the FMPU itself.

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