• Title/Summary/Keyword: polyester composites

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The Adhesion Promotion of Glass Fiber Reinforced Composite Using Methacrylate Functional Silanes (메타아크릴레이트 실란을 이용한 유리섬유 강화복합재료의 물성향상)

  • Jang, Jyong-Sik
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.133-139
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    • 1990
  • Methacrylate functional silanes with different methylene spacer groups have been synthesized and the orientation effect and absorption behavior of these silane coupling agent were investigated by Fourier transform infrared spectroscopy(FT-IR). The mechanical properties of glass bead/polyester composites are found to be dependent on the spacer group of treated silane coupling agent. The absorption rate of the silane coupling agent onto the fumed silica surface decreases with increasing the number of the methylene spacer in methacrylate functional silanes. Silane molecules containing long spacer groups are adsorbed onto silica slightly bowed with respect to the substrate surface. The relationship between silane molecular structure and mechanical properties of polymer composites is also investigated in order to improve hot/wet properties of glass fiber/polyester composites.

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Effect of Surface Modification of Polyester Cord on the Adhesion of SBR/Polyester (폴리에스터 코드의 표면개질 조건이 SBR/폴리에스터의 접착에 미치는 영향)

  • Park, Y.S.;Chung, K.H.
    • Elastomers and Composites
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    • v.42 no.2
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    • pp.75-85
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    • 2007
  • In this study, the new adhesion system was studied to improve the adhesion strength between polyester cord and rubber matrix. In order to enhance the adhesion strength through polyester cord's surface treatment, the NaOH solution was used. The NaOH solution concentrations of 0.03, 0.05, 0.1, 0.2, 0.5, 1 and 5 wt.% were used in surface modifying the polyester cord. The optimum condition showing the maximum adhesion strength of polyester cord with SBR compound containing bonding agent was at NaOH concentration of 0.05 wt.% with treatment time of 10 minutes. When the NaOH solution concentration was above 1 wt.%, the polyester cord due to the excess surface modification was damaged, and resulted in breakage during the adhesion test. Also, the adhesion strength between polyester and SBR could be improved by coating the polyester cord with triallylcyanurate(TC) adhesive. The drying condition of polyester cord coated with TC attributed to the adhesion strength. The maximum adhesion strength was obtained by using the polyester cord dried at $220^{\circ}C$ rather than dried at room temperature.

Photocatalyst Effect of Polyester Fabrics Treated with Visible-light Responsive Photocatalyst

  • Choi, Sei Young
    • Elastomers and Composites
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    • v.51 no.1
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    • pp.31-37
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    • 2016
  • In this study, we studied the photocatalytic functionality such as deodorant, antibacterial, antistatic of polyester fabrics treated with visible-light responsive photocatalyst. According to UV/visible spectrometry result, the UV-visible peak of visible-light responsive photocatalyst was found to be red shift at 420 nm sensitive in the visible light region. Also, the deodorizing and antimicrobial performance were shown to be retained more than 99% both before washing and even after 25 times washing. According to washing durability of polyester fabrics treated with visible-light responsive photocatalyst, the reduction effects for gas such as ammonia, trimethylamine, formaldehyde and toluene after 25 times washing appeared to be retained as much as before washing. At both before washing and after 25 times washing, antistatic property showed frictional voltage of approximately 250V.

Preparation of Unsaturated Polyester-based Hybrid Gel-Coats Containing Urethane Acrylate and Their Coating Performance

  • Kim, Ji-Hee;Baek, Seung-Suk;Kim, Oh Young;Park, Dong Hyup;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.247-251
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    • 2019
  • Two different urethane acrylates (mono-acrylate and di-acrylate) were used to prepare unsaturated polyester-based hybrid gel-coats. The physical properties and surface characteristics of these gel-coats were investigated on the basis of the content and type of urethane acrylate. The set-to-touch time increased and the physical properties (surface hardness and tensile strength) decreased with an increase in the urethane acrylate content. However, the type of urethane acrylate did not affect these parameters. It was found that the optimal urethane acrylate content for the application of unsaturated polyester-based hybrid gel-coats is ~10 wt%.

Preparation and Characterization of the Multi-functional Complex Utilizing PCB Powder (PCB Powder를 이용한 다기능 복합체의 제조 및 특성)

  • Park, Byoung Ki
    • Journal of the Korean Society of Safety
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    • v.30 no.1
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    • pp.34-39
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    • 2015
  • The feasibility of recycling wasted printed circuit board (PCB) is investigated by preparing PCB added flame retardant composites filled with either unsaturated polyester or polyurethane. In order to improve electroconductive properties, copper powder was added into the composites, which results also in improving their antistatic properties. The prepared composite samples showed a binding between the polymer fillers observed by a scanning microscope. The sample group using unsaturated polyester is elastomeric that led to appreciable elongation and elasticity. In case of polyurethane, the tensile strength increased proportionally as increase of the amount of PCB powder. The composite materials can be utilized as antistatic composite materials, since the surface resistivity result showed increase of the electroconductive properties by adding Cu. The flammability of the samples is not satisfactory according to UL-94 vertical test. However, the flame retardant properties were improved by adding PCB power. This study, therefore, showed that it is feasible to fabricate polymer composite materials and improve the material characteristics by adding PCB powder, which can replace existing additives used for the preparation of polymer composite materials and can reduce the environment contamination by recycling the wasted PCB.

Assessment of Geosynthetic Properties of Rubber Reinforced Composites (고무강화 복합재료의 지반용 특성 평가)

  • Jeon, H.Y.
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.247-252
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    • 1999
  • Rubber related geosynthetics(GS) as reinforcement and water barrier materials were manufactured by thermal bonding method and examined the their performance for applications to civil and environmental engineering fields. The spunbonded polyester nonwoven, fiber glass mat and fabric type geogrid of a high tenacity polyester filament were used as matrix and polyester film, elastomeric bitumen with SBS polymer and asphalt were used as reinforcements to manufacture the rubber related geosynthetics. A fiber glass mat and geogrid matrix GS showed more excellent mechanical properties and nonwoven and elastomeric bitumen matrix showed the more excellent permittivity. Softening points of rubber and asphalt mixture showed no difference and dimensional stability at high temperature, $120^{\circ}C$, represented no significant shrinkage. Resistance to ultraviolet of rubber related geosynthetics showed no visible alteration.

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Curing Behaviors and Mechanical Properties of Unsaturated Polyester Hosing with Different Glycol Molar Ratios (글리콜 몰비가 다른 UPE 수지의 경화거동과 물성에 관한 연구)

  • 이상효;이장우
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.599-609
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    • 2000
  • In order to improve the mechanical properties of unsaturated polyester (UPE) resins, the UPE resins with different glycol molar ratios were prepared. The effects of molar ratios of the UPE resins on the curing behaviors and mechanical properties were investigated. The microgel reaction mechanism was employed to characterize the system. It was found that the final conversion increased with increasing NPG molar ratios, and the conversion at the peak of differential scanning calorimetry (DSC) thermogram appeared to decrease with increasing NPG molar ratios. The flexural strength, tensile modulus, water resistance, and infiltration increased with increasing NPG content, but the tensile strength, tensile elongation, and flexural modulus decreased. Among the UPE resins prepared from the glycols with the molar ratios (PG/NPG) of 0.5/0.5, 0.25/0.75, those of laminated composites plates showed better mechanical properties.

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Effect of Spew fillet on Failure Strength Evaluation in Adhesive Bonded Joints involving Natural Fiber Reinforced Composites (접착제 접합된 자연섬유강화 복합재료의 파괴강도 특성에 미치는 접착제 필릿의 영향)

  • Kim, Yeon-Jik;Yun, Ho-Cheol;Im, Jae-Gyu
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.262-264
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    • 2005
  • This paper is concerned with a fracture strength study of composite adhesive lap joints. The tests were carried out on specimen joints manufactured hybrid stacked joints such as the polyester and bamboo natural fiber layer. The main objective of the work was to test the fracture strength using hybrid fiber composites with a polyester and bamboo natural fiber layer adjacent to the spew fillet of adhesive bonded joints and hybrid stacked joints. The results are presented using tensile-shear strength graph and finite element analysis. The failure mechanisms are discussed in order to explain that spew fillet at the end of the overlap reduces greatly the adhesive shear and effects the tensile-shear strength in hybrid stacked joints.

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