• 제목/요약/키워드: polycaprolactam

검색결과 3건 처리시간 0.015초

Formation of the Polycaprolactam between Layers of the [DEACOOH]-Montmorillonite Intercalations Complex and Its Characterization

  • Cho, Sung-Jun
    • 한국세라믹학회지
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    • 제43권4호
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    • pp.207-212
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    • 2006
  • [ ${\varepsilon}-caprolactam$ ] was polymerized in the layers of the [DEACOOH]-Montmorillonite intercalations complex at high temperatures ranging from 250% to 260% formed from Na-Montmorillonite and 10-Carboxy-n-decyldimethylethylammonium bromide to achieve [DEACOOH]-Polycaprolactam-Montmorillonite, in which an inorganic polymer (montmorillonite) is chemically combined with an organic polymer (polycaprolactam). The results of X-ray and IR analyses for the samples obtained after polymerization showed that the polymerization reaction was successfully accomplished. For the purpose of studying the polymeric reaction product more precisely, the polymerized product was separated from the silicate layers and analyzed with an X-ray diffractometer and an IR-spectrometer. A comparison of the results of the X-ray and IR analyses of the separated polymer and the polymer that was synthesized by the reaction of ${\varepsilon}-caprolactam$ solely with the organic cation without montmorillonite showed that the obtained both polymers are identical compounds.

A Kinetic Study of Thermal Degradations of Chitosan/Polycaprolactam Blends

  • Liao, Shen-Kun;Hung, Chi-Chih;Lim, Ming-Fung
    • Macromolecular Research
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    • 제12권5호
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    • pp.466-473
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    • 2004
  • We have used FT-IR spectra to explain the effects of hydrogen bonding between chitosan and polycaprolactam (PA6). A dynamic mechanical analysis study suggested that the optimum chitosan and PA6 miscibility under the conditions of this experiment were obtained at a blending ratio of 40:60. We studied the thermal degradation of chitosan blended with PA6 (chitosan/PA6) by thermogravimetric analysis and kinetic analysis (by the Ozawa method). Dry chitosan and PA6 exhibited a single stage of thermal degradation and chitosan/PA6 blends having> 20 wt% PA6 exhibited at least two stages of degradation. In chitosan/PA6 blends, chitosan underwent the first stage of thermal degradation; the second stage proceeded at a temperature lower than that of PA6, because the decomposition product of chitosan accelerated the degradation of PA6. The activation energies of the blends were between 130 and 165 kJ/mol, which are also lower than that of PA6.

키토산/카프로락탐 혼합체에 대한 수분의 영향 (Effect of Moisture on Molecular Motions of Chitosan/Polycaprotactam Blends)

  • 리아로센-쿤;훙치치;린망풍
    • 폴리머
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    • 제28권5호
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    • pp.433-443
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    • 2004
  • 키토산과 폴리카프로락탐 (PA6) 복합체의 박막을 개미산을 사용하여 만들었다. FT-IR 분광학적 자료는 키토산의 히드록시기와 PA6의 아마이드기 사이의 수소 결합이 형성되었음을 보여주었다. 열무게분석법은 혼합체 시료는 수분을 포함하고 있음을 나타내었다. 시료 속의 물의 분산은 저장 탄성률 (E')을 크게 감소한다고 DMA 결과는 보여주었다. 혼합체 시료의 기게적 손실 탄젠트 (tan $\delta$) 자료는 $\beta$d 손실 피크가 $0^{\circ}C$ 부근에서 나타남을 보여주었다. 혼합체 시료들은 진공에서 완전히 건조하였고 그 다음 소위 w-다리를 만드는 물을 흡수할 수 있도록 높은 습도 속에 두었다. 이 시료들의 E' 자료는 비정상적으로 증가하였고 $50^{\circ}C$ 부근에서 손실 피크의 어깨에 추가적인 손실 피크가 나타났다. 건조한 조건하에서는, 40/60 혼합 비율의 키토산/PA6가 두 성분의 섞임성이 더 좋았다.