• Title/Summary/Keyword: polyamide 6

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Thermal Properties of the Themoplastic Elastomers Based on EPDM Ionomer/Polyamide-6 Blends (EPDM 이오노머/Polyamide-6 블렌드계 열가소성 탄성체의 열적 성질)

  • Jin, Sung-Hoon;Song, Gwang Seok;Lee, Dai-Soo
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.167-172
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    • 2012
  • A new type of thermoplastic elastomer (TPE) based on EPDM ionomer as an elastomer and polyamide-6 as a reinforcing crystalline polymer was prepared and the thermal properties of TPEs were investigated. Especially effects of neutralization of maleated EPDM (MA-EPDM) to prepare EPDM ionomer with zinc oxide and the content of polyamide-6 on the thermal properties of the blends were investigated. Both the neutralization and blending were carried out employing a twin screw extruder. It was found that the neutralization of MA-EPDM results in the increase of cooling crystallization temperatures. Polyamide-6 plays the role of reinforcing filler in the blends due to the high crystallinity. Fine dispesion of polyamide-6 in the blends was confirmed and attributed to the imide formation between the maleic anhydride of MA-EPDM and amine group of polyamide-6. TPEs based on EPDM ionomer/Polyamide-6 blends showed balanced mechanical properties with improvement in heat resistance.

A Study on Polyamide-6 Sintering and Effect by $CO_2$ Laser ($CO_2$ Laser에 의한 Polyamide-6 소결과 그 영향에 관한 연구)

  • Bae S.W.;Kim D.S.;Ahn Y.J.;Kim H.I.;Choi K.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.197-198
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    • 2006
  • In the solid freeform fabrication (SFF) system using selective laser sintering (SLS), polyamide-12 powder is currently recognized as general material. In this study, some kinds of polyamide-6 powders with different shape and particlesize were fabricated to investigate the formability, the microstructure and mechanical properties. Also, to develop a more elaborate and rapid system, this study employs a new SLS device with a 3-axis dynamic focusing scanner system instead of the existing fe lens used in commercial SLS. Polyamide-6 powders having the average size of 100 m were treated thermally in order to keep the spherical symmetry in shape. These polyamide-6 powders were mixed with polyamide-12 powders having the average size of 50 m to give the bimodal distribution of size. These mixed powders showed the better fabrication in the selective laser sintering process because the smaller particles of polyamide-11 played an important role in the compact packing of powders by filling the void space between the large particles of polyamide-6. Also, Experiments have performed to evaluate the effect of a scanning path and sintering parameters by fabricating the various 3D objects.

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Sustained Drug Release of Polyamide Microcapsules (Polyamide Microcapsule의 성질과 서방성)

  • 김계용;김진홍
    • Journal of Biomedical Engineering Research
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    • v.8 no.2
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    • pp.135-144
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    • 1987
  • Polyamide microcapsules were designed for a sustained drug release. As a model, riboflavin was e no apsulated in polyamide microcapsules. Polyamide microcapsules were prepared from thiamines and acid bichlorides by the interfacial polycondensation reaction. The diamines used in ttlis works were ethylenediamine and 1, 6-hexamethylenediamine. Sebacoylchloride and teruphthaloylchloride were employed as acid bichlorides. The following parameters were studied; the release of several kinds of polyamide microcapsules , the various concentrations of diamines and acid dichlorides ; the various concentrations of surfactants : the various pH range of sink solution during the dissolution test. The release amount of riboflavin from aromatic polyamide micrcapsule was higher than that of aliphatic polyamide microcapsule The release rate of riboflavin from the polyamide microcapsule was decreased with increase of concentration of thiamines, arid dichlorides and surfactants which is used for preparing polyamide microcapsule. Release riboflavin from polyamide microcapsule was lower at pH 7 than pH 2 in sink-solution for dissolution test.

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Cure Reactions of Epoxy/Anhydride/(Polyamide Copolymer) Blends

  • Youngson Choe;Kim, Wonho
    • Macromolecular Research
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    • v.10 no.5
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    • pp.259-265
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    • 2002
  • The cure kinetics of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer, poly(dimmer acid-co-alkyl polyamine), were studied using differential scanning calorimetry (DSC) under isothermal condition. On increasing the amount of polyamide copolymer in the blends, the reaction rate was increased and the final cure conversion was decreased. Lower values of final cure conversions in the epoxy/(polyamide copolymer) blends indicate that polyamide hinders the cure reaction between the epoxy and the curing agent. The value of the reaction order, m, for the initial autocatalytic reaction was not affected by blending polyamide copolymer with epoxy resin, and the value was approximately 1.3, whereas the reaction order, n, for the general n-th order of reaction was increased by increasing the amount of polyamide copolymer in the blends, and the value increased from 1.6 to 4.0. A diffusion-controlled reaction was observed as the cure conversion increased and the rate equation was successfully analyzed by incorporating the diffusion control term for the epoxy/anhydride/(polyamide copolymer) blends. Complete miscibility was observed in the uncured blends of epoxy/(polyamide copolymer) up to 120 $^{\circ}C$, but phase separations occurred in the early stages of the curing process at higher temperatures than 120 "C. During the curing process, the cure reaction involving the functional group in polyamide copolymer was detected on a DSC thermogram.gram.

Laccase Treatment on Polyamide Fabrics (라카제를 이용한 폴리아미드 섬유의 효소 가공)

  • Seo, Hye-Young;Kim, Hye-Rim
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.10
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    • pp.1264-1270
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    • 2011
  • This study is to optimize the conditions for the treatment of polyamide fabrics using laccase. The pH, temperature, treatment time, and concentration were varied; their effects were evaluated by measuring the number of primary amide groups by the uptake of an acid dye measured by K/S of dyed polyamide fibers. The hydrophilicity of the fabrics was evaluated in terms of moisture regain and wettability. The effects of the mediator, ABTS, on the laccase activity were also evaluated. The optimal treatment conditions were identified as a pH of 4.5, temperature of $30^{\circ}C$, treatment time of 6 hours, and concentration of 10% of the weight of the fabric (o.w.f.). ABTS facilitated the activity of laccase on the polyamide fabrics. Voids and cracks on the surfaces of the laccase-treated polyamide fabrics were responsible for improved wettability. The results proved that laccase treatment improved the hydrophilicity of polyamide fibers without decreasing their strength.

Preparation of Mono-dispersed Polyamide 6(Nylon 6) Micro-particle (단분산린 Polyamide 6(Nylon 6) 미세입자의 제조)

  • Cho, Hangu-Gu;Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.322-328
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    • 2007
  • Mono-dispersed polyamide 6(Nylon 6) micro-particles sized in $4{\sim}5\;{\mu}m$ diameter were prepared by dispersion polymerization of ${\varepsilon}-caprolactam$ in liquid paraffin as a dispersion medium. Potassium metal(K) as a catalyst was separately added twice over the anionic ring-opening polymerization of ${\varepsilon}-caprolactam$. The size, shape, and size-distribution of prepared particles were varied with the concentration of anti-coagulant as well as the amount of initiator and catalyst. As the initiator concentration was in the range of $0.97{\sim}1.17\;wt%$ in monomer, about 90.6% of yield was accomplished. In addition, the highest yield of well-spherically shaped micro-particles was achieved by adding about $1.3{\sim}1.4\;wt%$ of catalyst.

Preparation and Characterization of Polyamide/MEPDM Alloy to Improve a Low Temperature Impact Strength and Antistatic Property (저온 충격강도 및 대전방지성 향상을 위한 개질 EPDM을 함유한 polyamide alloy의 제조 및 물성)

  • Lee, Soo;Jin, Seok-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.299-305
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    • 2011
  • Alloys of nylon(PA6) and ethylene-propylene-diene polymer, modified with maleic anhydride(MEPDM) were prepared using a melt kneading process. This study focuses on the effects of the content of MEPDM in PA6 blend on the mechanical and thermal properties of such blends where MEPDM is the dispersed phase. Mechanical properties were examined by stress-strain measurements and impact strength test. Both impact strength of PA6/MEPDM at room temperature and at $-20^{\circ}C$ were improved up to 400-550% with the amounts of MEPDM. However, PA6/MEPDM containing 3-5 wt% of MEPDM showed the about $700kg_f/m^2$ of the maximum tensile strength but 8.5 % of the lowest elongation. For certain compositions of PA6 with rubbery MEPDM, the interesting reduction of elongation is caused by the reaction of the polyamide amine end groups with maleic anhydride portion in MEPDM, that provided a reinforcement in the PA6 matrix. In addition, the introduction of antistatic agent on the surface of alloys causes significant reduction of their surface electrostatic resistance.

Microstructural Morphology of Molded Thin Composites of Thermotropic Liquid Crystalline Polymer and Polyamide 6 (서모트로픽 액정폴리머와 폴리아미드6으로 성형된 얇은 복합재료의 미세구조형태)

  • Choe, Nak-Sam;Choe, Gi-Yeong;Ha, Seong-Gyu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.7 s.178
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    • pp.1703-1711
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    • 2000
  • Microstructural morphology of molded composites of thermotropic liquid crystalline polymer(LCP) and polyamide 6 (PA6) has been studied as a function of epoxy fraction. Injection-moulding of a thin composite plaque at a temperature below the melting point of the LCP fibrils by suing the extruded LCP/PA6 pellets produced multi-layered structures: 1) the surface skin layer with thickness of 65-120 ym exhibiting a transverse orientation, 2) the sub-skin layer with an orientation perpendicular to the surface skin, i.e. in the flow direction, 3) the core layer with arc-curved flow patterns. Similar microstructural orientations were observed in the respective layers for the composite plaques with different fractions of epoxy.