• Title/Summary/Keyword: poly-crystallization

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Advanced P-Channel Poly-Si TFTs for SOG

  • Park, Seong-Jin;Kang, Sang-Hoon;Ku, Yu-Mi;Choi, Jong-Hyun;Jang, Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1019-1022
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    • 2004
  • High performance p-ch poly-Si TFTs with excellent stability were developed. By using a frequency doubled DPSS CW laser, the a-Si on glass could be crystallized into one dimensional single crystalline silicon named as a sequential lateral crystallization (SLC) region. We fabricated p-ch TFTs on SLC region and the typical characteristic values of the TFTs were $u_{fe}$ = 180 $cm^2$/Vs, $V_{th}$ = -3 V, S.S. = 0.5 V/dec, and $I_{off}$ = 1 pA/um@ $V_d$ = -10V. It is found that the TFTs are very stable after bias stresses such as negative and positive gate biases, hot carrier bias and high current bias. These results indicate that the poly-Si in SLC region is suitable for system on glass (SOG) application.

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Synthesis and Characterization of Poly(1,4-cyclohexanedimethylene/ethylene terephthalate) (Poly(1,4-cyclohexanedimethylene/ethylene terephthalate)의 합성 및 물성)

  • Cho, In-Ho;Rhee, Jong M.;Lee, Jong-Shin
    • Textile Coloration and Finishing
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    • v.3 no.3
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    • pp.23-28
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    • 1991
  • Poly(1, 4-cyclohexanedimethylene/ethylene terephthalate), PCET was prepared by condensing 1, 4-cyclohexanedimethanol(CHDM) and ethylene glycol with dimethylterephthalate(DMT), and some thermal properties of PCET were studied by DSC at a heating rate $20^{\circ}C$min. On increasing the CHDM content in PCET up to 20 mole%/DMT, the glass transition temperature(Tg) decreased a little and the crystallizability reduced sharply, and from 20 to 50 mole %/DMT the $T_g$ did not changed and the crystallization temperature was not detected. But on increasing the CHDM content above 70 mole %/DMT the TEX>$T_g$/ and the melting temperature increased.

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Electrical and Thermal Properties of Poly(p-phenylene sulfide) Reduced Graphite Oxide Nanocomposites

  • Chae, Byung-Jae;Kim, Do Hwan;Jeong, In-Soo;Hahn, Jae Ryang;Ku, Bon-Cheol
    • Carbon letters
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    • v.13 no.4
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    • pp.221-225
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    • 2012
  • Graphite oxide (GO) was produced using the modified Hummer's method. Poly(p-phenylene sulfide) (PPS)/reduced graphite oxide (RGO) composites were prepared by in situ polymerization method. The electrical conductivity of the PPS/RGO composites was no more than 82 S/m. It was found that as GO content increased in the PPS/RGO composites, the crystallization temperature and electrical conductivity of the composites increased and the percolation threshold value was at 5-8 wt% of GO content.

Investigation of Electro-optical Characteristics in a-TN-LCD on Poly(vinyl)cinnamate Surfaces (Poly(vinyl)cinnamate막을 이용한 a-TN-LCD의 시야각특성에 관한 연구)

  • Seo, Dae-Shik;Park, Ji-Ho;Lee, Chang-Hun;Lee, Bo-Ho
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1588-1590
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    • 1997
  • The viewing angle characteristics of amorphous(a)-twisted nematic(TN)-liquid crystal display (LCD) on poly(vinyl)cinnamate (PVC) surfaces with photo polymerrization were investigated. It was found that the threshold voltage increases with increasing the polymerization of PVC surfaces. That the domain size of a-TN-LCD is affected by the surface crystallization with increasing the photo polymerization of the photo-alignment film. We observed that the viewing angle of a-TN-LCD increased with increasing the photo polymerization on PVC surfaces. Finally, we consider that the viewing angle of a-TN-LCD on PVC surfaces is large compared to a-TN-LCD on polyimide(PI) surface.

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Direct deposition technique for poly-SiGe thin film achieving a mobility exceeding 20 $cm^2$/Vs with ~30 nm thick bottom-gate TFTs

  • Lim, Cheol-Hyun;Hoshino, Tatsuya;Hanna, Jun-Ichi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1028-1031
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    • 2009
  • High quality poly-SiGe thin films were prepared on 6-inch substrates using Reactive-thermal CVD with $Si_2H_6$ and $GeF_4$ around at $500^{\circ}C$ directly. Its thickness uniformity was ~ 3% on the entire substrate area. N-channel mobility of ~30 nm thick bottom-gate TFTs exceeded 20 $cm^2$/Vs without any further crystallization.

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The properties of CW laser crystallized poly-Si film (연속발진 레이저로 제작한 다결정 실리콘 박막의 특성연구)

  • Kim, Ki-Hyung;Kim, Eun-Hyun;Park, Seong-Jin;Ku, Yu-Mi;Kim, Chae-Ok;Jang, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.80-83
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    • 2005
  • $Nd:YVO_4$ 연속발진 레이저 (CW laser)를 이용하여 다결정실리콘 (CLC poly-Si)을 제작하였다. CLC 다결정 실리콘의 결정화 영역은 결정립 크기에 따라 SLC(Sequential Lateral Crystallization) 영역, SLG(Super Lateral Grain) 영역 및 Small Grain 영역으로 구분된다. 레이저를 중첩스캔 하여 제작한 CLC 다결정실리콘의 경우, 레이저 스캔 경계에서 단결정립이 형성됨을 SEM으로 확인하고, CLC 다결정실리콘의 결정성을 XRD와 라만 스펙트럼(Raman spectrum)을 이용하여 조사하였다.

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Miscibility and Mechanical Properties of Polycaprolactone-polyamide Block Copolymer/Poly(vinyl chloride) Blend (Polycaprolactone-폴리아미드 블록공중합체/Poly(vinyl chloride) 블렌드의 상용성과 기계적 성질)

  • 안소봉;이하용;정한모
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.128-132
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    • 2000
  • The miscibility between poly(vinyl chloride) (PVC) and polycaprolactone (PCL)-polyamide block copolymer whose content of PCL block is 62.7 wt%, was studied by differential scanning calorimetry. The PCL segment in the block copolymer and PVC has the miscibility showing single glass transition temperature (T$_{g}$). The miscible PVC molecule inhibited the crystallization of PCL segment, making an amorphous homogeneous phase of PCL and PVC segments at high PVC content. The blends had rubber elasticity at the temperature range between the T$_{g}$ of amorphous homogeneous phase of PCL and PVC segments and the melting temperature of polyamide segment, when both phases coexist.ist.

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Study of Post Excimer Laser Annealing effect on Silicide Mediated Polycrystalline Silicon. (실리사이드 매개 결정화된 다결정 실리콘 박막의 후속 엑시머 레이저 어닐링 효과에 대한 연구)

  • Choo, Byoung-Kwon;Park, Seoung-Jin;Kim, Kyung-Ho;Son, Yong-Duck;Oh, Jae-Hwan;Choi, Jong-Hyun;Jang, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.173-176
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    • 2004
  • In this study we investigated post ELA(Excimer Laser Annealing) effect on SMC (Silicide Mediated Crystalization) poly-Si (Polycrystalline Silicon) to improve the characteristics of poly-Si. Combining SMC and XeCl ELA were used to crystallize the a-Si (amorphous Silicon) at various ELA energy density for LTPS (Low Temperature Polycrystalline Silicon). We fabricated the conventional SMC poly-Si with no SPC (Solid Phase Crystallization) phase using UV heating method[1] and irradiated excimer laser on SMC poly-Si, so called SMC-ELA poly-Si. After using post ELA we can get better surface morphology than conventional ELA poly-Si and enhance characteristics of SMC poly-Si. We also observed the threshold energy density regime in SMC-ELA poly-Si like conventional ELA poly-Si.

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The Effect of Nucleating Agent for Improving Heat Resistance Properties of L-Lactide Polymer (L-Lactide 폴리머의 내열성 향상을 위한 핵제의 효과 연구)

  • Sim, Jae-Ho;Kim, Soo-Jong;Shim, Jae-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.11
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    • pp.5595-5600
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    • 2012
  • This paper is to review and study about the crystallization nucleating agent to improve the heat-resistance properties of poly(lactic acid). Four sub-micron sized nucleating agents, metallic salts of 2,2'-methylene bis(4,6-di-tert-butylphenol), were prepared and used as a crystallization nucleating agent. Thermal and mechanical properties of polymer compounds were investigated by DSC, HDT and UTM. As the results, While the heat-resistance properties of the polymer compound samples were increased linearly with the contents of nucleating agent as well as their smaller size. Among them, the highest heat-resistance property of compound was observed with 2 wt% of MPZ2. HDT values of PL98Z2 compound was $116^{\circ}C$ at 0.455Mpa.

Structure Development in Drawn Poly(trimethylene terephthalate) (연신에 의한 폴리(트리메틸렌 테레프탈레이트)의 구조 변형)

  • 전병환;김환기;강호종
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.477-483
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    • 2003
  • The structure development of drawn poly(trimethylene terephthalate) PTT as a function of draw down ratio and drawing temperature was studied. The special effort was made to find out the effect of structural development on thermal properties and crystallinity in drawn PTT. The changes in shrinkage ratio and mechanical properties were understood base on the level of crystallinity and orientation of the drawn PTT. The stress induced crystallization caused the increase in glass transition temperature and the decrease in cold crystallization temperature and enthalpy. The crystallinity and orientation were dependent upon the level of applied stress level as well as chain flexibility at high drawing temperature. The drawing resulted in the increase of shrinkage ratio but it was minimized by increasing of crystallinity. The development of orientation resulted in increasing modulus and tensile strength while decreasing elongation at break.