• Title/Summary/Keyword: poly(vinylalcohol) (PVA)

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Synthesis of PVA/PVP Hydrogel by Irradiation Crosslinking (방사선 가교에 의한 PVA/PVP 하이드로겔 제조 및 드레싱에의 응용)

  • 김태훈;노영창
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.270-278
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    • 2001
  • Hydrogels for wound dressing were manufactured using poly(vinylalcohol)(PVA) and poly(N-vinylpyrrolidone)(PVP). The hydrogels were obtained by exposing to $^{60}$ Co${\gamma}$-rays after freezing and thawing of aqueous solutions of PVA and PVP to improve mechanical strength. Mechanical properties such as gelation, water absorptivity and gel strength were examined after repeating the \"freezing and thawing\" of PVA/PVP hydrogels, and then irradiating them at 40 kGy. The PVA/PVP ratio was in the range of 30:70 ~ 100:0, and the solid concentration of PVA/PVP was 20 wt%. The gelation and strength of hydrogels were much higher when \"freezing and thawing\" and the irradiation process were used than when only the irradiation process was utilized. In addition, the mechanical properties of PVA/PVP hydrogels after repetition of \"freezing and thawing\" are discussed. thawing\" are discussed.ssed.

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고분자 물질을 사용한 토양 중 방사성 핵종의 고정화

  • 원휘준;김계남;김민길;오원진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.293-297
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    • 2003
  • A series of laboratory experiments was conducted to investigate the fixation characteristics of poly(vinylalcohol)-poly(methacrylic acid)(PVA-PMAA) mixed solution on the soluble (equation omitted)-radionuclides. Using the potentiometric titration technique, it was found out that the PVA and PMAA in a solution form intermacromolecular complex. The mobilized portion of each radionuclide by water from sand surface treated with a fixative was measured by ${\gamma}$-ray spectroscopy, The mobilized portion of minor radionuclides such as $^{241}$ Am, $^{154}$ Eu, $^{155}$ Eu and $^{144}$ Ce were higher than those of $^{134}$ Cs and $^{137}$ Cs. The capability of PVA-PMAA system was better among the candidate solutions for the fixation of total (equation omitted)-radioactivity, $^{134,137}$Cs which is composed of more than 85 % of total ${\gamma}$-radioactivity could be fixed effectively by the PVA-PMAA solution.

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Fixation of $\gamma$-Radionuclides by the PVA-PMAA System

  • Won, Hui-Jun;Ahn, Byung-Gil;Jung, Chong-Hun;Kim, Gye-Nam;Oh, Won-Zin
    • Nuclear Engineering and Technology
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    • v.32 no.3
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    • pp.205-213
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    • 2000
  • A series of laboratory experiments was conducted to investigate the fixation characteristics of poly(vinylalcohol)-poly(methacrylic acid)(PVA-PMAA) mixed solution on the soluble ${\gamma}$- radionuclides. Using the potentiometric titration technique, it was found out that the PVA and PMAA in a solution form intermacromolecular complex. The mobilized portion of each radionuclide by water from sand surface treated with a fixative was measured by ${\gamma}$-ray spectroscopy. The mobilized portion of minor radionuclides such as 241Am, 154Eu, 155Eu and 144Ce were higher than those of 134Cs and 137Cs. The capability of PVA-PMAA system was better among the candidate solutions for the fixation of total ${\gamma}$-radioactivity. 134,137Cs which is composed of more than 85 % of total ${\gamma}$-radioactivity could be fixed effectively by the PVA-PMAA solution.

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Sensing characteristics of polyaniline sensor coated with porous PVDF layers to methanol gas under various humidity conditions (다공성 PVDF막이 코팅된 Polyaniline 센서의 다양한 습도분위기의 메탄올 가스에 대한 감응특성)

  • Lim, Cheol-Beom;Sohn, Sung-Ok;Huh, Jeung-Soo
    • Journal of Sensor Science and Technology
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    • v.15 no.3
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    • pp.205-210
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    • 2006
  • Hydrophobic polymer [ex. Poly(vinylidenfluoride)] layer was coated on polyaniline (PANi) sensor to reduce the contamination humidity. The differences in sensitivity to methanol gas detection in various humidity condition between pure-PANi sensor and sensor coated with poly(vinylidenfluoride) polymer (PVDF) (coated-PANi sensor) were investigated. Considering the relation between the density of pore, which was coated on the layer of the PANi sensor, and sensitivity was investigated. To fabricate the porous PVDF layer on PANi sensor, poly(vinylalcohol) (PVA), which is water-soluble polymer, was used. Coated-PANi sensor was less affected by humidity compared with pure-PANi sensor. And higher density of pore on PVDF layer led to higher sensitivity.

Preparation of water-swollen-hydrogel membrane for gas separation. I. (기체 분리용 수팽윤성 분리막 제조. I.)

  • 박유인;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.43-44
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    • 1996
  • Water-swollen-hydrogel membranes for gas separation were prepared by dipcoating and thermal crosslinking of poly(vinylalcohol) (PVA) - poly(acrylacid) (PAA) blends on asymmetric porous polyetherimide(PEI) supporters. The polyetherimide supporters, prepared by phase inversion of polyetherimide solutions in N-methylpyrrolidone(NMP) (composition of PEI/NMP=25/75), had good heat and chemical resistane. The coating materials with different blending ratios of PVA/PAA(=90/10, 80/20, 70/30) were characterized with differential scanning calorimetry (DSC), infrared spectroscopy(IR) and the water swelling ratios. The permeabilities and the separation factors of carbon dioxide through these membranes were measured by a mass flow meter and gas chromatograph at different temperatures, respectively, under a vacuum mode of downstream.

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Organic Thin-Film Transistors with Polymer Buffer Layer (고분자 완충층을 이용한 유기박막트랜지스터)

  • Choi, Hak-Bum;Hyung, Gun-Woo;Park, Il-Houng;Hwang, Seon-Wook;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.182-183
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    • 2008
  • We fabricated a pentacene thin film transistor with Poly-vinylalcohol (PVA) as a dielectric. And we used Poly(9-vinylcarbazole) (PVK) as a buffer layer to improve the electrical characteristics. PVK is a material used often host material for OLED device, as it has good film forming properties, large HOMO-LUMO(highest occupied molecular orbital-lowest unoccupied molecular orbital) bandgap. The performance of a OTFT device with PVA gate dielectric was improved by using the PVK. Field effect mobility, threshold voltage, and on-off current ratio of device with PVK layer were about 0.6 $cm^2$/Vs, -17V, and $5\times10^5$, respectively.

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Preparation of Composite Membranes Via PVA/PAM Solution Coating onto Hydrophilized PVDF Hollow Fiber Membrane and Their Pervaporation Separation of Water-ethanol Mixture (PVDF 중공사막의 표면친수화 후 PVA/PAM 용액의 코팅을 통한 복합막제조와 이의 물-에탄올계의 투과증발 분리)

  • Kim, Ji Seon;Park, Chae Young;Park, Hun Whee;Seo, Chang Hee;Rhim, Ji Won
    • Membrane Journal
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    • v.23 no.4
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    • pp.312-318
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    • 2013
  • Poly vinylidene fluoride (PVDF) hollow fiber membranes were hydrophilized using polyethylenimine (PEI) and p-xylylene dichloride (XDC), and poly(vinyl alcohol) (PVA) and poly (acrylic acid -co- maleic acid) (PAM) mixed solutions by varying the concentration of PAM were coated onto PVDF membrane surface. The surface coating was verified by the observation of scanning electron microscope (SEM) and the permselective characteristcs of the resulting composite membranes were tested for 90 wt% aqueous ethanol solution by the pervaporation technique. The effects of the corsslinking agent concentraion, the temperature of feed solution, and the reaction temperature on the flux and separation factors were measured. Typically, the flux, $1,480g/m^2hr$ at the reaction temperature $100^{\circ}C$, PAM 3 wt%, feed temperature $70^{\circ}C$ was obtained, on the other hand, for the separation factor, ${\alpha}_{W/E}=82$ at the conditions of the reaction temperature $100^{\circ}C$, PAM 15 wt% and feed temperature $25^{\circ}C$ was shown.

Dissolution Profiles of Solid Dispersions Containing Poorly Water-Soluble Drugs and Solubilizing Compositions (가용화 조성물과 난용성 약물군을 함유하는 고체분산체의 용출양상)

  • Kim, Tae-Wan;Choi, Choon-Young;Cao, Qing-Ri;Kwon, Kyoung-Ae;Lee, Beom-Jin
    • Journal of Pharmaceutical Investigation
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    • v.32 no.3
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    • pp.191-197
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    • 2002
  • Polymer based physical mixtures or solid dispersions containing solubilizing compositions[OA, tween80 and SLS] were prepared using a spray-dryer. Lovastatin(LOS), simvastatin(SIMS), aceclofenac(AFC) and cisapride(CSP) were selected as poorly water-soluble drugs. Dextrin, poly(vinylalcohol) (PVA), poly(vinylpyrrolidone)(PVP) and polyethylene glycol(PEG) were chosen as solubilizing carriers for solid dispersions. The solid dispersions containing solubilizing compositions without drug were prepared without using organic solvents or tedious changes of formulation compositions. This system could be used to quickly screen the dissolution profiles of poorly water-soluble drugs by simply mixing with drugs thereafter. In case of solid dispersion containing drug, organic solvent systems could be used to solubilize model drugs. The dissolution rates of the drugs were higher when mixed with drug and solid dispersions containing solubilizing compositions. However, solid dispersions of LOS, AFC, and CSP simultaneously containing drug and solubilizing compositions in organic solvent systems were more useful than physical mixtures of drug and solid dispersions without drug except SIMS. Based on solubilizing capability of polymer based physical mixtures in gelatin hard capsules, optimal solid dispersion system of poorly water-soluble drugs could be formulated. However, it should be noted that dissolution rate of poorly water-soluble drugs were highly dependent on drug properties, solubilizing compositions and polymeric carriers.

Radiation Preparation and Characterization of Antimicrobial Hydrogels (방사선 이용 항균성 천연추출물 함유 하이드로겔 제조 및 특성 연구)

  • Gwon, Hui-Jeong;Park, Eun Ji;Choi, Jong-Bae;Lim, Jong-Young;Jeong, Jin-Oh;Shin, Young Min;Jeong, Sung In;Park, Jong-Seok;Lim, Youn-Mook
    • Journal of Radiation Industry
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    • v.7 no.1
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    • pp.87-91
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    • 2013
  • Taraxacum platycarpum (TP) has been used for years without restriction on usual dose for its non-toxic nature and nonexistence of the side effects. To develop antimicrobial hydrogel, poly (vinylalcohol) (PVA) hydrogels containing the aqueous extracted TP as an antimicrobial agent were prepared by using gamma-rays irradiation. The antimicrobial activities of the TP hydrogels were tested against Staphylococcus aureus and Staphylococcus epidermidis by disc diffusion method. The inhibition zones (IZ) of the TP extracts and TP hydrogels against S. aureus were 16 mm and 20 mm and against S. epidermidis was 10 mm and 13 mm, respectively. In conclusion, the TP hydrogel that has an excellent antimicrobial activity was proved to be a valuable material for functional skin care.