• Title/Summary/Keyword: poly(trimethylene terephthalate) (PTT)

Search Result 50, Processing Time 0.027 seconds

Preparation and Physical Properties of Stretch Fabrics Using with Poly(trimethylene terephthalate) Fiber (Poly(trimethylene terephthalate) 섬유를 이용한 신축성직물의 제조 및 물성)

  • Choi, Hee
    • Fashion & Textile Research Journal
    • /
    • v.5 no.1
    • /
    • pp.53-58
    • /
    • 2003
  • The stretch fabrics were made by the use of PTT[Poly(trimethylene terephthalate)] fibers and changes in their physical properties were analysed. Tenacity and elongation of D-1(PTT DTY) yarn were 3.32 g/d and 50.4%, respectively, while these of D-2(PTT+CDP DTY) yarn were 2.46 g/d and 32.1%, respectively. The tenacity of PTT-1 and PET-1 fabrics was similar, but the elongation of PTT-1 and PET-1 fabrics was 75% and 44%, respectively. Thus, the elongation of PTT-1 fabric was two times higher than those of PET-1 fabric. In addition, the elastic recovery at 20% elongation of PTT-1, PTT-2 and PET-1 fabric was 85.0%, 80.5% and 60.0%, respectively, indicating that so PTT-1 fabric showed better elastic recovery. The light, wash, and abrasion fastness of PTT-1 and PTT-2 fabrics were above Grade 3, Grade 4-5, and Grade 4-5, respectively. Therefore, there was little effect of substance on the fastness.

Sorption Equilibria of C. I. Disperse Yellow 54 Dye between Supercritical Carbon Dioxide and PTT and PET Textiles (초임계이산화탄소와 PTT및 PET섬유 사이에서 C. I. Disperse Yellow 54 염료의 수착평형)

  • Ihm, Bang-Hyun;Choi, Jun-Hyuck;Shim, Jae-Jin
    • Clean Technology
    • /
    • v.13 no.3
    • /
    • pp.173-179
    • /
    • 2007
  • In this study the amount of equilibrium sorption of C.I. Disperse Yellow 54 dye in the polymeric textiles such as PTT (poly(trimethylene terephthalate)) and PET (poly(ethylene terephthalate)) textiles was measured in the presence of supercritical carbon dioxide at different temperatures, pressures, and time. The amount of dye sorption increased with temperature and pressure in both PTT and PET textiles, but the increasing rate decreased with pressure. The PTT textile has much larger dye sorption than PET textile. The increasing rate of dye sorption decreased with time at same temperature and pressure for both PTT and PET textiles.

  • PDF

Synthesis and Characterization of Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate) Copolymers (Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate) 공중합체의 합성과 분석)

  • 김영호;최재원;서용환;이한섭
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2002.04a
    • /
    • pp.41-44
    • /
    • 2002
  • 블렌딩이나 공중합체의 합성은 한가지 또는 모든 구성성분 고분자의 단점을 보완하면서 효과적인 물성 발현을 위해 연구되어 왔다. 특히 방향족 폴리에스테르계 고분자들 사이에서는 PET/PEN, PEN/PHN, PBT/PBN, 또는 PET/PBT 등의 공중합체가 보고되고 있다[1-3]. 한편, poly(trimethylene terephthalate)(PTT)는 최근 섬유로 방사되어 카펫, 의류 등으로 응용된 이후 PTT를 주성분으로 하는 bicomponent 멜트블로운 부직포[4], 염색[5] 등의 연구가 활발히 이루어지고 있다. (중략)

  • PDF

Structure Development of Uniaxially Drawn Poly(trimethylene terephthalate)/ Poly(ethylene terephthalnte) Blends (일축 연신에 의한 폴리(트리메틸렌 데레프탈레이트)/ 폴리(에틸렌 데레프탈레이트) 블렌드의 구조 변화)

  • 전병환;김환기;강호종
    • Polymer(Korea)
    • /
    • v.28 no.1
    • /
    • pp.67-76
    • /
    • 2004
  • The effects of drawing temperature and draw down ratio on thermal properties, crystallinity and orientation of poly(trimethylene terephthalate)/poly(ethylene terephthalate) (PTT/PET) 100/0 ,90/10, and 80/20 blends have been investigated. The crystallinity and glass transition temperature increased while cold crystallization temperature and cold enthalpy decreased due to the development of orientation and stress induced crystallization by the cord drawing. Introducing PET to PTT decreased the crystallinity of PTT. However, it enhanced the orientation of PTT/PET blends drawn at below the glass transition temperature of PET. This lead to the increase of tensile modulus and tensile strength of PTT/PET blends. The shrinkage increased with increasing orientation, which might be minimized by the development of crystalline morphology of PTT in the course of cold drawing.

The Physical Properties and Dyeability of Poly(trimethylene terephthalate) Fibers (Poly(trimethylene terephthalate) 섬유의 물성과 염색성)

  • 윤석한;김태경;임용진;조규민
    • Textile Coloration and Finishing
    • /
    • v.13 no.3
    • /
    • pp.197-202
    • /
    • 2001
  • The mechanical properties and dyeability of Poly(trimethylene terephthalate)(PTT) were investigated and compared to PET. Glass transition temperature of PTT was lower than that of PET, because amorphous region of PTT is mote flexible. n has smaller molecular and specific stress and larger strain than those of PET, due to the difference of molecular structure. Dyeing transition temperature of PTT was lower by $20^\circ{C}$ than that of PET. Because PTT has flexible chain and zigzag structure, dyeing Fate of PTT is faster than PET and dyeing of PTT is begun at lower temperature. As the hydrophobicity of disperse dyes increased, the ratio of equilibrium dye uptake on PTT to that on PET was increased.

  • PDF

Miscibility of Poly(trimethylene terephthalste)/Poly(ethylene naphthalate) Blends (Poly(trimethylene terephthalate)/Poly(ethylene naphthalate) 블렌드의 혼화성)

  • 최재원;김영호
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2003.10b
    • /
    • pp.70-73
    • /
    • 2003
  • 최근 들어 poly(trimethylene terephtha)ate)(PTT)를 폴리에스터계 고분자들인 PET, PTN, PBN 등과 블렌드하고 이들의 특성 변화에 대해 검토한 결과가 많이 발표되고 있다. PTT를 PET나 PTN과 블렌드시키면 혼화성이 없으나, 이들 블렌드물을 용융시키면 점차 하나의 T$_{g}$를 나타내어 혼화성을 갖는다[1-3]. 반면에 PTT와 PBN을 블렌드시키면 처음부터 혼화성이 존재한다[4]. 이같이 PTT와 혼합되는 고분자의 종류에 따라 혼화성이 달라지는데, 본 연구는 PTT와 poly(ethylene naphthalate)(PEN)을 블렌드시키면 혼화성이 어떻게 되는가를 검토한 것이다. (중략)

  • PDF

Fine Structure Formation and Physical Properties of Poly(trimethylene terephtha late) Fibers with Drawing and Annealing (연신 및 열처리에 따른 Poly(trimethylene terephthalate) 섬유의 미세구조 형성 및 물성)

  • 주시환;김경효;조현혹
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2002.04a
    • /
    • pp.363-366
    • /
    • 2002
  • Poly(trimethylene terephthalate)(이하 PTT)는 1941년 Caligo Printing Ink 사의 Whinfield와 Dickson에 의해 PET와 함께 처음으로 중합방법이 보고[1]되었으나, 원료인 1,3-propanediol의 제조가격이 너무 높아 지난 60년간 상업화 및 학문적 연구가 거의 이루어지지 않았다. 최근 미국의 Shell사와 독일의 Degussa(현재 미국의 duPont)에 의해 1,3-propanediol이 대량생산되면서 PTT섬유의 상업적 생산에 점점 관심이 집중되고 있다. (중략)

  • PDF

Transesterification and Compatibilization in the Blends of Bisphenol-A Polycarbonate and Poly(trimethylene terephthalate)

  • Na Sang-Kuwon;Kong Byeong-Gi;Choi Changyong;Jang Mi-Kyeong;Nah Jae-Woon;Kim Jung-Gyu;Jo Byung-Wook
    • Macromolecular Research
    • /
    • v.13 no.2
    • /
    • pp.88-95
    • /
    • 2005
  • Melt blending of Bisphenol A polycarbonate (PC) and poly(trimethylene terephthalate) (PTT) was carried out over the entire composition range. The mixing time was varied up to 90 min. The resulting samples were analyzed by FT-IR, DSC, XRD, DMTA, $^{1}H NMR$, and SEM. The process of transesterification between the two polymers and their resulting compatibilization were observed. The behaviors of the PTT-rich and PC-rich blends were different and an equilibrium was found to exist. Peculiar behavior, which was different from that of the PTT-rich and PC-rich blends, was exhibited by the 50/50 (PTT/PC) blend.

Change on Fine Structure of PTT Fiber with Vibrating Drawing and Annealing (진동 연신.열처리에 따른 PTT 섬유의 미세구조 변화)

  • 박은영;김경효;이양헌;조현혹
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2003.10b
    • /
    • pp.213-214
    • /
    • 2003
  • 1950년 Poly(ethylene terephthalate)(이하 PET)의 상업화 이후 Poly(trimethylene terephthalate)(이하 PTT)는 동종의 Poly(methylene terephthalate)계열의 고분자 중에서 Poly(butylene terephthalate) (이하 PBT)와 함께 최근 가장 주목받는 섬유 중의 하나이다. PTT 섬유는 얼마 전까지만 해도 주원료인 1,3-propanediol(이하 PDO)의 가격이 너무 높아 지난 60년 간 상업화 및 학문적 연구가 거의 이루어지지 않다가 최근 미국의 Shell사와 독일의 Degussa(미국의 Dupont)에 의해 PDO가 대량 생산되면서 상업화에 대한 연구가 활발히 이루어지고 있다. (중략)

  • PDF

Effect on the Orientation of Poly(trimethylene terephthalate) Fibers in Drawing Condition(II) (연신조건이 PTT섬유의 배향에 비치는 영향(II))

  • 김경효;강석진;이양헌;조현혹
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2003.04a
    • /
    • pp.68-71
    • /
    • 2003
  • Poly(trimethylene terephthalate)는 1941년 Caligo printing Ink 사의 Whinfield와 Dickson에 의해 PET와 함께 처음으로 그 중합방법이 보고 된 이래, 주원료인 1,3-propanediol의 생산가격이 너무 높아 지난 60년간 상업화 및 학문적 연구가 거의 이루어져 있지 않다. 미국의 Shell사와 독일의 Degussa(미국의 Dupont)에 의해 1,3-propanediol이 대량 생산되면서[1], PTT 섬유의 상업적 생산에 점점 관심이 집중되고 있다. 국내에서도 S사와 Shell의 공동연구에 의해 제품이 생산되는 둥 많은 연구가 진행중에 있기는 하지만, Poly(ethylene terephthalate)의 연구에 비한다면 아직 걸음마 단계의 기초 자료로 제품이 생산되고 있는 실정이다. (중략)

  • PDF