• Bulletin of the Korean Chemical Society
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• 제34권5호
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• pp.1391-1396
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• 2013

The photocontrolled reduction of silver nitrate to silver (Ag) nanoparticles on honeycomb-patterned poly(N-vinylcarbazole) (PVK)-cellulose triacetate (CTA) composite thin films was studied. The composites were prepared via the oxidative polymerization of N-vinylcarbazole with ferric chloride using different CTA concentrations. A honeycomb-patterned film was fabricated by casting the composite solution under humid conditions. Ag particles with a homogeneous distribution were produced by the composite film in a moderate CTA concentration, whereas aggregated Ag was obtained from the pure PVK film.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2006년도 추계학술발표대회 및 제11회 신소재 심포지엄
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• pp.14.1-14.1
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• 2006

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.298-302
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• 2010

We report the effect of surface morphology on the conductivity of the poly-N-vinylcarbazole (PVK)/silica gel ($SiO_2$) nanocomposites as a function of $SiO_2$ weight percentage (%).The polymerization of PVK was initiated by a free-radical polymerization. The surface morphology of the prepared composite shows the incorporation of $SiO_2$ in the prepared PVK-$SiO_2$ (PS) nanocomposites. The conductivity increased from $9.2{\times}10^{-5}S\;cm^{-1}$ to $9.6{\times}10^{-4}S\;cm^{-1}$ with the increase in the percentage of silica gel from 5 to 30%. The nanocomposites show a percolation behavior having a threshold value between 15 and 20%.

• 한국응용과학기술학회지
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• 제20권2호
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• pp.173-176
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• 2003

We have seen the effects of buffer layer in organic light-emitting diodes using poly(N-vinylcarbazole)(PVK). Polymer PVK buffer layer was made using static spin-casting method. Two device structures were made; one is ITO/TPD/Alq3/Al as a reference and the other is ITO/PVK/TPD/Alq3/Al to see the effects of buffer layer in organic light-emitting diodes. Current-voltage characteristics, luminance-voltage characteristics and luminous efficiency were measured with a variation of spin-casting speeds. We have obtained an improvement of luminous efficiency by a factor of two and half when the PVK buffer layer is used.

• Bulletin of the Korean Chemical Society
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• 제12권3호
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• pp.271-273
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• 1991

Poly (N-vinylcarbazole) was obtained spontaneously by 1,1,2,2-tetracyanocyclopropylstyrene(1) in polar solvents such as dichloromethane and acetonitrile at room temperature. The polymerization reactions were faster in more polar solvent and were not proceeded in less polar solvents such as chloroform and diethyl ether. The formation of poly (N-vinylcarbazole) was explained by bond-forming initiation theory, in which the initiating species are zwitterionic tetramethylene intermediates.

• 전자공학회논문지D
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• 제35D권11호
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• pp.55-61
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• 1998

정공 전달 중합체인 Poly(N-vinylcarbazole) (PVK)와 전자전달 유기물 재료인 2-(4-biphenyl)-5-(t-butyl-phenyl)-1,3,4-oxadiazole (Bu-PBD)에 발광 유기물 색소 Coumurine 6, TPB, Rhodamine B를 각각 도핑한 단층박막 유기물 전기발광 소자를 제작하였다. 스핀 코팅 방법에 의한 단층 구조와 가용성 재료의 사용으로부터 소자제작이 간단하였다. 활성영역은 인듐주석산화물(ITO) 과 알루미늄 전극 사이에 놓인 단층으로 구성하고 있다. 이러한 구조에서 전자와 정공의 전하가 각 전극에서 PVK : Bu-PBD 활성층으로 주입된다. 전압을 인가한 후 발광된 빛의 색은 각각 TPB, C6, Rhodamine B의 유기물 색소에 의해 481nm, 500nm, 585nm 파장을 갖는 푸른색, 초록색 및 오렌지색을 나타내었다. PVK유기물은 다른 발광색을 갖는 유기물 색소를 분자 적으로 도핑 함으로서 주요한 중합체로서 사용될 수 있다. 그리고 전기발광색은 전체 가시광선 파장 내로 조절될 수 있다.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2967-2972
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• 2010

Poly-N-vinylcarbazole/polyaniline (PVK-PANI) composites are synthesized by varying target loading concentrations of aniline (0.025 - 0.1 M). The surface morphology of the composites is studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The temperature-dependent DC conductivity of PVK-PANI composite films was studied at the temperature range of 300 - 500 K. The data suggest that the conductivity increase with an increase in aniline concentration in the composite with an increase in temperature. Further based on the conductivity behavior we can suggest that the PVK-PANI composites show a semiconducting behavior with a positive temperature coefficient of resistivity (TCR). The enhanced conductivity and the positive TCR of the PVK-PANI composite films may be due to the strong interaction between PANI and PVK in the composite films.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.606-609
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• 1999

We fabricated white light-emitting diode which have a mixed single emitting layer containing poly(N-vinylcarbazole), trois(8-hydroxyquinoline)aluminum and poly(3-hexylthiophene) and investigated the emission properties of it. It is possible to obtain a blue light from poly(N-vinylcarbazole). green light from tris(8-hydroxyquinoline)aluminum and red light from poly(3-hexylthiophene). The fabricated device emits white light with slight orange light. We think that the energy transfer in a mixed layer occurred from PVK to Alq₃ and P3HT resulted in decreasing the blue light intensity from PVK. We find that the efficiency of the white light electroluminescent device can be improved by injecting electron more effectively and blue light need to improve the color purity of white light.

• 센서학회지
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• 제6권4호
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• pp.252-257
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• 1997

ITO(indium-tin-oxide)/PPV(poly(p-phenylenevihylene))/음극 전극의 단층구조와 ITO /PVK(poly(N-vinylcarbazole))/PPV/음극전극의 이층구조를 가진 유기 EL(electroluminescence) 소자를 제작하였으며, 전기-광학적 특성을 측정하였다. 실험 결과, 단층구조에서는 PPV막의 열변환 온도를 $140^{\circ}C$에서 $260^{\circ}C$로 증가할수록 최대 휘도가 $118.8\;cd/m^{2}$(20V)에서 $21.14\;cd/m^{2}$(28V)으로 감소하였고, EL 스펙트럼의 최대 피크가 500nm에서 580nm로 이동하였다. 또한, 음극전극의 일함수가 낮을수록 소자의 발광휘도와 주입 전류는 증가되었다. 이층구조에서는 PVK막의 농도가 감소함에 따라 발광휘도가 $70.71\;cd/m^{2}$(32V)에서 $152.7\;cd/m^{2}$(26V)으로 증가하였다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1999년도 가을 한국섬유공학회 학술발표회 논문집(Proceedings of the Korean Textile Conference)
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• pp.33-36
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• 1999