• 한국환경과학회지
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• 제21권12호
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• pp.1495-1501
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• 2012

In this study, an experiment was conducted on influent water with low concentrations of organic matter, such as river water or secondary treatment water of a sewage treatment plant, according to HRT changes by using aerobic biofilm. In the biofilm process, as the biofilm increases in thickness, the inner membrane can be low in oxygen transfer rate and become anaerobic conditions, while the detachment of biomass from biofilm occurs. To overcome these limitations in the detachment of microorganisms in biofilm, the yarn, which was made from poly propylene(PP), was weaved and manufactured into a tube. Then, a test was carried out by injecting air so that the interior of the biofilm could create aerobic conditions. The results of the experiment showed that the removal efficiency of $TCOD_{cr}$ reached 66.1~81.2% by HRT 2hr, and 50.9 ~61.8% after HRT 1 hr. The removal efficiency of $SCOD_{cr}$ was 45.9 to 55.1% by HRT 1hr, and 26.1% in HRT 0.5hr, showing the highest removal efficiency in HRT 1hr. The SS removal efficiency was at 81.8 to 94.6%, and the effluent SS concentration was very low, indicating less than 2.2 mg/L in all HRT's. As a result, the $SCOD_{cr}$ and $NH_4{^+}$-N that were removed per specific surface area and attached to microbial biofilm showed the highest efficiency in HRT 1hr with 8.37 $gSCOD_{cr}/m^2{\cdot}d$, 2.93 $gNH_4{^+}-N/m^2{\cdot}d$. From the result of reviewing the characteristics of biofilm growth, microorganisms were found to be attached, and increased by 36 days. Later, they decreased in number through detachment, but showed a tendency to increase again 41 days later due to microbial reproduction.

• 한국물환경학회지
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• 제37권5호
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• pp.363-368
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• 2021

On the assessment results of the non-point source pollutant removability of bio-block using waste sewage sludge, at the reactor's initial operation stage, the removal efficiency of COD was slightly unstable. However, after the reactor was stabilized, the COD removal efficiency was higher in the reactor filled with bio-blocks compared to the reactor filled with broken stones. In terms of nitrogen and phosphorus, their removal efficiency was unstable at the initial stage of the reactor operation. This phenomenon was investigated through the bio-block elution experiments. Results indicated that nitrogen and phosphorus were eluted from the bio-blocks affecting their removal at the initial operation. Furthermore, based on elution tests conducted after the dry ashing of the waste sewage sludge, part of the nitrogen and phosphorus was eluted similar to the bio-block elution test results, although considerable amounts of nitrogen and phosphorus were reduced compared to the sludge cake. Prior to the use of the waste sewage sludge bio-blocks as a filter medium to remove non-point source pollutants, a stabilization period of 10 days was required. After the stabilization process, results showed similar characteristics as general aggregates. Moreover, to use the bio-block as a filter medium for the non-point pollutant removal, the filling ratio of 75% was the most suitable as it resulted in the highest nitrogen removal efficiency after the stabilization. The results of this study suggested that waste sewage sludge can be suitably recycled as a mixed raw material for the bio-blocks, with satisfactory application as a filter medium in artificial wetlands, stormwater runoff problems, stream water pollutants to eliminate non-point source pollutants.

• Journal of Microbiology and Biotechnology
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• 제19권9호
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• pp.1028-1033
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• 2009

In this study, the dynamics of living cells (LC) and dead cells (DC) in a laboratory-scale biofilm membrane bioreactor for waste gas treatment was examined. Toluene was used as a model pollutant. The bacterial cells were enumerated as fluoromicroscopic counts during a 140 operating day period using BacLight nucleic acid staining in combination with epifluorescence and confocal laser scanning microscopy (CSLM). Overall, five different phases could be distinguished during the biofilm development: (A) cell attachment, (B) pollutant limitation, (C) biofilm establishment and colonization, (D) colonized biofilm, and (E) biofilm erosion. The bioreactor was operated under different conditions by applying different pollutant concentrations. An optimum toluene removal of 89% was observed at a loading rate of 14.4 kg $m^{-3}d^{-1}$. A direct correlation between the biodegradation rate of the reactor and the dynamics of biofilm development could be demonstrated. This study shows the first description of biofilm development during gaseous toluene degradation in MBR.

• 한국습지학회지
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• 제12권3호
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• pp.39-47
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• 2010

최근 우리나라 농경지 면적은 해마다 감소하고 있는 추세이나 이러한 농업지역으로부터 발생되는 오염부하량은 오히려 증가하고 있는 실정이다. 농업지역으로부터 발생되는 오염물질 중 대부분은 비점오염원에 의해 배출되며 이는 주로 저농도이면서 넓은 지역에서 대량으로 배출되는 특성을 보인다. 본 연구의 목적은 농업지역 내 비점오염원을 관리하기 위한 방안으로 인공습지를 적용하여 수질정화효율을 분석함으로써 인공습지 적용가능성과 오염물질 제거기작, 설계인자 등을 제공함에 있다. 모니터링 결과를 토대로 수질분석을 실시하였으며 분석 결과, 유입수의 평균 농도 제거율은 TSS가 26 %, BOD가 28 %, TN이 16 %, TP가 39 %로 나타났다. 또한 국내 하천수질기준에 준하여 인공습지 유입수과 유출수의 수질을 비교해 본 결과 대부분의 항목에서 수질등급이 향상되었다.

• Journal of Animal Science and Technology
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• 제45권4호
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• pp.641-648
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• 2003

본 연구에서는 돈사 폐수내의 인과 질소를 함께 결정화하여 회수하고 그 상등액을 전기분해 시키는 회분식 돈사 폐수공정에서의 오염물질 부하량과 수처리시간 변화에 따른 처리효율의 변화 및 각 오염물질 제거특성을 파악하였다. Struvite 형성을 위한 Mg원으로는 $MgCl_2$를 사용하였고 주입량은 폐수내 인 기준 1.3 Mole이었다. 총 4개의 운전(Run I, II, III, IV)에서 얻어진 평균 제거효율과 그 제거특성을 분석한 결과 인의 경우 부하량 변화에 따른 처리효율의 변화는 관찰되지 않았으며 제거의 주요 역할을 하는 반응조는 Struvite 반응조로서 적정 Mg원만 제공된다면 pH 조절제 첨가 없이 폭기만으로도 부하량에 관계없이 88% 이상의 제거가 MAP 형성을 통해 얻어지는 것으로 나타났다. 높은 암모니아성 질소 제거효율을 유지하기 위한 적정 부하량은 약 100g/$m^3$.d로서 동 부하량 이하에서는 부하량이 증가함에 따라 제거량도 증가하면서 90% 이상의 높은 효율과 일정한 제거특성을 보인 반면 그 이상에서는 불안정한 제거특성을 나타내면서 제거효율이 감소하였다. TOCs의 경우에는 부하량 변화에 따른 처리효율 변화는 관찰되지 않았으며, 그 제거효율은 수처리 시간에 의존적인 것으로 나타났다 ($r^2$ = 0.97). 색도 제거 효율은 전기분해조 용적기준 수처리시간 2일 이상에서 94%의 매우 높고 일정한 효율을 얻을 수 있었다.

• 한국농공학회논문집
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• 제48권3호
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• pp.97-106
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• 2006

The pollutant concentrations at experimental paddy plots with three (excessive, standard, reduced) different fertilization rates were investigated during 2001-2002 irrigation seasons. Mean concentrations of pollutants in ponded water were not significantly different among three experimental plots, but the T-N concentrations in percolated water significantly depended on fertilization rates. The T-N, T-P and $COD_{Cr}$, concentrations in ponded water during early irrigation season (late May to mid-June) were much higher than those during later irrigation season likely due to fertilization and low uptake by young rice crops. The T-N concentrations decreased but the concentrations of T-P and $COD_{Cr}$, increased three days after tillering fertilization. The removal rates of T-N by paddy plots were $0.13-0.16g/m^2{\cdot}d$ for an excessive fertilization plot, $0.08-0.25g/m^2{\cdot}d$ for a standard fertilization plot, and $0.03-0.34g/m^2{\cdot}d$ for a reduced fertilization plot three days after tillering fertilization. On the other hand, T-P and $COD_{Cr}$, were released three days after tillering fertilization.

• 한국환경농학회지
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• 제19권5호
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• pp.426-432
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• 2000

Field experiment was performed from August 1996 to December 1999 to examine the feasibility of constructed wetland system for sewage treatment in rural areas. A pilot system was installed in Konkuk University and the effluent of septic tank for school building was used as an influent to the wetland treatment basin. The system was composed of sand and reed, and operated continuously including winter time. Average removal rate of about 70% was observed for BOD, COD, and SS, about 50% for T-P, and about 25% for T-N. The reason for poor T-N removal might be due to high loading rate and short retention time. The system demonstrated satisfactory effluent concentration and stable performance in growing season. And it also worked adequately in wintertime even below $10^{\circ}C$ without freezing, and removal was still significant. The amount removed in BOD, COD, and SS was almost the same as in the growing season, and the amount removed in nutrients was about half of the one in growing season. Overall performance of the experimental system was compared with existing data base (NADB, 1994), and it was within the range of general system performance. As study period increased, removal rates for BOD, COD, SS, and T-P were consistently maintained and even enhanced, but removal rate for T-N decreased slightly. Wetland system was thought to be a feasible alternative for sewage treatment in rural area considering its low cost and low maintenance requirement. However, the effluent of the experimental wetland system often exceeded current effluent water quality standards, therefore, further treatment could be required if the effluent should be discharged to public waters. Wetland system of interest locates in rural area and is a part of rural ecosystem, therefore, ultimate disposal of reclaimed sewage for agricultural purpose or subsequent land treatment might be available and further research in this matter is recommended.

• 한국환경과학회지
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• 제11권8호
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• pp.819-827
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• 2002

Laboratory scale experiments were conducted to evaluate the performance of a biofilter for eliminating dimethyl sulfide(DMS). A commercial compost/pine bark nugget mixture served as the biofilter material for the experiments. The gas flow rate and DMS concentration entering the filter were varied to study their effect on the biofilter efficiency. The operating parameters, such as the residence time, inlet concentration, pH, water content, and temperature, were all monitored throughout the filter operation. The kinetic dependence of the DMS removal along the column length was also studied to obtain a quantitative description of the DMS elimination. High DMS removal efficiencies(>95％) were obtained using the compost filter material seeded with activated sludge. DMS pollutant loading rates of up to 5.2 and 5.5 g-DMS/m$^3$/hr were effectively handled by the upflow and downflow biofilter columns, respectively. The macrokinetics of the DMS removal were found to be fractional-order diffusion-limited over the 9 to 25 ppm range of inlet concentrations tested. The upflow column had an average macrokinetic coefficient(K$\_$f/) of 0.0789 $\pm$ 0.0178 ppm$\^$$\sfrac{1}{2}$//sec, while the downflow column had an average coefficient of 0.0935 $\pm$ 0.0200 ppm$\^$$\sfrac{1}{2}$//sec. Shorter residence times resulted in a lower mass transfer of the pollutant from the gas phase to the aqueous liquid phase, thereby decreasing the efficiency.

• 한국환경농학회지
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• 제19권2호
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• pp.122-127
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• 2000

A stream purification system was applied to the upper reaches of the Masan Reservoir to improve the water quality. This system consisted of two channels which were constructed on both sides of the stream, one side packed with crushed gravels and the other with plastic filter media. The system operated under low pollutant concentrations and high hydraulic loadings during a dry season to avoid clogging of the filter media. Removal rate and efficiency of chemical oxygen demand (COD) in the channel packed with crushed gravel were $14.8g/m^3/d$ and 11.5%, and for the channel with plastic filter media, $50.1g/m^3/d$ and 13.5%, respectively. Removal efficiencies of total phosphorus (T-P) were 6.6% (gravel) and 10.0% (plastic media). These results indicated plastic filter media having relatively high specific surface areas were more efficient than crushed gravels in removing pollutants. However, due to low influent water quality during dry season, the removal efficiencies were low. The proportion of nitrate nitrogen to total nitrogen (T-N) of the inflow was high but, as the system operated under aerobic condition, nitrate nitrogen could not denitrified. Accordingly, total nitrogen was not attenuated with this system. To improve the reservoir water quality effectively, this system should be able to treat the storm runoff containing higher pollutant loadings. When the filter materials are clogged by the storm runoff instead of backwashing, it would be more efficient to replace them, Therefore, the use of natural materials which are light, easily obtaining and replaceable, and have high specific surface areas is recommended.

• Membrane and Water Treatment
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• 제10권1호
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• pp.75-82
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• 2019

In a highly urbanized area, land availability is limited for the installation of space consuming stormwater systems for best management practices (BMPs), leading to the consideration of underground stormwater treatment devices connected to the stormwater pipe system. The configuration of a stormwater pipe network determines the hydrological and pollutant transport characteristics of the stormwater discharged through the pipe network, and thus should be an important design consideration for effective management of stormwater quantity and quality. This article presents a multi-objective optimization approach for designing a stormwater pipe network with on-line stormwater treatment devices to achieve an optimal trade-off between the total installation cost and the annual removal efficiency of total suspended solids (TSS). The Non-dominated Sorted Genetic Algorithm-II (NSGA-II) was adapted to solve the multi-objective optimization problem. The study site used to demonstrate the developed approach was a commercial area that has an existing pipe network with eight outfalls into an adjacent stream in Yongin City, South Korea. The stormwater management model (SWMM) was calibrated based on the data obtained from a subcatchment within the study area and was further used to simulate the flow rates and TSS discharge rates through a given pipe network for the entire study area. In the simulation, an underground stormwater treatment device was assumed to be installed at each outfall and sized proportional to the average flow rate at the outfall. The total installation cost for the pipes and underground devices was estimated based on empirical formulas using the flow rates and TSS discharge rates simulated by the SWMM. In the demonstration example, the installation cost could be reduced by up to 9% while the annual TSS removal efficiency could be increased by 4% compared to the original pipe network configuration. The annual TSS removal efficiency was relatively insensitive to the total installation cost in the Pareto-optimal solutions of the pipe network design. The results suggested that the installation cost of the pipes and stormwater treatment devices can be substantially reduced without significantly compromising the pollutant removal efficiency when the pipe network is optimally designed.