• Title/Summary/Keyword: polarization force

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A STUDY ON THE PHYSICAL PROPERTIES AND BIOLOGICAL CHARACTERISTICS OF DENTAL MAGNETIC ATTACHMENTS (치과용 자석부착장치의 물리적, 생물학적 특성에 관한 연구)

  • Lim, Yong-Sik;Kim, Yung-Soo;Kim, Chang-Whe;Kim, Yong-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.37 no.1
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    • pp.1-22
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    • 1999
  • In order to investigate various physical and biological properties of dental magnetic attachments studies on retentive characteristics, corrosion properties, cytotoxicity of different magnetic systems for dental applications were done. For the study of retentive characteristics changes of retentive force by increasing air gap, wear properties of various attachment systems and loss of magnetic force by heat treatment were measured. Forte study of corrosion property of magnet covering metal electrochemical corrosion was done in artificial saliva and 0.9% NaCl solution between $-1,000mV_{SCE}\;and\;+1,000mV_{SCE}$. Anodic polarization curves are obtained about 6 types of samples and 2 types of solution. Corroded surfaces were examined with metallurgical microscope, scanning electron microscope and surface profilometer. For the study of cytotoxicity of magnetic attachment and its field cell growth and agar overlay test were done. The results of this study were as follows. 1. In Magnetic attachments using closed circuit retentive force at zero air gap was greater than magnets using open circuit, but decrease of retentive force by increasing air gap was also greater than open systems. 2. After 40,000 cycles of wear test all mechanical attachment resulted in varing degree of retention loss but in magnetic attachments no loss of retentive force was observed. 3. The magnetic attachment using Neodymium magnet showed early loss of retentive force about $200^{\circ}C$ but attachment using Samarium magnet showed some resistance to heat treatment and complete retention loss was observed about $500^{\circ}C$. The keeper was not influenced by heat treatment in retention. 4. In electrochemical corrosion test Dyna magnetic attachment covering metal showed the highiest corrosion resistance and Shiner magnet covering metal showed the least corrosion resistance and examination of corroded surface with metallurgical microscope, scanning electron micro-scope and surface profilometer also showed same results with anodic polarization corves. 5. The result of cell culture tests on the magnet covered with metal showed least recognizable cytotoxicity.

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Dielectric properties of $Bi_{3.25}La_{0.75}Ti_3O_{12}$ thin films with Bi contents (Bi 첨가량에 따른 BLT 박막의 유전특성)

  • 김경태;김창일;강동희;심일운
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.371-374
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    • 2002
  • Bismuth lanthanum titanate thin films with excess Bi contents were prepared onto Pt/Ti/$SiO_2$/Si substrate by metalorganic decomposition (MOD) technique. The structure and morphology of the films were analyzed using X-ray diffraction (XRD) and atomic force microscopy (AFM), respectively. From the XRD analysis, BLT thin films show polycrystalline structure and the layered-perovskite phase was obtained over 10% excess of Bi contents. As a result of ferroelectric characteristics related to the Bi content of the BLT thin film, the remanent polarization and dielectric constant decreased with increasing over Bi content of 10 % excess. The BLT film with Bi content of 10% excess was measured to have a dielectric constant of n9 and dielectric loss of 1.85[%]. The BLT thin films showed little polarization fatigue test up to 3.5 x $10^{9}$ bipolar switching cycling.

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temperature synthesis and ferroelectric properties of (117)-oriented $Bi_{3.25}La_{0.75}Ti_3O_{12}$ thin films on $LaNiO_3$ electrodes

  • Kim, Kyoung-Tae;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.264-267
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    • 2004
  • [ $Bi_{3.25}La_{0.75}Ti_3O_{12}$ ] (BLT) thin films were prepared by using metal organic decomposition method onto the $LaNiO_3$ (LNO) bottom electrode. Both the structure and morphology of the films were analyzed by x-ray diffraction (XRD) and atomic force microscope (AFM). Even at low temperatures ranging from 450 to $650^{\circ}C$, the BLT thinfilms were successfully deposited on LNO bottom electrode and exhibited (117) orientation. The BLT thin films annealed as low as $600^{\circ}C$ showed excellent ferroelectricity, higher remanent polarization and no significant degradation of switching charge at least up to $5{\times}10^9$ switching cycles at a frequency of 100 kHz and 5 V. For the annealing temperature of $600^{\circ}C$, the remanent polarization Pr and coercive field were $23.5\;C/cm^2$ and 120 kV/cm, respectively.

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Novel Long-period Fiber Grating devices for Monitoring the Deformation of Ship Hull (선체의 변형을 감지하기 위한 새로운 형태의 장주기 광섬유 격자 소자)

  • Sohn, Kyung-Rak
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.6
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    • pp.761-767
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    • 2007
  • We have developed novel optical-fiber sensors based on strain-induced long-period fiber gratings for monitoring the deformation of a hull. They have no external pressure for sustaining the mechanical formed gratings. The pressure, which provides a force to form the periodic grating along the single mode fiber, was realized by the bonding strength of a photopolymer. To reduce the polarization dependency of the sensors caused by the asymmetry structure of gratings, a Faraday Rotator Mirror (FRM) was utilized in this experiment. We have realized the polarization-insensitive function of the proposed sensors. The change of an external strain are measured by an optical spectrum analyzer. When the external stain increases. the attenuation at the resonant wavelength decreases and the loss peak was slightly shifted to the shorter wavelength.

Ultraprecision polishing for micro parts using electric polarization effect of abrasive particles (연마입자의 전기적 분극성을 이용한 초정밀연마기술)

  • 이승환;김욱배;이상조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.227-230
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    • 2002
  • New polishing technique for small parts has been tried out using the principle of particle electromechanics. Common fine abrasives such as alumina, diamond, silicon carbide are dielectric materials which are polarized under an electric field, and a non-uniform electric field makes abrasive particles translate along the field line. Using this principle, We make abrasive particles aggregate in the vicinity of the micro tool which is fir the surface finishing of a small part without contact with it. The behavior of particles is optically measured, and the machined depth of glass is examined.

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Effect of Dry Process on Dielectric Properties of PZT Thin Films Prepared by Sol-Gel Process

  • Bae, Min-Ho;Lim, Kee-Joe;Kim, Hyun-Hoo;No, Kwang-soo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.42-45
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    • 2002
  • Properties of lead zirconate titanate ferroelectric thin films prepared by rapid thermal annealing/direct insertion thermal annealing were investigated. The remnant polarization (Pr), saturation polarization (Ps), and coercive force (Ec) of typical samples annealed by rapid thermal annealing (RTA) are about 13.7 $\mu$ C/cm$^2$, 27.1 $\mu$C/cm$^2$, and 55.6 kV/cm, respectively. The dielectric constant of the sample is about 786, the dielectric loss tangent is about 2.4% at 1 kHz. Furthermore, ferroelectric, conduction, and piezoelectric properties of the thin films annealed by RTA process and the direct insertion thermal annealing (DITA) process were compared. The influence of temperature in the dry process on the above properties was also investigated.

A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques

  • Ozkir, Demet
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.37-54
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    • 2019
  • A new organic Schiff base compound N-benzylidene-2,5-dichloroaniline (BDC) was synthesized and the structure of the Schiff base is illuminated by some spectroscopic techniques. In addition, whether it is an applicable inhibitor in the industrial field was examined by conventional methods such as linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization for different concentrations. The BDC concentration and temperature effects were surveyed for elucidating the inhibitive mechanism. The BDC molecules are adsorbed to surface of mild steel via the Langmuir isotherm. Atomic force (AFM) and scanning electron microscope (SEM) techniques were utilized to give insight into surface characterization.

Role of chloride ions with Zwitterions and phosphate groups on the improvement of the passive film in alkaline environment (알칼리성 환경에서 부동태 피막 개선에 대한 양쪽성 이온 및 인산염 그룹을 갖는 염화물 이온의 역할)

  • Tran, Duc Thanh;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.43-44
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    • 2022
  • In this study, the optimum amount of chloride ions is used to collaborate with hybrid corrosion inhibitor for carbon steel rebar treatment in simulated pore concrete (SCP) solution is discovered. The corrosion inhibition performance of hybrid inhibitors is carried on by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (PP). The highest corrosion inhibition resistance is found in case of LP-C2 after 240 h exposure. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate well with electrochemical studies. Anodic type inhibition action was confirmed by potentiodynamic polarization study.

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Effect of Hybrid Inhibitor on the Mitigation of Corrosion Initiation in SCP Solution Contaminated 3.5 wt.% NaCl (3.5 wt.% NaCl로 오염된 SCP 용액의 부식 개시 완화에 대한 하이브리드 억제제의 효과)

  • Tran, Duc Thanh;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.65-66
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    • 2021
  • In this study, the optimum amount of hybrid inhibitors i.e. L-Arginine (LA) and sodium phosphate tribasic dodecahydrate (SP), applied for carbon steel rebar in simulated pore concrete (SCP) solution contaminated with 3.5 wt.% NaCl, was discovered. The corrosion inhibition performance of hybrid inhibitors was investigated by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization. The highest corrosion inhibition efficiency was found as 99.52% corresponding to 2% LA and 0.25% SP after 210 h exposure. Anodic type inhibition action was confirmed by potentiodynamic polarization study. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate with electrochemical studies.

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Hydrogen Production by the High Temperature Steam Electrolysis of NiO/YSZ/Pt Cell (NiO/YSZ/Pt 전해셀의 고온 수증기 전해에 의한 수소제조 특성)

  • Yu, Ji-Haeng;Kim, Young-Woon;Lee, Shi-Woo;Seo, Doo-Won;Hong, Ki-Suk;Han, In-Sub;Woo, Sang-Kuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.1
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    • pp.62-68
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    • 2006
  • High temperature electrolysis is a promising technology to produce massively hydrogen using renewable and nuclear energy. Solid oxide fuel cell materials are candidates as the components of steam electrolysers. However, the polarization characteristics of the typical electrode materials during the electrolysis have not been intensively investigated. In this study, NiO electrode was deposited on YSZ electrolyte by spin coat process and firing at $1300^{\circ}C$. Pt electrode was applied on the other side of the electrolyte to compare the polarization characteristics with those by NiO during electrolysis. The $H_2$ evolution rate was also monitored by measuring the electromotive force of Lambda probe and calculated by thermodynamic consideration. At low current density, Pt showed lower cathodic polarization and thus higher current efficiency than Ni, but the oxidation of Ni into NiO caused the increase of anodic resistance with increasing current density. High overpotential induced high power consumption to produce hydrogen by electrolysis.