• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2669-2674
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• 2012

Crown ether is one of well-known host molecules and able to selectively sequester metal cation. We employed M06-2X density functional theory with IEFPCM and SMD continuum solvation models to study selectivity of dibenzo-18-crown-6-ether (DB18C6) for alkaline earth dications, $Ba^{2+}$, $Sr^{2+}$, $Ca^{2+}$, and $Mg^{2+}$ in the gas phase and in aqueous solution. $Mg^{2+}$ showed predominantly strong binding affinity in the gas phase because of strong polarization of CO bonds by cation. In aqueous solution, binding free energy differences became smaller among these dications. However, $Mg^{2+}$ had the best binding, being incompatible with experimental observations in aqueous solution. The enthalpies of the dication exchange reaction between DB18C6 and water cluster molecules were computed as another estimation of selectivity in aqueous solution. These results also demonstrated that $Mg^{2+}$ bound to DB18C6 better than $Ba^{2+}$. We speculated that the species determining selectivity in water could be 2:1 complexes of two DB18C6s and one dication.

• The Journal of Engineering Geology
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• v.6 no.1
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• pp.33-43
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• 1996

In this study, hypocentor parameters of some local and regional earthquakes and explosions, including focal depth and origin time, were redetermined by using a single station of three-component. We attempt to do the job by the combination of polarization analyses, by which azimuths and trial epicenters of earthquakes can be figured out, and a layered constant velocity model, on the basis of which theoretical travel times can be computed to match a series of input seismic phases of the event. Magnitudes were determined by using coda duration. Results, which correspond to the least misfit, showed that the average focal depth of all earthquakes in this study is around 15km, which fits well to that by investigation (Kang and Choi, 1993).

• Atmosphere
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• v.24 no.1
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• pp.77-87
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• 2014

The radar reflectivity is significantly affected by ground clutter, beam blockage, anomalous propagation (AP), birds, insects, chaff, etc. The quality of radar reflectivity is very important in quantitative precipitation estimation. Therefore, Weather Radar Center (WRC) of Korea Meteorological Administration (KMA) employed two quality control algorithms: 1) Open Radar Product Generator (ORPG) and 2) fuzzy quality control algorithm to improve quality of radar reflectivity. In this study, an occurrence of AP echoes and the performance of both quality control algorithms are investigated. Consequently, AP echoes frequently occur during the spring and fall seasons. Moreover, while the ORPG QC algorithm has the merit of removing non-precipitation echoes, such as AP echoes, it also removes weak rain echoes and snow echoes. In contrast, the fuzzy QC algorithm has the advantage of preserving snow echoes and weak rain echoes, but it eliminates the partial area of the contaminated echo, including the AP echoes.

• Korean Journal of Optics and Photonics
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• v.6 no.1
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• pp.26-32
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• 1995

A Kerr cell was utilized as an optical shutter to generate a shortened pulse and as an isolator between amplifiers in an iodine laser system. By rotating the polarization of incident laser pulse only during the timing window of high voltage applied to the Kerr cell, shortened pulses of 5 ns and 1 ns, corresponding to the difference in propagation time of two coaxial cables, were obtained. It was also noticed that more than one timing window of Kerr cell was produced with a long incident laser pulse from the oscillator. The measured transmittance of Kerr cell with respect to applied voltage was compared with the theoretical estimation using the electro-optic Kerr effect theory. Through the amplification of the shortened pulse in iodine amplifiers. a pulse of 0.5 GW(2 J in 4 ns) was obtained. ained.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.324-327
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• 2008

Microwave remote sensing has great potential, especially in monsoon Asia, since optical observations are often hampered by cloudy conditions. The radar backscattering characteristics of rice crop were investigated with a ground-based automatic scatterometer system. The system was installed inside a shelter in an experimental paddy field at the National Institute of Agricultural Science and Technology (NIAST) before transplanting. The rice cultivar was a kind of Japonica type, called Chuchung. The scatterometer system consists of X-band antennas, HP8720D vector network analyzer, RF cables, and a personal computer that controls frequency, polarization and data storage. This system automatically measures fully-polarimatric backscattering coefficients of rice crop every 10 minutes, accompanied by a digital camera that takes pictures in a fixed position with the same interval. The backscattering coefficients were calculated by applying a radar equation. Plant variables, such as leaf area index (LAI), biomass, plant height and weather conditions were measured periodically throughout the rice growth season. We have performed polarimetric decomposition of paddy data such as single, double and volume scattering to extract the scattering information effectively. We investigated the relationships between backscattering coefficients and the plant variables.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.464-475
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• 2009

Electrical resistivity can be used for porosity estimation. In order to improve previously developed ERCP(Electrical Resistivity Cone Probe), 4ERP(4 Electrical Resistivity Probe), which has Wenner array at the tip of probes, has been developed. In properties of current flow Wenner array measures electrical properties of undisturbed area during penetration and relatively correct measurements are guaranteed without polarization. Furthermore, Wenner array equation can estimate electrical resistivity without extra calibration. 4ERP is developed into 2 types, penetration and fixation. Penetration type has wedge-shaped tip. Considering disturbance minimization, fixed type has plane tip. Fixed type 4ERP in consolidation cell measure electrical resistivity increment along porosity decrease, and penetration type 4ERP measured resistivity profile along the depth in chamber. Applying Archie's law, porosity profile was estimated with electrical resistivity. The tests result suggests that 4ERP can be new site investigation equipment with little disturbance.

• Journal of the Korean Ceramic Society
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• v.42 no.12 s.283
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• pp.793-799
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• 2005

A composite cathode of LSCF$(La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3)\;and\;GDC\; (Gd_2O_3-doped\;CeO_2:Ce_{0.9}Gd_{0.1}O_{1.95_})$ was characterized in terms of an electrode response, using a point contact in an Yttria-Stabilized Zirconia (YSZ) electrolyte incorporated into AC two-point impedance spectroscopy. The point-contacted configuration amplifies the responses occurring near the YSZ/cathode interface through the aligned point contact on the planar LSCF/GDC electrode. The point contact interface increases the bulk resistance allowing the estimation of the point contact geometry and resolving the electrode-related responses. The resultant impedance spectra are analyzed through an equivalent circuit model constructed by resistors and constant phase elements. The bulk responses can be resolved from the electrode-related portions in terms of spreading resistance. The electrode-related polarizations are measured in terms of temperature and oxygen partial pressure. The modified impedance spectroscopy is discussed in terms of methodology and analytical aspects, toward resolving the electrode-polarization issues in solid oxide fuel cells.

• Journal of the Institute of Convergence Signal Processing
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• v.18 no.1
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• pp.21-24
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• 2017

Passive millimeter wave (MMW) imaging penetrates clothing to detect concealed objects. The distances extraction to the concealed objects is critical for the security and defense. In this paper, we address a passive stereo 3 mm MMW imaging system to extract the longitudinal distance to the concealed object. The concealed object area is segmented and extracted by the k-means clustering algorithm with splitting initialization. The distance to the concealed object is estimated by the corresponding centers of the segmented objects. In the experimental two pairs (each pair for horizontal and vertical polarization) of stereo MMW images are obtained to estimate distances to concealed objects.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.132-132
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• 2021

Access to accurate spatial precipitation in many hydrological studies is necessary. Existence of many mountains with diverse topography in South Korea causes different spatial distribution of precipitation. Rain gauge stations show accurate precipitation information in points, but due to the limited use of rain gauge stations and the difficulty of accessing them, there is not enough accurate information in the whole area. Weather radars can provide an integrated precipitation information spatially. Despite this, weather radar data have some errors that can not provide accurate data, especially in heavy rainfall. In this study, some location-based variable like aspect, elevation, plan curvature, profile curvature, slope and distance from the sea which has most effect on rainfall was considered. Then Automatic Weather Station data was used for spatial training of variables in each event. According to this, K-fold cross-validation method was combined with Adaptive Neuro-Fuzzy Inference System. Based on this, 80% of Automatic Weather Station data was used for training and validation of model and 20% was used for testing and evaluation of model. Finally, spatial distribution of precipitation for 1×1 km resolution in Gwangdeoksan radar station was estimates. The results showed a significant decrease in RMSE and an increase in correlation with the observed amount of precipitation.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.1
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• pp.23-31
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• 2013

Microwave remote sensing can help monitor the land surface water cycle and crop growth. This type of remote sensing has great potential over conventional remote sensing using the visible and infrared regions due to its all-weather day-and-night imaging capabilities. In this paper, a ground-based multi-frequency (L-, C-, and X-band) polarimetric scatterometer system capable of making observations every 10 min was developed. This system was used to monitor the wheat over an entire growth cycle. The polarimetric scatterometer components were installed inside an air-conditioned shelter to maintain constant temperature and humidity during the data acquisition period. Backscattering coefficients for the crop growing season were compared with biophysical measurements. Backscattering coefficients for all frequencies and polarizations increased until dat of year 137 and then decreased along with fresh weight, dry weight, plant height, and vegetation water content (VWC). The range of backscatter for X-band was lower than for L- and C-band. We examined the relationship between the backscattering coefficients of each band (frequency/polarization) and the various wheat growth parameters. The correlation between the different vegetation parameters and backscatter decreased with increasing frequency. L-band HH-polarization (L-HH) is best suited for the monitoring of fresh weight (r=0.98), dry weight (r=0.96), VWC (r=0.98), and plant height (r=0.96). The correlation coefficients were highest for L-band observations and lowest for X-band. Also, HH-polarization had the highest correlations among the polarization channels (HH, VV and HV). Based on the correlation analysis between backscattering coefficients in each band and wheat growth parameters, we developed prediction equations using the L-HH based on the observed relationships between L-HH and fresh weight, dry weight, VWC and plant height. The results of these analyses will be useful in determining the optimum microwave frequency and polarizations necessary for estimating vegetation parameters in the wheat.