• 제목/요약/키워드: polarization efficiency

검색결과 306건 처리시간 0.021초

Inhibitions of Corrosion of Nickel in Perchloric Acid by mono-substituted Phenyl N-phenylcarbamates

  • A. K. Mohamed;S.S. El;A.S. Fouda
    • Bulletin of the Korean Chemical Society
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    • 제10권6호
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    • pp.564-567
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    • 1989
  • The use of some mono-substituted phenyl N-phenylcarbamates derivatives as corrosion inhibitors for nickel in 1M perchloric acid was studied by galvanostatic polarization. The inhibition appears to function through general adsorption isotherm. However, galvanostatic polarization data suggest that in the case of all seven inhibitors both anode are polarized under the influence of an external current. Electrocapillary measurements have also revealed that the tendency of the inhibitors tested to adsorb on metallic surface follows the same order of efficiency.

The Effect of Imidazole and 2-Methyl Imidazole on the Corrosion of Mild Steel in Phosphoric Acid Solution

  • Chandrasekara, V.;Kannan, K.;Natesan, M.
    • Corrosion Science and Technology
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    • 제4권5호
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    • pp.191-200
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    • 2005
  • Two azole compounds viz., Imidazole (IM) and 2-Methylimidazole (2-MIM) were studied to investigate their inhibiting action on corrosion of mild steel in phosphoric acid ($H_3PO_4$) solution by mass loss and polarization techniques at 302K-333K. It has been found that the inhibition efficiency of the all inhibitors increased with increase in inhibitor concentration and decreases with increasing temperature and also with increase in acid concentrations. The inhibition efficiency of these compounds showed very good inhibition efficiency. At 0.5% of IM and 2-MIM in 1N and 5N phosphoric acid solution at 302K to 333K for 5 hours immersion period, the inhibition efficiency of 2-Methylimidazole found to be higher than Imidazole. The adsorption of these compounds on the mild steel surface from the acids has been found to obey Tempkin's adsorption isotherm. The values of activation energy ($E{\alpha}$) and free energy of adsorption (${\Delta}G{\alpha}ds$) were also calculated. The plots of log $W_f$ against time (days) at 302K give straight line which suggested that it obeys first order kinetics and also calculate the rate constant k and half life time $t_{1/2}$. Surface was analyzed by SEM and FITR spectroscopy.

Evaluation of the Inhibitive Performance of Cyperus Conglomeratus Leaves Extract as a Green Corrosion Inhibitor on Mild Steel XC70 in Acid Medium

  • Belkis, Guessoum;Abdelkader, Hadj Seyd;Oumelkheir, Rahim
    • Corrosion Science and Technology
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    • 제21권3호
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    • pp.171-183
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    • 2022
  • The performance and inhibitory action of the aqueous extract of Cyperus Conglomeratus's leaves against corrosion of XC70 steel in a 1M HCl acid medium are studied by the determination of the weight loss, the potentiodynamic polarization curves analysis, and electrochemical impedance measurements (electrochemical techniques). The corrosion inhibitory efficiency of XC70 steel increases with the increasing concentration of the green inhibitor, however, the corrosion rate of the steel decreases. Weight loss measurements show that the maximum percentage corrosion inhibition efficiency is approximately 61.86%, while the analysis of the mixed character polarization curves shows that the inhibitor could achieve an inhibition efficiency of 86.96%. The electrochemical impedance study confirmed that the value of the charge transfer resistance (Rct) increases and the value of the double layer capacity (Cdl) decreases with increasing concentration of the aqueous extract of Cyperus Conglomeratus's leaves, thus increasing the inhibition efficiency. The study showed that this aqueous extract acts by adsorption on the metal surface; this adsorption follows the Langmuir isotherm. This research work showed that Cyperus Conglomeratus leaves extract acts as an effective and eco-friendly inhibitor on mild steel in an acid medium.

$KH_2PO_4(KDP)$ 결정을 이용한 Nd:YAG 레이저의 제3고조파 변환 (Second Harmonic Conversion of Nd:YAG Laser using $KH_2PO_4(KDP)$ Crystal)

  • 장용무;김병태;강형부
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1989년도 하계종합학술대회 논문집
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    • pp.633-636
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    • 1989
  • The simulation results of the third harmonic conversion with 1.064 um Nd :YAG laser using polarization mismatch method are reported. The third harmonic conversion efficiency was over 65% for the Gaussian incident pulse of $300{\sim}400MW/cm^2$ peak intensity, and over 80% for $3{\sim}4GW/cm^2$ peak intensity pulse. The dependence of the third harmonic conversion efficiency' on the variation of incident polarization angle ${\theta}_p$ and angular discrepancy ${\Delta}{\theta}$ of phase matched angle ${\theta}_m$ is discussed.

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InGaAsP 전계흡수 광변조기 최적설계에 관한 연구 (Optimum design of InGaAsP electroabsorption optical modulator)

  • 한섭;한상국
    • 전자공학회논문지D
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    • 제34D권11호
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    • pp.83-89
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    • 1997
  • An optimize delectroabsorption modulator structure is designed for high speed optical communication systems considering the extinction efficiency, operating bandwidth, polarization loss, and wavelength chirping. the operating wavelength region is $1.55\mu\textrm{m}$ and the deep ridge structure is adapted for th eminimum polarization loss. Simulations show that the absorption layer thickness larger than $0.25\mu\textrm{m}$, and the modulator length shorter than $200\mu\textrm{m}$ are required for the bandwidth over 10GHz. To obtain the modulatiron efficiency over 10dB/V, a wavelength detuning needs to be determined less than 40meV.

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Synergistic Effect on Corrosion Inhibiton Efficiency of Ginger Affinale Extract in Controlling Corrosion of Mild Steel in Acid Medium

  • Subramanian, Ananth Kumar;Arumugam, Sankar;Mallaiya, Kumaravel;Subramaniam, Rameshkumar
    • 대한화학회지
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    • 제57권6호
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    • pp.672-676
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    • 2013
  • The corrosion inhibition nature of Ginger affinale extract for the corrosion of mild steel in 0.5N $H_2SO_4$ was investigated using weight loss, electrochemical impedance and potentiodynamic polarization methods. The results revealed that Ginger affinale extract acts as a good corrosion inhibitor in 0.5N $H_2SO_4$ medium. The inhibition efficiency increased with an increase in inhibitor concentration. The inhibition could be attributed to the adsorption of the inhibitor on the steel surface.

십자 개구 결합 급전을 이용한 -1 모드 원형 편파 안테나 (-1 Mode Circular Polarization Antenna Design by Using Cross Aperture-Coupled Feed)

  • 김준식;이정해
    • 한국전자파학회논문지
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    • 제25권2호
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    • pp.156-163
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    • 2014
  • 본 논문에서는 composit right-left handed (CRLH) 전송 선로에서 발생하는 -1 모드를 이용하여 십자 개구 결합 급전을 갖는 소형 원형 편파 메타 물질 안테나를 제안한다. -1 모드는 일반적인 패치 안테나의 기본 모드인 $TM_{010}$ 모드와 동일한 성질을 가지고 있기 때문에, 원형 편파의 동작원리를 동일하게 적용할 수 있다. 원형 편파는 두 개의 수직인 모드가 $90^{\circ}$의 위상 차이를 가질 때 형성된다. 두 개의 -1 모드를 얻기 위해서 사각형 형태를 갖는 4개의 버섯 구조를 이용하였고, 모드 간에 $90^{\circ}$의 위상차를 인가하기 위해서 십자형 개구의 폭과 길이를 최적화 하였다. 제작된 안테나의 4개로 배열된 버섯 구조의 면적은 $0.34{\lambda}_g{\times}0.34{\lambda}_g$이며, RT/duroid5880 기판에 설계되었다. 제안된 안테나의 중심 주파수는 좌수 원형 편파 안테나의 경우 1.622 GHz 원형 편파의 3 dB 대역폭은 3 MHz로 측정되었다. 우수 원형 편파 안테나의 경우, 중심 주파수는 1.609 GHz로 원형 편파의 3 dB 대역폭은 3 MHz로 측정되었다. 각각 안테나의 효율은 좌수 원형 편파 안테나의 경우 61.1 %, 우수 원형 편파 안테나의 경우 54.5 %로 측정되었다.

Analysis of Major Error Factors in Coherent Beam Combination: Phase, Tip Tilt, Polarization Angle, and Beam Quality

  • Jeongkyun Na;Byungho Kim;Changsu Jun;Yoonchan Jeong
    • Current Optics and Photonics
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    • 제8권4호
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    • pp.406-415
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    • 2024
  • The major error factors that degrade the efficiency of coherent beam combining (CBC) are numerically studied in a comprehensive manner, paying particular attention to phase, tip-tilt, polarization angle, and beam quality. The power in the bucket (PIB), normalized to the zero-error PIB, is used as a figure of merit to quantify the effect of each error factor. To maintain a normalized PIB greater than or equal to 95% in a 3-channel CBC configuration, the errors in phase, tip-tilt, and polarization angle should be less than 1.06 radians, 1.25 ㎛, and 1.06 radians respectively, when each of the three parameters is calculated independently with the other two set to zero. In a worst-case scenario of the composite errors within the parameter range for the independent-95%-normalized-PIB condition, the aggregate effect would reduce the normalized PIB to 83.8%. It is noteworthy that the PIB performances of a CBC system, depending on phase and polarization-angle errors, share the same characteristic feature. A statistical approach for each error factor is also introduced, to assess a CBC system with an extended number of channels. The impact of the laser's beam-quality factor M2 on the combining efficiency is also analyzed, based on a super-Gaussian beam. When M2 increases from 1 to 1.3, the normalized PIB is reduced by 2.6%, 11.8%, 12.8%, and 13.2% for a single-channel configuration and 3-, 7-, and 19-channel CBC configurations respectively. This comprehensive numerical study is expected to pave the way for advances in the evaluation and design of multichannel CBC systems and other related applications.

An Orthogonally Polarized Negative Resonance CRLH Patch Antenna

  • Kahng, Sungtek;Jeon, Jinsu;Park, Taejoon
    • Journal of Electrical Engineering and Technology
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    • 제10권1호
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    • pp.331-337
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    • 2015
  • A novel fully-printed microstrip antenna with negative first resonance and dual polarization is proposed. The radiator is printed on the 1-layer substrate instead of multilayers. The -1st resonance results from a composite right- and left-handed(CRLH) structure that has a circumferentially interlocked gap capacitively coupling a patch with a shorted-ring. This compact antenna is provided with a dual-polarization capability by creating two orthogonal linear polarizations in one body with coaxial feeds. The design is carried out by doing full-wave EM field simulation which is compared with the measurement of the fabricated antenna prototype. The measured results give the gain of 5 dBi and the efficiency of 78% at the -1st resonance mode as the center frequency of a downlink channel of the bandwidth over 20 MHz with 29 dB polarization isolation for mobile communication.

Lornoxicam & Tenoxicam Drugs as Green Corrosion Inhibitors for Carbon Steel in 1 M H2SO4 Solution

  • Fouda, A.S.;El-Defrawy, A.M.;El-Sherbeni, M.W.
    • Journal of Electrochemical Science and Technology
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    • 제4권2호
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    • pp.47-56
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    • 2013
  • Inhibition performance of Lornoxicam & Tenoxicam against corrosion of carbon steel in 1M $H_2SO_4$ solutions was investigated by weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The inhibition efficiency increased with increasing inhibitor's concentration, but decreased with increase in temperature. Potentiodynamic polarization curves showed that, the inhibitors were of mixed type. The apparent activation energy ($E^*_a$) and other thermodynamic parameters for the corrosion process have also been calculated and discussed. The inhibition of carbon steel corrosion is due to the adsorption of the inhibitor molecules on the surface, which follows Temkin adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.