• Title/Summary/Keyword: polarization efficiency

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Catalytic effects of heteroatom-rich carbon-based freestanding paper with high active-surface area for vanadium redox flow batteries

  • Lee, Min Eui;Kwak, Hyo Won;Jin, Hyoung-Joon
    • Carbon letters
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    • v.28
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    • pp.105-110
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    • 2018
  • Owing to their scalability, flexible operation, and long cycle life, vanadium redox flow batteries (VRFBs) have gained immense attention over the past few years. However, the VRFBs suffer from significant polarization, which decreases their cell efficiency. The activation polarization occurring during vanadium redox reactions greatly affects the overall performance of VRFBs. Therefore, it is imperative to develop electrodes with numerous catalytic sites and a long cycle life. In this study, we synthesized heteroatom-rich carbon-based freestanding papers (H-CFPs) by a facile dispersion and filtration process. The H-CFPs exhibited high specific surface area (${\sim}820m^2g^{-1}$) along with a number of redox-active heteroatoms (such as oxygen and nitrogen) and showed high catalytic activity for vanadium redox reactions. The H-CFP electrodes showed excellent electrochemical performance. They showed low anodic and cathodic peak potential separation (${\Delta}E_p$) values of ~120 mV (positive electrolyte) and ~124 mV (negative electrolyte) in cyclic voltammetry conducted at a scan rate of $5mV\;s^{-1}$. Hence, the H-CFP-based VRFBs showed significantly reduced polarization.

Single-Feed Composite Cavity-Backed Four-Arm Curl Antenna

  • Ta, Son Xuat;Park, Ikmo
    • Journal of electromagnetic engineering and science
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    • v.14 no.4
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    • pp.360-366
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    • 2014
  • A single-feed composite cavity-backed four-arm curl antenna is presented for use in global positioning systems (GPS). Its primary radiating element is fed by a vacant-quarter printed ring, which helps the antenna directly match to a $50-{\Omega}$ coaxial line and produce a good circular polarization (CP). The cavity-backed reflector is employed to improve the CP radiation characteristics in terms of 3-dB axial ratio (AR) beamwidth and minimum AR value. The optimized design with an overall size of $90{\times}90{\times}25mm^3$ ($0.4725{\lambda}_o{\times}0.4725{\lambda}_o{\times}0.13{\lambda}_o$ at 1,575 MHz) results in a ${\mid}S_{11}{\mid}<-10dB$ bandwidth of 8.66% (1,514-1,651 MHz) and a 3-dB AR bandwidth of 2.23% (1,555-1,590 MHz). The antenna radiates a widebeam right-hand circular polarization and operates with a measured radiation efficiency greater than 90% within its impedance matching bandwidth.

A Study on the Design and Efficiency of Membrane-Electrolyte Assembly in PEFC (PEFC 막-전극 접합체의 설계 및 효율에 관한 연구)

  • Kim H. G.;Kim Y. S.;Kim H. Y.;Yang Y. M.;Nah S. C.
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.180-184
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    • 2005
  • An experimental study is performed to evaluate the performance and the efficiency by humidifying MEA and by making the double-tied catalyst layers in a fuel cell system which is taken into account the physical and thermal concept. An electrical output produced by PEFC(polymer Electrolyte Fuel Cell) is measured to assess the performance of the stack and the efficiency is also evaluated according to the different situation in which is placed with and without the humidification of MEA (Membrane Electrolyte Assembly). Subsequently, It is found that the measured values of stack voltage and current are influenced by the stack temperature, humidification, and the double-tied catalyst layers which gives more enhanced values to apply for electric units.

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TA Study on the Performance and the Efficiency in Polymer Electrolyte embrane Fuel Cell (고분자전해질형 연료전지의 성능해석 및 효율에 관한 연구)

  • Kim Hong-Gun;Kim Yoo-Shin;Yang Sung-Mo;Nah Seok-Chan
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.4
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    • pp.75-80
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    • 2005
  • An experimental study is carried out to investigate the performance and the efficiency humidifying Membrane Electrolyte Assembly and having the double-tied catalyst layers in a fuel cell system which is taken into account the physical and thermal concept. Subsequently, an electric output produced by PEMFC(Polymer Electrolyte Membrane Fuel Cell) is measured to assess the performance of a stack, and the efficiency is also evaluated according to the different situation in which unit cell is placed with and without the humidification of the MEA. It is found that the measured values of stack voltage and current are influenced by the stack temperature, humidification, and the double-tied catalyst layers which give more enhanced values to be applied to electric units.

Miniaturization of Microstrip Antenna Using the folded Structure (폴디드 구조를 이용한 마이크로스트립 안테나의 소형화)

  • Heo Hee-Moo;Jang Yon-Jeong;Woo Jong-Myung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.16 no.5 s.96
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    • pp.526-533
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    • 2005
  • In this paper, the miniaturized the linear polarization and the circular polarization microstrip antennas, which are the two ends in the resonance length direction or all the four-ends were folded are designed and fabricated at the resonant frequency of 1.575 GHz(fur GPS system). For the linear polarization microstrip antenna, the antenna was bent. downward so that the visible length(=L) was reduced by $31.7\%(\varepsilon_r=1.06)$. The folded antenna was folded toward the center of the antenna once again. In this case, the visible length reduction rate, gain, -10 dB bandwidth, E-plane and H-plane HPBW were $73.9\%$, 5.12 dBd, $64MHz(4\%),\;151^{\circ}\;and\;79.2^{\circ}$, respectively. For the circular polarization microstrip antenna, the folded structure of the linear polarization antenna was applied to all the few directions. For the most efficiency the folded bottom surfaces were designed in a triangular shape. In this case, the visible area reduction rate, gain, -10 dB bandwidth, and HPBW in horizontal polarization of the z-x plane and the z-y plane were $71.5\%,\;3.96dBd,\;84MHz(5.3\%),\;80.6^{\circ}\;and\;82.1^{\circ}$, respectively. Therefore, we have confirmed that the folded structure is suitable fer the miniaturization of the microstrip antenna.

Schiff Bases as Anticorrosive Additives for Mild Steel Corrosion in Acid Media

  • Abirami, M.;Sasikala, S.;Chitra, S.;Parameswari, K.;Selvaraj, A.
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.1-10
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    • 2009
  • The influence of Schiff bases on the corrosion inhibition of mild steel in 1 M $H_2SO_4$ have been investigated by weight loss, gasometry, impedance and polarization techniques. The results obtained reveal that these compounds act as good inhibitors. The inhibition efficiency of Schiff bases increased with concentration and synergistically increased on addition of chromate, sulphate and halide ions. Potentiodynamic polarization measurements clearly reveal that the investigated inhibitors are of mixed type but they are more cathodic in nature. The adsorption of these compounds on mild steel surface for both the acids were found to obey Langmuir adsorption isotherm. The surface morphology was studied by SEM and UV reflectance spectra.

Role of Some Phenylthiourea Derivatives as Corrosion Inhibitors for Carbon Steel in HCl Solution

  • Fouda, Abd El-Aziz El-Sayed;Hussein, Ahmed
    • Journal of the Korean Chemical Society
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    • v.56 no.2
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    • pp.264-273
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    • 2012
  • Five derivatives of phenylthiourea namely: 1-(4-methoxyphenyl)-3-phenylthiourea (1), 1-(4-methylphenyl)-3- phenylthiourea (2), 1-(4-bromophenyl)-3-phenylthiourea (3), 1-(4-chlorophenyl)-3-phenylthiourea (4) and 1-phenylthiourea (5) have been evaluated as new inhibitors for the corrosion of carbon steel in 2 M HCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic polarization measurements showed that these derivatives are mixed-type inhibitors. The inhibition efficiency was found to increase with inhibitor concentration and decreases with rise in temperature. The thermodynamic parameters of adsorption and activation were determined and discussed. Nyquist plots showed depressed semicircles with their centre below real axis. The adsorption process of studied derivatives on carbon steel surface obeys Temkin adsorption isotherm. The synergistic effect of these derivatives and some anions is discussed from the viewpoint of adsorption models. The electrochemical results are in good agreement with the calculated quantum chemical HOMO and LUMO energies of the tested molecules.

Compact-Size Fractal Antenna with Stable Radiation Properties for Wi-Fi and WiMAX Communications

  • Abed, Amer T.;Singh, Mandeep S.J.;Islam, Mohammad Tariqul
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.12 no.6
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    • pp.2734-2747
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    • 2018
  • In this study, a novel fractal ring antenna with a compact size of $24{\times}9{\times}0.8mm^3$ was configured using three iterations. Low profile, circular polarization, and measured operating bands (4.5-6.5 GHz) meet specifications of the upper band used in Wi-Fi and WiMAX applications. The antenna featured, stable radiation properties, especially gain and efficiency, in the notched band (92%). In deep, the antenna impedance, reflection coefficients, surface current distribution and circular polarization for the three iterations had been studied to improve the process of antenna design and its radiation characteristics.

A Study on the Fabriation of Mode Convertible Optical Filter Utilizing Strain-optic Effect in LiNbO$_{3}$ (LiNbO$_{3}$의 스트레인광학 효과를 이용한 모드변환형 광여파기 제작에 관한 연구)

  • 박석봉;장홍식
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.1
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    • pp.72-78
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    • 1998
  • Polarization mode converters have been produced by utilizing Ti:LiNbO$_{3}$ channel waveguide and strain-optic effect. Shear strain for periodic perturbations of optical channel waveguides and phase matching can be obtained by an evaporated periodic SiO$_{2}$ thin film at 300.deg. C. The electrodes located on the either side of waveguide provide a means to electro-optically tune the wavelength for maximum polarization conversion via the electrooptic effect. The maximum conversion effeciency was observed at 21.deg. C for V=0 and 46.deg. C for V=30V aro the device having 7 .mu.m waveguide wiith and 350 periodic pads. The dependence of the number of pads on conversion efficiency was observed experimentally.fficiency was observed experimentally.

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The Optical Novelty Filter Using a Self-pumped Phase Conjugator and LCTV (자기펌핑 위상공액경과 액정TV를 이용한 Novelty 필터)

  • 문영훈;이권윤;백남식;박한규
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.29A no.4
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    • pp.14-21
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    • 1992
  • An optical novelty filter is implemented using photorefractive materal(BaTiO$_{3}$) as a recording materal and commercial liquid crystal TV as a spatial light polarization modulator. If a signal beam incident at the proper, the loop and the crossing angle inside th e crystal is formed to get maximum diffraction efficiency and BaTiO$_{3}$ as a self-pumped phase conjugation mirror show that phase conjugate reflectivity was 20 times as much as ordinary polarization if signal beam is extraordinary. In this paper, the stoke's theorem which is a reciprocal theorem for which is a reciprocal theorem for beam path is experimentally proved, and good output images were obtained with optical experiment of novelty filter which is formed by use of Michelson interferometer.

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