• Title/Summary/Keyword: polarity shift

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Studies on the Natural Dyes(10) -Dyeing properties of safflower yellow for silk fibers- (天然染料에 관한 硏究(10) -홍화 황색소의 견섬유에 대한 염색성-)

  • Cho, Kyung Rae
    • Textile Coloration and Finishing
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    • v.9 no.5
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    • pp.10-18
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    • 1997
  • In order to study the properties of safflower yellow colors, thermodynamic parameters and dyeing properties on the silk in several dyeing conditions were investigated. The uv-visible spectra of safflower yellow colors in several solvents show hypsochromic shift with the polarity of solvent but bathochromic shift with increasing acidity of solution. The apparent diffusion coefficients and standard affinities of dyeing increased with the increase of dyeing temperature. The standard heat of dyeing(${\Delta}H^0$), entropy change(${\Delta}S^0$) and activation energy($E_{act}$) were calculated to be - 1.144kcal/mol, -7.498(5$0^{\circ}C$)~-3.804(9$0^{\circ}C$)cal/molㆍdeg and 0.123kcal/mol, respectively. The concentration of safflower yellow colors in the silk fiber increased with dyeing temperature, time, concentration of colors and acidity of initial dyebath. Silk fabrics were dyed bright yellow by pre-mordanting with tin chloride. Lightfastness of silk fabrics pre-mordanted by tin chloride was not excellent.

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Study on Grid-Connected Photovoltaic System using Current-Source Inverter (전류형 인버터를 이용한 계통 연계형 태양광 발전 시스템에 관한 연구)

  • Lim, J.M.;Park, S.J.;Lee, S.H.;Moon, C.J.;Choi, J.H.
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.677-681
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    • 2005
  • This Paper presents a 6 pulse shift operation control mode of current-source-inverter to make improvement of efficiency and to reduce the frequency of inverter switching for photovoltaic generation system using PWM current-source-inverter. This system is connected solar cell energy directly without using a storage cell. The proposed circuit can maintain maximum voltage of photovoltaic generation of take advantage of six Buck-Boost converter and a full-bridge inverter determines the polarity of AC output. That is controlled by using digital signal processor TMS320F2812 for operation about a 6 pulse shift operation control of current-source-inverter, and it is verified through the experimental results.

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Fluorescence Spectroscopy Studies on Micellization of Poloxamer 407 Solution

  • Lee, Ka-Young;Shin, Sang-Chul;Oh, In-Joon
    • Archives of Pharmacal Research
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    • v.26 no.8
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    • pp.653-658
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    • 2003
  • It has been reported that at low temperature region, poloxamers existed as a monomer. Upon warming, an equilibrium between unimers and micelles was established, and finally micelle aggregates were formed at higher temperature. In this study, the fluorescence spectroscopy was used to study the micelle formation of the poloxamer 407 in aqueous solution. The excitation and emission spectra of pyrene, a fluorescence probe, were measured as a function of the concentration of poloxamer 407 and temperature. A blue shift in the emission spectrum and a red shift in the excitation spectrum were observed as pyrene transferred from an aqueous to a hydrophobic micellar environment. From the $I_1/I_3 and I_{339}/I_{333}$ results, critical micelle concentration (cmc) and critical micelle temperature (cmt) were determined. Also, from the fluorescence spectra of the probe molecules such as 8-anilino-1-naphthalene sulfonic acid and 1-pyrenecarboxaldehyde, the blue shift of the $\lambda_{max}$ was observed. These results suggest a decrease in the polarity of the microenvironment around probe because of micelle formation. The poloxamer 407 above cmc strongly complexed with hydrophobic fluorescent probes and the binding constant of complex increased with increasing the hydrophobicity of the probe.

Effects of Remanent Polarization State and Internal Field in Ferroelctric Film on the Hydrogen-induced Degradation Characteristics in Pt/Pb(Zr, Ti)O3/Pt Capacitor (강유전막의 잔류 분극 상태와 내부 전계가 Pt/Pb(Zr,Ti)O3/Pt 커패시터의 수소 열화 특성에 미치는 영향)

  • Kim, Dong-Cheon;Lee, Gang-Un;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.75-81
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    • 2002
  • The ferroelectric properties of Pb(Zr,Ti)O$_3$[PZT] films degrade when the films with Pt top electrodes are annealed in hydrogen containing environment. This is due to the reduction activity of atomic hydrogen that is generated by the catalytic activity of the Pt top electrode. At the initial stage of hydrogen annealing, oxygen vacancies are formed by the reduction activity of hydrogen mainly at the vicinity of top Pt/PZT interface, resulting in a shift of P-E (polarization-electric field) hysteresis curve toward the negative electric field direction. As the hydrogen annealing time increases, oxygen vacancies are formed inside the PZT film by the inward diffusion of hydrogen ions, as a result, the polarization degrades significantly and the degree of P-E curve shift decreases gradually. The direction and the magnitude of the remnant polarization in the PZT film affect the motion of hydrogen ions which determines the degradation of polarization characteristics and the shift in the P-E hysteresis curve of the PZT capacitor during hydrogen annealing. When the remnant polarization is formed in the PZT film by applying a pre-poling voltage prior to hydrogen annealing, the direction of the P-E curve shift induced by hydrogen annealing is opposite to the polarity of the pre-poling voltage. The hydrogen-induced degradation behavior of the PZT capacitor is also affected by the internal field that has been generated in the PZT film by the charges located at the top interface prior to hydrogen annealing.

Apolar growth of Neurospora crassa leads to increased secretion of extracellular proteins

  • Lee, In-Hyung;Rodney G. Walline;Michael Plamann
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 2000.04a
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    • pp.78-89
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    • 2000
  • Protein secretion in filamentous fungi has been shown to be restricted to actively growing hyphal tips. To determine whether an increase in the amount of growing surface area of a fungus can lead to an increase in the amount of protein secretion, we examined secretion in a temperature-sensitive Neurospora crassa mcb mutant that shows a loss of growth polarity when incubated at restrictive-temperature. Incubation of the mcb mutant at restrictive-temperature results in a three- to five-fold increase in the level of extracellular protein and a 20- fold increase in carboxymethyl cellulase activity relative to a wild-type strain. A mutation in the cr-l gene has been shown previously to suppress the apolar growth phenotype of the mcb mutant, and we find that the level of extracellular protein produced by a mcb; cr-l double mutant was reduced to that of the wild-type control. Immunolocalization of a secreted endoglucanase revealed that proteins are secreted mainly at hyphal tips in hyphae exhibiting polar growth and over the entire surface area of bulbous regions of hyphae that are produced following a shift of the mcb mutant to restrictive-temperature. These results support the hypothesis that secretion of extracellular protein by a filamentous fungus can be significantly increased by mutations that alter growth polarity.

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A Study on 6-pulse-shift Current-source PWM Inverter for Photovoltaic System (태양광발전을 위한 6-pulse-shift 전류형 인버터에 관한 연구)

  • Lim, Joung-Min;Lee, Sang-Hun;Park, Sung-Jun;Moon, Chae-Joo;Chang, Young-Hak;Lee, Man-Hyung
    • The Transactions of the Korean Institute of Power Electronics
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    • v.11 no.3
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    • pp.193-200
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    • 2006
  • This paper suggests a 6-pulse-shift converter structure with PWM current-source inverter based on buck-boost configuration to improve the efficiency and to reduce the switching frequency of inverter for photovoltaic generation system, the device can be operated as interface system between solar module system and power system grid without energy storage cell. The circuit has six current-source buck-boost converter which operate chopper part and kas one full bridge inverter which make a decision the polarity of AC output. Therefore, the proposed PWM power inverter has advantages such as the reduction of witching loss and realization of unity power factor operation. The theoretical backgrounds are discussed and the input-output characteristics for the implemented prototype inverter using TMS320F2812 are verified experimentally in this paper.

Electro-optical devices from polymer-stabilized liquid crystals with molecular shape polarity

  • Kim, Sang-Hwa;Chien, Liang Chy;Komitov, Lachezar
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.839-842
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    • 2004
  • We present a fast-switching electro-optical device based on flexoelectro-optic effect in short pitch cholesterics oriented in uniform lying helix texture. The device has two operating modes: amplitude and phase modulation mode. The amplitude modulation mode is a fast in-plane switching of the device optic axis that enables to achieve a high percent of modulation of the transmitted light intensity whereas the phase mode gives a continuous change of the refractive index and thus of the phase shift of the transmitted light. By using a small concentration of diacrylate monomer and selecting the illumination conditions we have been able to create a inhomogeneous polymeric network mostly localized at both substrate surfaces and stabilize the two switching modes.

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Study on the Formation of SiOC Films and the Appropriate Annealing Temperature

  • Oh, Teresa
    • Journal of information and communication convergence engineering
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    • v.9 no.2
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    • pp.217-219
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    • 2011
  • As silicon devices shrink and their density increases, the low dielectric constant materials instead of $SiO_2$ film is required. SiOC film as low-k films was deposited by the capacitively coupled plasma chemical vapor deposition and then annealed at $300{\sim}500^{\circ}C$ to find out the properties of the dependence on the temperature and polarity. This study researched the dielectric constant using by the structure of the metal/SiOC film/p-Si, chemical shift, thickness, refractive index and hardness. The trend of reflective index was inverse proportioned the thickness, but the dielectric constant was proportioned it. The dielectric constant decreased with decreasing the thickness and the increment of the refractive index.

Placement inspection of the SMT components using 3-D vision (시각센서를 이용한 SMT 부품장착상태 검사)

  • 손영탁;오형렬;윤한종
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.605-608
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    • 1996
  • The aim of this thesis is to develop a SMT-components placement inspection system equipped with a visual sensor. The visual sensor, which consists of a camera and 2-layer LED illuminator, developed to inspect the component placement state such as missing, shift, flipping, polarity and tomb-stone. on PCB in the reflow-process. In practical applications, however, it is too hard to classify component from images mixed pad on PCB, cream solder paste and component. To overcome the problem, this thesis proposes the 2-layer illumination method and the heuristic image processing algorithms according to inspection type. To show the effectiveness of the proposed approach, a series of experiments on the inspection were conducted. The results show that the proposed method is robust to visual noise and variations in component conditions.

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Capacitance-Voltage Characteristics of MIS Capacitors Using Polymeric Insulators

  • Park, Jae-Hoon;Choi, Jong-Sun
    • Journal of Information Display
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    • v.9 no.2
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    • pp.1-4
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    • 2008
  • In this study, we investigate the capacitance-voltage (C-V) characteristics of metal-insulator-semiconductor (MIS) capacitors consisting of pentacene, as an organic semiconductor, and polymeric insulators such as poly(4-vinylphenol) (PVP) orpolystyrene (PS) prepared by spin-coating process, to analyze the interfacial characteristics between pentacene and polymeric insulators. Compared with the device with PS, the MIS capacitor with PVP exhibited a pronounced shift in the flat-band voltage according to the bias sweep direction. This hysteric feature in the C-V characteristics is thought to be attributed to the trapped charges at the interface between pentacene and PVP owing to the hydrophilicity of PVP. From the experimental results, we can conclude that surface polarity of polymeric insulator has a critical effect on the interfacial properties, thereby affecting the bias stability of organic thin-film transistors.