• Title/Summary/Keyword: point defects

Search Result 497, Processing Time 0.028 seconds

Optical Bleaching Behaviour of Neutron Irradiated KCI Single Crystal

  • Suh, In-Suck
    • Nuclear Engineering and Technology
    • /
    • v.5 no.4
    • /
    • pp.286-290
    • /
    • 1973
  • Hydroxide free KCI single crystals are prepared and doped with samall amounts of KSH or $K_2$S. The samples are subjected to neutron irradiations while keeping them under the condition of liquid nitrogen temperature in the dark. The irradiated ones are then bleached by using a U.V. lamp and analysed as four different kinds of chemical forms in $^{35}$ S whose valence states are -2, 0, +4 and +6. It semms that the sulphide fraction of $^{35}$ S in doped crystals is higher than that in pure crystals. In addition, two distinct patterns in bleaching process up to 30 minutes results in a fast increase in the sulphide fraction and then the sulphide levels off to a slowly increasing region upon prolonged bleaching. A detailed description on the distribution of $^{35}$ S valence states will be made in connection with point defects in the crystals.

  • PDF

Enhanced Photocurrent from CdS Sensitized ZnO Nanorods

  • Nayak, Jhasaketan;Son, Min-Kyu;Kim, Jin-Kyoung;Kim, Soo-Kyoung;Lee, Jeong-Hoon;Kim, Hee-Je
    • Journal of Electrical Engineering and Technology
    • /
    • v.7 no.6
    • /
    • pp.965-970
    • /
    • 2012
  • Structure and optical properties of cadmium sulphide-zinc oxide composite nanorods have been evaluated by suitable characterization techniques. The X-ray diffraction spectrum contains a series of peaks corresponding to reflections from various sets of lattice planes of hexagonal ZnO as well as CdS. The above observation is supported by the Micro-Raman spectroscopy result. The optical reflectance spectra of CdS-ZnO is compared with that of ZnO where we observe an enhanced absorption and hence diminished reflection from CdS-ZnO compared to that from only ZnO. A very small intensity of the visible photoluminescence peak observed at 550 nm proves that the ZnO nanorods have very low concentrations of point defects such as oxygen vacancies and zinc interstitials. The photocurrent in the visible region has been significantly enhanced due to deposition of CdS on the surface of the ZnO nanorods. CdS acts as a visible sensitizer because of its lower band gap compared to ZnO.

Study on the Optimization of HSS STI-CMP Process (HSS STI-CMP 공정의 최적화에 관한 연구)

  • Jeong, So-Young;Seo, Yong-Jin;Park, Sung-Woo;Kim, Chul-Bok;Kim, Sang-Yong;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.05c
    • /
    • pp.149-153
    • /
    • 2003
  • Chemical mechanical polishing (CMP) technology for global planarization of multi-level inter-connection structure has been widely studied for the next generation devices. CMP process has been paid attention to planarized pre-metal dielectric (PMD), inter-layer dielectric (ILD) interconnections. Expecially, shallow trench isolation (STI) used to CMP process on essential. Recently, the direct STI-CMP process without the conventional complex reverse moat etch process has established by using slurry additive with the high selectivity between $SiO_2$ and $Si_3N_4$ films for the purpose of process simplification and n-situ end point detection(EPD). However, STI-CMP process has various defects such as nitride residue, tom oxide and damage of silicon active region. To solve these problems, in this paper, we studied the planarization characteristics using a high selectivity slurry(HSS). As our experimental results, it was possible to achieve a global planarization and STI-CMP process could be dramatically simplified. Also we estimated the reliability through the repeated tests with the optimized process conditions in order to identify the reproducibility of HSS STI-CMP process.

  • PDF

The Cu-CMP's features regarding the additional volume of oxidizer (산화제 배합비에 따른 연마입자 크기와 Cu-CMP의 특성)

  • Kim, Tae-Wan;Lee, Woo-Sun;Choi, Gwon-Woo;Seo, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.07a
    • /
    • pp.20-23
    • /
    • 2004
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing(CMP) process was required for the global planarization of inter-metal dielectric(IMD) layer with free-defect. However, as the IMD layer gets thinner, micro-scratches are becoming as major defects. Chemical-Mechanical polishing(CMP) of conductors is a key process in Damascene patterning of advanced interconnect structure. The effect of alternative commercial slurries pads, and post-CMP cleaning alternatives are discuss, with removal rate, scratch dentisty, surface roughness, dishing, erosion and particulate density used as performance metrics. Electroplated copper deposition is a mature process from a historical point of view, but a very young process from a CMP perspective. While copper electro deposition has been used and studied for decades, its application to Cu damascene wafer processing is only now gaining complete acceptance in the semiconductor industry. The polishing mechanism of Cu-CMP process has been reported as the repeated process of passive layer formation by oxidizer and abrasion action by slurry abrasives. however it is important to understand the effect of oxidizer on copper passivation layer in order to obtain higher removal rate and non-uniformity during Cu-CMP process. In this paper, we investigated the effects of oxidizer on Cu-CMP process regarding the additional volume of oxidizer.

  • PDF

A Study point defect for thermal annealed ZnSe/GaAs epilayer

  • Hong, Kwang-Joon;Lee, Sang-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.11a
    • /
    • pp.120-123
    • /
    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, $I_2$ ($D^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3 meV. The exciton peak, $I_1^d$, at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The $I_1^d$ peak was dominantly observed in the ZnSe/GaAs:Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs:Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a $(V_{Se}-V_{Zn})-V_{Zn}$.

  • PDF

An innovative idea for developing a new gamma-ray dosimetry system based on optical colorimetry techniques

  • Ioan, Mihail-Razvan
    • Nuclear Engineering and Technology
    • /
    • v.50 no.3
    • /
    • pp.519-525
    • /
    • 2018
  • Obtaining knowledge of the absorbed dose up-taken by a certain material when it is exposed to a specific ionizing radiation field is a very important task. Even though there are a plenitude of methods for determining the absorbed dose, each one has its own strong points and also drawbacks. In this article, an innovative idea for the development of a new gamma-ray dosimetry system is proposed. The method described in this article is based on optical colorimetry techniques. A color standard is fixed to the back of a BK-7 glass plate and then placed in a point in space where the absorbed dose needs to be determined. Gamma-ray-induced defects (color centers) in the glass plate start occurring, leading to a degree of saturation of the standard color, which is proportional, on a certain interval, to the absorbed dose. After the exposure, a high-quality digital image of the sample is taken, which is then processed (MATLAB), and its equivalent $I_{RGB}$ intensity value is determined. After a prior corroboration between various well-known absorbed dose values and their corresponding $I_{RGB}$ values, a calibration function is obtained. By using this calibration function, an "unknown" up-taken dose value can be determined.

A study on Defect Diagnosis of Gas Turbine Engine Using Hybrid SVM-ANN in Off-Design Region

  • Seo, Dong-Hyuck;Choi, Won-Jun;Roh, Tae-Seong;Choi, Dong-Whan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2008.03a
    • /
    • pp.72-79
    • /
    • 2008
  • The weak point of the artificial neural network(ANN) is that it is easy to fall in local minima when it learns too much nonlinear data. Accordingly, the classification ratio must be low. To overcome this weakness, the hybrid method has been proposed. That is, the ANN learns data selectively after detecting the defect position by the support vector machine(SVM). First, the SVM has been used for determination of the defect position and then the magnitude of the defect has been measured by the ANN. In off-design condition, the operation region of the engine is wide and the nonlinearity of learning data increases. The module system, dividing the whole operating region into reasonably small-size sections, has been suggested to solve this problem. In this study, the proposed algorithm has diagnosed the defects of triple components as well as single and dual components of the gas turbine engine in off-design condition.

  • PDF

Performance of Adhesives in Glulam after Short Term Fire Exposure

  • Quiquero, Hailey;Chorlton, Bronwyn;Gales, John
    • International Journal of High-Rise Buildings
    • /
    • v.7 no.4
    • /
    • pp.299-311
    • /
    • 2018
  • As engineered timber such as Glulam is seeing increasing use in tall timber buildings, building codes are adapting to allow for this. In order for this material to be used confidently and safely in one of these applications, there is a need to understand the effects that fire can have on an engineered timber structural member. The post-fire resilience aspect of glulam is studied herein. Two sets of experiments are performed to consider the validity of zero strength guidance with respect to short duration fire exposure on thin glulam members. Small scale samples were heated in a cone calorimeter to different fire severities. These samples illustrated significant strength loss but high variability despite controlled quantification of char layers. Large scale samples were heated locally using a controlled fuel fire in shear and moment locations along the length of the beam respectively. Additionally, reduced cross section samples were created by mechanically carving a way an area of cross section equal to the area lost to char on the heated beams. All of the samples were then loaded to failure in four-point (laterally restrained) bending tests. The beams that have been burnt in the shear region were observed as having a reduction in strength of up to 34.5% from the control beams. These test samples displayed relatively little variability, apart from beams that displayed material defects. The suite of testing indicated that zero strength guidance may be under conservative and may require increasing from 7 mm up to as much as 23 mm.

Phase-field simulation of radiation-induced bubble evolution in recrystallized U-Mo alloy

  • Jiang, Yanbo;Xin, Yong;Liu, Wenbo;Sun, Zhipeng;Chen, Ping;Sun, Dan;Zhou, Mingyang;Liu, Xiao;Yun, Di
    • Nuclear Engineering and Technology
    • /
    • v.54 no.1
    • /
    • pp.226-233
    • /
    • 2022
  • In the present work, a phase-field model was developed to investigate the influence of recrystallization on bubble evolution during irradiation. Considering the interaction between bubbles and grain boundary (GB), a set of modified Cahn-Hilliard and Allen-Cahn equations, with field variables and order parameters evolving in space and time, was used in this model. Both the kinetics of recrystallization characterized in experiments and point defects generated during cascade were incorporated in the model. The bubble evolution in recrystallized polycrystalline of U-Mo alloy was also investigated. The simulation results showed that GB with a large area fraction generated by recrystallization accelerates the formation and growth of bubbles. With the formation of new grains, gas atoms are swept and collected by GBs. The simulation results of bubble size and distribution are consistent with the experimental results.

Some Considerations on Developments in Reliabili~ Maintainability and Manning Indices for Engine Systems During the Past 30 Years in Japan - and the Future (일본의 과거 30년간 박용기관시스템의 신뢰성, 정비성 및 매닝인덱스의 발전에 대한 소고와 그 장래)

  • Hashimoto, T.;Harada, T.;Kume, K.
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.17 no.5
    • /
    • pp.18-32
    • /
    • 1993
  • A marine engine system (MES) should be evaluated by not only reliability (R) but also maintainability (M) and manning index (MI), because this system can be recognised as a typical man-machine system. In 1977 at the first ICMES Conference in Paris one of the authors presented a total evaluation of the MES with the three indices, R, M, MI, proving the human ability of detecting faults and defects in this system. This paper describes how the MES has developed from the point of view of the above three indices during the past 30 years in Japan and its problems in the future, and arrives at the following conclusions : the reliability of the MES has developed due to quality control (QC) ; the maintainability of the MES has improved due to education and training ; the manning index of the MES has improved due to Rand M ; the availability of the MES has kept constant due to the decreasing complement onboard, at the rate of one person per year approximately ; and two esimations having the three indices were shown by the SRIC 1990 Data Base in Japan, for the two kinds of subsystems in the developed MES.

  • PDF