• 에너지공학
• /
• 제19권4호
• /
• pp.221-227
• /
• 2010

본 연구에서는 바이오매스 및 플라스틱에 가스화 효율을 높이기 위한 탄산염 촉매 또는 Ni based 촉매를 혼합한 시료에 대하여, 고정층 반응기를 이용하여 급속 등온 열분해 실험을 수행하여, 생성된 가스의 온도, 시료 및 촉매의 영향에 관한 분석을 통하여, 최적의 수소 생성 수율을 얻고자 한다. 고위발열량 측정 결과, 바이오매스보다 플라스틱 폐기물의 발열량이 높아짐을 알 수 있었다. 원소분석 결과로부터 수소 함량은 플라스틱 시료가 더 높았다. 계산된 활성화 에너지는 촉매 적용에 의해 감소하였고, 5 wt% 이상의 경우에는 큰 변화를 보이지 않았다. 수소수율은 플라스틱 폐기물이 포함된 시료, 온도에 대해서는 대부분 높은 온도 범위에서 최대값이 얻어졌다. 또한 대부분의 시료에서 높은 혼합비를 갖는 조건의 수소수율이 가장 높은 결과를 보였으나, 5 wt% 이상의 조건에서는 촉매 혼합비 증가의 영향은 미비하여, 활성화 에너지의 결과와 잘 일치함을 확인하였다. 전체적으로 촉매 반응이 무촉매 반응에 비하여 높은 수소수율이 얻어졌다. 촉매 종류에 대하여, 탄산염 촉매인 $Na_2CO_3$ 및 $K_2CO_3$보다 Ni-$ZrO_2$ 촉매가 수소 생산을 위한 목적에 더 적합한 촉매임을 확인하였고, 본 연구로부터의 최대 수소수율을 위한 조건은 $900^{\circ}C$, 20 wt%의 Ni-$ZrO_2$(1:9) 촉매가 혼합된 Pitch Pine, Polyethylene 시료에 대하여 65.9 vol%의 높은 수소수율의 결과를 얻었다.

• 자원리싸이클링
• /
• 제29권6호
• /
• pp.88-97
• /
• 2020

본 연구는 시멘트 소성 공정에 사용되는 선별된 폐플라스틱 페기물류를 선별 및 파분쇄 공정을 거쳐 2종으로 분류하여 그에 따른 각각의 특성을 분석하고, 이를 기반으로 시멘트 소성 후의 강도에 대한 상관관계를 분석한 연구이다. 실험 변수로는 연질과 경질 폐플라스틱 폐기물로 분류하였으며 그에 따른 발열량, 염소, 수분 등의 상관관계를 분석하였다. 또한 각 폐기물 중 일부를 채택하여 용융시킨 후 조직 및 발열량을 분석하여 기초 특성을 평가하였다. 실험 결과 시멘트 소성에 사용되기 위해서는 연질 폐플라스틱 폐기물류 분리시키고 그 중 유사한 특성을 갖는 소재로 소성하는 것이 열원을 얻기에 적합한 것으로 평가되었다. 시멘트 소성 후의 강도별로 폐기물류에 대해 검토한 결과 경질 플라스틱류의 사용은 1일 및 28일 압축강도에 크게 기여하며, 연질 플라스틱류의 사용은 28일 압축강도에 기여하는 것으로 분석되었다. 그러나 이런 특성들은 폐기물을 일부만 채취하여 평가한 것으로 폐기물의 편차가 발생하기에 지속적인 관리가 필요하며 폐기물의 사용에 따른 환경적 문제에 대한 후속 연구가 요구된다.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
• /
• pp.155-160
• /
• 2007

This study was conducted to find out the chlorine removal characteristics of waste plastic mixture by pyrolysis process with thermogravimetric analysis(TGA) and a lab-scale pyrolyzer. The material used as plastic wastes were PE (Poly-ethylene), PP (Poly-prophylene), and PVC (Poly Vinyl Chloride). Experimental procedure were composed of three steps; 1st step: TGA of PVC, PP and PE, 2nd step: chlorine removal rate of PVC in a lab-scale pyrolyzer, 3rd step: chlorine removal rate of PVC-PE and PVC-PP mixture in a pyrolyzer. Through the results of TGA, we can estimate the basic pyrolysis characteristics of each plastic, and then we can also derive the design parameters and operating conditions of the lab-scale pyrolyzer. The results can be used as primary data for designing a system to produce RPF (Refuse Plastic Fuel), a waste incinerator and a pyrolysis/gasification process.

• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.214-214
• /
• 2006

The huge amounts of wastes were produced nowadays. Among the solid waste stream, the waste plastic portion is about 20 % in weight, over 50 % in volume. But the most of waste plastics were incinerated or land filled. Only a bit of waste plastics were recycled and reused. On the view point of current energy crisis, this will be an extravagance of beneficial resource. So we should consider the waste plastics as a beneficial raw material. Also need to develop the field of reusing and recycling of post-consumed plastic. In this context, present paper describes the methodology for enhancing or improving the specific properties by way of using inorganic filler waste. Also develop the product from these post-consumed plastic.

• 한국건설순환자원학회논문집
• /
• 제8권3호
• /
• pp.317-324
• /
• 2020

플라스틱은 우수한 물성과 가공성 및 경제성으로 소비가 급증하고 있는 반면에, 분리, 선별이 제대로 이루어지고 있지 않아 재활용률이 저조한 실정이다. 특히, 생활폐기물 발생 폐플라스틱은 이물질과 혼합배출로 분리, 선별 공정 비용이 증가하여 재활용이 상대적으로 저조한 실정이다. 이에 본 연구는 생활폐기물 발생 복합 폐플라스틱을 콘크리트용 골재로 재활용하기 위한 기초 연구로 폐플라스틱 종류(복합재질 1종류 및 단일 재질 2종류) 및 치환율(잔골재 용적 대비 25%, 50% 및 75%)에 따른 콘크리트 특성 변화를 실험적으로 평가하였다. 복합재질의 폐플라스틱 굵은 골재는 양호한 입도 분포로 부순 굵은 골재 대비 밀도는 낮고 흡수율은 높은 것으로 나타났다. 반면에, 단일재질의 폐플라스틱 잔골재는 균일한 크기의 입자로 구성되었으며 부순 잔골재 대비 밀도와 흡수율 모두 낮은 것으로 나타났다. 복합재질 굵은 골재 치환 콘크리트는 가장 많은 폐플라스틱 치환량에도 양호한 입도 분포로 재료 분리 현상이 발생하지 않았으며, 공기랑도 증가량도 적은 것으로 나타났다. 한편, 폐플라스틱 골재의 낮은 강도, 소수성으로 인한 시멘트 수화반응 억제, 폐플라스틱 골재와 시멘트 페이스트 사이의 낮은 부착력 등으로 폐플라스틱 골재 치환량이 증가함에 따라 콘크리트의 압축강도 및 휨강도는 감소하였으며, 입도 분포가 양호한 복합재질의 폐플라스틱 굵은 골재를 치환한 콘크리트의 압축강도 및 휨강도의 저하 정도가 상대적으로 작은 것으로 나타났다.

• Geomechanics and Engineering
• /
• 제8권1호
• /
• pp.53-66
• /
• 2015

Plastic wastes, particularly polyethylene terephthalate (PET) generated from used bottled water constitute a worldwide environmental issue. Reusing the PET waste for geotechnical applications not only reduces environmental burdens of handling the waste, but also improves inherent engineering properties of soil. This paper investigated factors affecting shear strength improvement of PET-mixed residual soil. Four variables were considered: (i) plastic content; (ii) plastic slenderness ratio; (iii) plastic size; and (iv) soil particle size. A series of unconfined compression tests were performed to determine the optimum configurations for promoting the shear strength improvement. The results showed that the optimum slenderness ratio and PET content for shear strength improvement were 1:3 and 1.5%, respectively. Large PET pieces (i.e., $1.0cm^2$) were favorable for fine-grained residual soil, while small PET pieces (i.e., $0.5cm^2$) were favorable for coarse-grained residual soil. Higher shear strength improvement was obtained for PET-mixed coarse-grained residual soil (148%) than fine-grained residual soils (117%). The orientation of plastic pieces in soil and frictional resistance developed between soil particles and PET surface are two important factors affecting the shear strength performance of PET-mixed soil.

• Geomechanics and Engineering
• /
• 제12권1호
• /
• pp.111-125
• /
• 2017

Swelling and shrinkage characteristics of expansive fine grained soil cause volumetric changes followed by distress and damage to the structures. Soil stabilization can be explained as the alteration of the soil properties by chemical, mechanical or any other means in order to enhance the engineering properties of the soil. Utilization of industrial wastes in soil stabilization is cost effective and environment friendly. This paper presents an experimental study on stabilization of expansive soil using industrial wastes, viz. fly ash and dolochar. The paper includes the evaluation of engineering properties like unconfined compressive strength and California bearing ratio (CBR) of expansive soil collected from Balasore district of Odisha stabilized with fly ash and dolochar in different proportions and to predict the influence of these additives on engineering properties and strength characteristics of expansive soil. Both fly ash and dolochar were found to increase the CBR and decrease many index properties such as liquid limit, plastic limit, plasticity index, swelling index and UCS, thus enhancing the strength parameters of expansive soil.

• 한국산업보건학회지
• /
• 제34권2호
• /
• pp.107-114
• /
• 2024

Objectives: This study was performed to evaluate the musculoskeletal symptoms of workers treating electronics industry waste at a recycling sorting plant by case survey. Methods: The musculoskeletal symptoms were investigated by conducting a survey targeting workers treating waste from the electronics industry. Through utilizing the ergonomic evaluation techniques such as RULA, REBA, and OWAS, the four tasks were divided into three detailed processes (sorting, movement, loading) and the work of workers was evaluated for a total of 12 processes. Results: As a result of the questionnaire survey on musculoskeletal symptom, 40% of workers answered that they had musculoskeletal disease symptoms, and the symptom sites were hands(30%), legs(20%), arms(10%), and shoulders(5%). Based on the results obtained from analysis through ergonomic evaluation techniques such as RULA, REBA, and OWAS, 75% of them were found to need improvement or follow-up immediately or immediately after the second stage or higher. As compared to REBA and OWAS, the RULA, which evaluates the upper limb in detail, has a higher score, and in the process of sorting and loading relatively light wastes such as paper and plastic, the waist is raised by repeating the work of bowing and stretching. Conclusions: The heavy wastes such as 200L drums were evaluated as having a low load on the elbows and wrists because body action was relatively lower than moving paper and plastic. In addition, the overall load score was evaluated lower in the moving work compared to the sorting or loading process.

• 한국전기전자재료학회논문지
• /
• 제33권4호
• /
• pp.310-314
• /
• 2020

Although waste oil derived fuel (WDF) production technology was developed under a government initiative ~10 years ago, it became stagnant owing to the small size of participating companies, residents' rejection of foul odor, and the nature of the technology for recycling waste that was avoided. However, this subject is under the spotlight again because of recent developments, such as garbage crisis. In particular, plastic is the most difficult waste to dispose of, with more than 4 million tons of plastic waste produced every year according to statistics from the Ministry of Environment. The most effective method for treating plastic waste is to produce WDF through low temperature thermal decomposition. The WDF includes several volatile ingredients that mostly limit the use of fuel for boilers, owing to safety concerns. In particular, flash point is legally stipulated because of secondary contamination in the distribution process and the risk of fire and explosion. It is required that external shipments (distribution) should be maintained in the range of at least 30~60℃ (excluding explosion prevention facilities) for diesel power generation. Therefore, this study seeks to find the flash point that is best suited to WDFs produced from plastic waste.

• 신재생에너지
• /
• 제4권2호
• /
• pp.81-86
• /
• 2008

Rotary kiln in cement work has been evaluated for a wide variety of organic wastes such as wood, used tyres, plastic wastes and automobile shredder residue (ASR). However the presence of chlorine hampers the use of ASR as fuel in rotary kiln. Therefore, the behavior characteristics of chlorine components in rotary kiln should be considered to develop an effective method for ASR treatment to recovery energy resources. The aim of this paper is to present the chlorine control system applied to a cement manufacturing process for ASR use as an alternative fuel. In this work, the simulation of bypass unit and cyclones for chlorine control in rotary kiln has been studied and compared with the operation results of field test.