• Proceedings of the Mineralogical Society of Korea Conference
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• 2000.05a
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• pp.24-24
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• 2000

We studied about petrological characteristics of the Bangeujin granite belongs to porphyritic biotite granite, petrogenesis of the enclaves in the granite and contact metamorphism of the sedimentary rock around the granite. The enclaves in the granite are concentrated in the eastern part of the Mipo fault but in the western part, these are rare. The enclaves can be divided into three types according to the petrographical characteristics. These three types are: (1) enclaves having few phenocrysts and fine grained igneous texture and ellipsoid is predominant; (2) enclaves similar In petrographical characteristics and having many phenocrysts considered as being originated from the granitic host rock; and (3) enclaves corresponding to granite in mode composition, having large phenocrysts and of which the matrix is corresponding to fine granular. First two types are correspond to mafic micro granular enclaves and the third is corresponds to felsic microgranular enclaves. In addition, the felsic microgranular enclaves capture the mafic microgranular enclaves. The fact that the compositions of biotite and plagioclase in the enclaves are nearly identical with those of biotite and plagioclase in the granitic host rock is considered as the results of supporting magma mingling. The major elements show well the linear variations as the SiOz$.$ content increases. The rare earth elements content decrease with increasing SiOz content, interpreted as the results of magma mingling. Therefore, we can conclude that the Bangeujin granite captured the felsic microgranular enclaves formed by collapse of early chilled margin during the crystallization and there was magma mingling by the injection of the mafic magma after that time. In addition, these aspects are predominant in the eastern part of the Mipo fault is considered as related to the fault movement.vement.

• Journal of the Mineralogical Society of Korea
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• v.17 no.2
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• pp.177-187
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• 2004

Measurements of the lattice parameters of albite and oligoclase from electron diffraction patterns with the Au internal standard resulted in errors of less than 1 %. An electron diffraction map for natural oligoclase samples was constructed and 11 stations of zone-axes diffraction patterns were obtained. This process is indispensible for reliable TEM studies of triclinic feldspars. Utilizing the [001] cleavage plane of feldspar and the double-tilting TEM holder the following information is obtainable: Si-Al ordering and chemistry of alkali feldspars could be estimated from the $\alpha$＊ - ＊ plot, where ＊ is measured from the [001] orientation, while $\alpha$＊ is measured from the [100] orientation. Si-Al ordering of Na-rich plagioclase could be estimated from ＊ [001] patterns. Structure and chemistry or Na-poor plagioclase could be estimated from existence of e-reflections, their intensity variations as well as their positional changes.

• Journal of the Mineralogical Society of Korea
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• v.31 no.2
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• pp.103-111
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• 2018

Mineralogical properties of two Asian dust (Hwangsa) samples collected during dust events in April 6 and 15, 2018 were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD analyses showed that Asian dusts were dominated by phyllosilicates (62 wt%) comprising illite-smectite series clay minerals (ISCMs) (55%), chlorite (3%) and kaolinite (4%). Nonphyllosilicate minerals were quartz (18%), plagioclase (9%), K-feldspar (3%), calcite (3%), and gypsum (2-4%). Mineral compositions determined by SEM chemical analyses were consistent with XRD data. ISCMs occur as submicron grains forming aggregate particles or coating coarse mineral grains such as quartz, plagioclase, K-feldspar, chlorite, and calcite. The ISCMs are often associated with calcite nanofibers and gypsum blades. Mineralogical properties of 2018 dusts were similar to those of previous dusts although clay contents were higher than that of coarse 2012 dust.

• Economic and Environmental Geology
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• v.21 no.2
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• pp.171-174
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• 1988

A muscovite and a sericite altered from plagioclase taken from the Sungyeong tin-bearing pegmatite near the Sangdong mine are dated by K-Ar method. The muscovite and the sericite yield $1546.94{\pm}29.4\;Ma$ and $187.80{\pm}4.19\;Ma$,respectively. The muscovite age can be assumed to become younger than the previously reported K-Ar muscovite ages of the pegmatites around this area, because radiogenic argon in the muscovite could be partially lost by the heat of later hydrothermal activities which caused the plagioclase to be sericitized in the Jurassic time (about 190 Ma).

• Economic and Environmental Geology
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• v.7 no.3
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• pp.123-152
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• 1974

The study focused to the so called "Yangpyeong Igneous Complex" which intruded into the Gyeong Gi gneiss complex of Pre-cambrian basement of Yangpyeong area. The geologic sequence of the mapped area was shown in table 1. In laboratory work, 31 modal analyses and 7 chemical analyses on the rock samples taken from the igneous complex have been made to discuss the nomenclature of the rocks and the petrological relationship between rock types. The petrographical and petrochemical features based on the analyses are as follow; 1) The classification of this rocks based on the systematics of igneous rocks of IUGS showed that Yangpyeong Igneous complex consist of hornblende gabbro, diorite and porphyritic monzonite. The major rock forming minerals in hornblende gabbro are hornblende and plagiodase ($An_{46{\sim}55}$), in diorite, hornblende, biotite and plagioclase ($An_{23{\sim}33}$) and in porphyritic monzonite, K-feldspar, plagioclase ($An_{21{\sim}35}$), hornblende and biotite. Hornblende gabbro and diorite show coarse to medium grained hypidiomorphic granular texture and porphyritic monzonite was named by the characteristically porphyritic texture of K-feldspar phenocrysts. 2) Silica-oxides variation diagram (Fig.4) illustrate that the igneous complex is similar ttl that of Daly's average basalt-andesite-dacite-rhyolite and equivalent to the calc-alkalic rock series of Peacock's rock series. In AMF diagram (Fig. 5), the trend of the igneous complex is nearly pararell to that of the Skaergaard intrusion which shows the trend of the fractional crystalization of magma. 3) In normative Or-Ab-An diagram (Fig. 6) the general trend of the data points from gabbro to porphyritic monzonite of the igneous complex directs to a point of Or/Ab=1:1 on the side of Or-Ab. The field and laboratory evidences suggested that the Yangpyeong igneous complex was thought to be a series of comagmatic differential products.

• Economic and Environmental Geology
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• v.27 no.4
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• pp.387-396
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• 1994

Mineralogical and geochemical studies on gold-bearing quartz veins and wallrock from the Mugeug mine were carried out in order to investigate the variation of mineralogical composition and the geochemical behavior of elements with distance from the gold-bearing quartz veins. Gold-bearing quartz veins occur in early Cretaceous medium- to coarse-grained biotite granite. The unaltered wallrock is composed mainly of quartz, plagioclase, orthoclase, microcline, biotite and hornblende with accessory minerals of sphene and apatite. Mineralogical changes in altered wallrock around the gold-bearing quartz veins were observed as follows; 1) biotite and hornblende altered into chlorite, and next to sericite, 2) plagioclase, orthoclase and microcline altered into sericite, and 3) calcite and quartz introduced into wallrock. Contents of $K_2O$, Rb, Cs, Au, As and Sb in altered wallrock increase, whereas those of $Na_2O$, CaO, Ba, and Sr decrease with proximity to the gold-bearing quartz veins. The loss on ignition also increases with the increase of alteration mineral. The width of primary dispersion increases in order $Au=SiO_2<As=Cs=Rb<K_2O=Sb$ and $MnO<Na_2O=CaO=Ba<Sr$. The sericitization index, $K_2O/(K_2O+Na_2O)$, is an important indicator to interpret the degree of alteration at the Mugeug mine, which is more than 0.8 in strongly and moderately altered granite, 0.5~0.8 in wea altered granite, and less than 0.5 in unaltered granite. Alteration indices for major and trace elements, and the ratio of Rb/Sr are also useful to discriminate alteration zones.

• Economic and Environmental Geology
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• v.56 no.3
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• pp.259-275
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• 2023

Pan African granitoids of Kaiama is comprised of K-feldspar rich granites, porphyritic granites, and granitic gneiss that are intruded by quartz veins and aplitic veins and dykes which trend NE-SW. In order to establish the geochemical signatures, petrogenesis, and tectonic settings of the lithological units, petrological, petrographical, and geochemical studies was carried out. Petrographic analysis reveals that the granitoids are dominantly composed of quartz, plagioclase feldspar, biotite, and k-feldspar with occasional muscovites, sericite, and opaque minerals that constitute very low proportion. Major, trace, and rare earth elements geochemical data reveal that the rocks have moderate to high silica (SiO₂=63-79.7%) and alumina (Al₂O₃=11.85-16.15) contents that correlate with the abundance of quartz, feldspars, and biotite. The rocks are calc-alkaline, peraluminous (ASI=1.0-<1.2), and S-type granitoids sourced by melting of pre-existing metasedimentary or sedimentary rocks containing Al, Na, and K oxides. They plot dominantly in the WPG and VAG fields suggesting emplacement in a post-collisional tectonic setting. On a multi-element variation diagram, the granitoids show depletion in Ba, K, P, Rb, and Ti while enrichment was observed for Th, U, Nd, Pb and Sm. Their rare-earth elements pattern is characterized by moderate fractionation ((La/Yb)_N=0.52-38.24) and pronounced negative Eu-anomaly (Eu/Eu^*=0.02-1.22) that points to the preservation of plagioclase from the source magma. Generally, the geochemical features of the granitoids show that they were derived by the partial melting of crustal rocks with some input from greywacke and pelitic materials in a typical post-collisional tectonic setting.

• The Journal of the Petrological Society of Korea
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• v.2 no.2
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• pp.74-94
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• 1993

Metabasites and metapelites in the Mungyong area were intruded by Cretaceous granites with radius of 4-8 km. As the distance from granite body increases, the mineral assemblage of metabasite changes from amphibole + plagioclase through amphibole + plagioclase + epidote to amphibole + plagioclase + epidote + chlorite. The compositional variations of amphibole and plagioclase according to the change of metamorphic grade and bulk rock compositions are very complex. Towards the Mungyong Cretaceous granite body, the mineral assemblage of metapelite changes from chlorite+ muscovite(ch1orite zone) through biotite + chlorite + muscovite(biotite zone) to andalusite+biotite + muscovite${\pm}$chlorite or cordierite+ biotite+ muscovite${\pm}$chlorite(cordierite zone). The estimated metamorphic conditions of cordierite zone are 480~$580^{\circ}C$ 1.5-3.3 kb. The theoretical study on the thermal metamorphism caused by the Cretaceous granite with radius longer than 4 km in the Mungyong area suggests the followings: The degree of metamorphism is mainly determined not by the size of granite body but by the temperature of granite intrusion; The country rocks within 2 km from Cretaceous granite have undergone metamorphism with temperature higher than $500^{\circ}C$, which is consistent with the petrological study in the Mungyong area. Mungyong Cretaceous granite caused a low P/T thermal metamorphism to the country rocks; the amphibolite facies metamorphism to the country rocks within 1-2 km from the granite body and the epidote-amphibolite and greenschist facies metamorphism to the country rocks within 2-5 km.

• Economic and Environmental Geology
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• v.4 no.4
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• pp.167-215
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• 1971

I. Purpose and Importance of the Study The purpose of the present study is to clarify to geological, mineralogical, and physico-chemical properties of the clay minerals deposits imbedded in the Tertiary sediments in the areas between. Pohang and Ulsan along southeastern coastal region of Korea. These clays are being mined and utilized for filter and insecticide after activation or simple pulverizing, nontheless activated clays are short coming as chemical industry in Korea has been rapidly grown in recent years. In spite of such increase in clay demand, no goological investigation on clay deposits nor physico-chemical properties of the clays have been carried out up to date. Consequently activated clays produced in Korea is not only of low grade but also of shortage in supply, so that Korea has to import activated clays of better grade. The importance of the present study lies, therefore, on that guiding principle could be laid down by knowing stratigraphical horizons, of clay deposits and fundamental data of improving grade of activated clays might be derived from the results of physico-chemical examinations. II. Contents and Scope of the study The contents of the study are pinpointed down in the following two subjects: 1) General geological investigation of Tertiary formations distributed in the areas between Pohang and UIsan, and detail geological study of the bentonitic clay deposits imbedded in them. 2) To clarifty physico-chemical characteristics of the clays by means of chemical analysis, X-ray diffraction and electron microscope. The scope of the study involves the following there points: i) Regional geological investigation-This investigation has been carried out in order to find out the distribution of Tertiary sediments and exact location of clay mineral deposits in the areas between Pohang and UIsan. ii) Detail geological investigation-This has been concentrated in and around the clay deposits which. had been found out by the regional investigation. iii) Laboratory researchs include i) age determination and correlation of Tertiary sediments by paleontological study, and ii) Chemical analysis, X-ray diffraction, and electron microscopic studies on clays, samples taken from various clay deposits. III. Research Results and Suggestions 1) The geology of the area investigated is composed mainly of Janggi and Beomgokri groups of Miocene age in ascending order rested on the upper Silla system, Balkuksa granite and volcanic rocks of upper Cretaceous age as base. 2) Janggi group is composed in ascending order of Janggi conglomerate, Nultaeri rhyolitic tuff, Keumkwangdong shale, two beds of lignite-bearing formations which consist of alternation of conglomerate, sandstone and mudstone, and andesitic, rhyolitic, and basaltic tuff beds. 3) Beomgokri group is mainly composed of andesitic to rhyolitic tuff interlayered by conglomerate and tuffaceous sandstone. In the areas around boundary between North-and South Kyeongsang-do is distributed Haseori farmation which is composed of conglomerate, sandstone, mudstone and andesitic to rhyolitic tuff, and which is correlated to Eoilri formation of Janggi group. 4) Clay deposits of the area are interbedded in Eoilri, Haseori, Nultaeri tuff, Keumkwangdong shale, upper and lower horizon of the lower lignite-bearing seam, and Keumori rhyolitic tuff formations of Janggi group; and are genetically classi.fied into four categories, that is, i) those derived from volcanic ash beds(Haseori and Daeanri deposits), ii) those of secondary residual type from rhyolitic tuff beds(Seokupri deposits), iii) Clay beds above and beneath the lignite seams, (Janggi and Keumkwangdong deposits), and iv) those derived from rhyolitic tuff beds(Sangjeong and Tonghae deposits). 5) Mineral constituents of clay deposits are, according to X-ray diffraction, montmorillonite accompanied in different degree by cristobalite, plagioclase, quartz, stilbite, and halloysite in rare occasion. The clays are grouped according to mineral composition into four types; i) those consist mostly of montmorillonite, ii) those composed of montmorillonite and cristobalite, iii) those composed of montmorillonite and plagioclase, and iv) those composed of montmorillonite, plagioclase and quartz. 6) Clays interbedded in Haseori formation and vicinity of lignite seams belong to the first type, are of good quality and derived either from volcanic ash bed, or primary clay beds near lignite seams. Clays belonged to other types are derived from weathering of rhyolitic tuff formations and their quality varies depending upon original composition and degree of weathering. Few clays in secondary residual type contain small amount of halloysite. 7) Judging from analytical data, content of silica($SiO_2$) varies proportionally with content of cristobalite, and alumina($Al_2O_3$) content does not vary with that of plagioclase, but increases in the sedimentary bedded type of deposits. 8) It is unknown whether or not these days could be upgraded by beneficiation since no grain size of these impurities nor beneficiation test had been studied. 9) Clay beds derived from valcanic ash layers or sedimentary layers at the vicinity of lignite seams are thin in thickness and of small, discontinueous lenticular shape, although they are of good quality; and those derived from rhyolitic tuff formations or residual type from tuff are irregular in both occurrence and quality. It is, therefore, not only very difficult but also meaningless to calculate its reserve, and reserve estimation, even if done, will greatly be deviated from practically minable one. Consequently, way of discovery and exploitation of clay deposits in the area under consideration is to check the geologically favorable areas whenever needed.

• Economic and Environmental Geology
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• v.2 no.2
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• pp.73-75
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• 1969

Ogbang scheelite deposit imbedded in amphibolite of unknown age was believed, by the previous workers, to be of pegmatite vein. The vein material is composed mainly of plagioclase (albite and oligoclase) and minor amount (less than 5 to 10% each) of hornblende, biotite and quartz. Orthoclose and tourmaline are accompanied in few places and scheelite and minor amount of fluorite, are the ore minerals. On the basis of mineralogical constituents of the vein, vein structures, mode of occurrence of the vein and gradational contact between veins and amphibolite, the present writer conclude that the deposit was formed by segregation from the parent basic igneous rock of amphibolite. The main portions of the deposit were formed by intrusion of ore solution into already solidified amphibolite after being segregated in deeper horizone, whereas the minor portion by segregation of ore solution in situ.