• Title/Summary/Keyword: physio-chemical

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Leveraging artificial intelligence to assess explosive spalling in fire-exposed RC columns

  • Seitllari, A.;Naser, M.Z.
    • Computers and Concrete
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    • v.24 no.3
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    • pp.271-282
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    • 2019
  • Concrete undergoes a series of thermo-based physio-chemical changes once exposed to elevated temperatures. Such changes adversely alter the composition of concrete and oftentimes lead to fire-induced explosive spalling. Spalling is a multidimensional, complex and most of all sophisticated phenomenon with the potential to cause significant damage to fire-exposed concrete structures. Despite past and recent research efforts, we continue to be short of a systematic methodology that is able of accurately assessing the tendency of concrete to spall under fire conditions. In order to bridge this knowledge gap, this study explores integrating novel artificial intelligence (AI) techniques; namely, artificial neural network (ANN), adaptive neuro-fuzzy inference system (ANFIS) and genetic algorithm (GA), together with traditional statistical analysis (multilinear regression (MLR)), to arrive at state-of-the-art procedures to predict occurrence of fire-induced spalling. Through a comprehensive datadriven examination of actual fire tests, this study demonstrates that AI techniques provide attractive tools capable of predicting fire-induced spalling phenomenon with high precision.

Electrochemical Study of [Ni63-Se)2μ4-Se)3(dppf)3] Cluster and Its Catalytic Activity towards the Electrochemical Reduction of Carbon Dioxide

  • Park, Deog-Su;Jabbar, Md. Abdul;Park, Hyun;Lee, Hak-Myoung;Shin, Sung-Chul;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1996-2002
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    • 2007
  • The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.

Effects of Electron-Beam Irradiation on Saponins and Physio-chemical Properties of Ginseng Powders (Electron Beam 조사가 인삼분말의 사포닌 및 생리화학적 특성에 미치는 영향)

  • 이미경;이종원;도재호;권중호
    • Food Science and Preservation
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    • v.10 no.2
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    • pp.206-212
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    • 2003
  • Comparative effects of electron beam and gamma-ray irradiation (25 ∼15 kGy) were investigated on saponin stability and some physiological and chemical properties of white and red ginseng powders. Saponin components were found stable upon irradiation of both energies when determined by TLC and HPLC, after 4 months of storage at room temperature as well as immediately after treatment The contents of total phenolics and acidic polysaccharides of the samples were higher in red ginseng than in white. Polysaccharide contents increased with irradiation doses. Amylase activity of white ginseng was stimulated by irradiation but decreased with the lapse of storage time. There were no apparent differences in electrophoresis patterns of extracted proteins depending on irradiation doses and energy sources.

Generation of novel hyaluronic acid biomaterials for study of pain in third molar intervention: a review

  • Shuborna, Nadia Sultana;Chaiyasamut, Teeranut;Sakdajeyont, Watus;Vorakulpipat, Chakorn;Rojvanakarn, Manus;Wongsirichat, Natthamet
    • Journal of Dental Anesthesia and Pain Medicine
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    • v.19 no.1
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    • pp.11-19
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    • 2019
  • Hyaluronic acid (HA) has long been studied in diverse applications. It is a naturally occurring linear polysaccharide in a family of unbranched glycosaminoglycans, which consists of repeating di-saccharide units of N-acetyl-D-glucosamine and D-glucuronic acid. It is almost ubiquitous in humans and other vertebrates, where it participates in many key processes, including cell signaling, tissue regeneration, wound healing, morphogenesis, matrix organization, and pathobiology. HA is biocompatible, biodegradable, muco-adhesive, hygroscopic, and viscoelastic. These unique physico-chemical properties have been exploited for several medicinal purposes, including recent uses in the adjuvant treatment for chronic inflammatory disease and to reduce pain and accelerate healing after third molar intervention. This review focuses on the post-operative effect of HA after third molar intervention along with its various physio-chemical, biochemical, and pharmaco-therapeutic uses.

Characteristics of the Inorganic Element Contents or the Korean Ginsengs from Various Soils of Keumsan (금산 지역 토양 차이에 의한 인삼 중 무기 원소의 함량 변화)

  • Song, Suck-Hwan;Min, Ell-Sik
    • Journal of Ginseng Research
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    • v.33 no.1
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    • pp.13-25
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    • 2009
  • Geochemical relationships between ginsengs and soils from three representative soil types, shale, phyllite and granite regions, from Keumsan were examined. High elements ere shown at the granite and shale areas of the weathered soils, the phyllite areas of he cultivated soils and the shale areas of the host rocks. T1 was enriched in ginsengs grown in the shale areas, Cs and B in the phyllite areas, and Be and Cd in the granite areas. Positive correlations were dominated by the shale areas. These relationships can be explained for mineral characteristics within the soils, and their behaviors related to the physio-chemical conditions. High elements were shown in the 2 year ginsengs of the hale areas, and 4 year ginsengs of the phyllite and granite areas in comparisons with ginsengs of the different ages from the same areas. These differences can be explained with ages of the ginsengs, solubilities of the minerals and physio-chemical differences within soils. The content differences of high elements such as Cs, T1 and Be were found between soils and ginsengs. Overall, these results suggest that components of ginsengs grown in the granite areas are chemically similar to the soils.

Fruit-body Formation of Pleurotus florida on the Synthetic Medium (합성배지(合成培地)를 이용(利用)한 고온성(高溫性) 느타리버섯의 자실체(子實體) 형성(形成)에 관한 연구(硏究))

  • Hong, Jai-Sik;Kang, Kui-Hwan
    • The Korean Journal of Mycology
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    • v.11 no.3
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    • pp.121-128
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    • 1983
  • Nutritional and physio-chemical conditions for mycelial growth and fruit-body formation of Pleurotus florida were determined in synthetic media. Mannitol and sucrose were good sugar substances for the mycelial growth and fruit-body formation whereas less mycelial growth and no fruit-body formation was obtained with arabinose, lactose and inulin. The optimum concentration of mannitol was about 2%. Peptone as a nitrogen sources resulted in a rapid mycelial growth and fruit-body formation with higher yield, but nitrite-nitrogens inhibited the mycelial growth. The higher yield was obtained with 0.2% peptone. Among the vitamins used, the greatest mycelial growth and fruit-body formation brought about by thiamine and folic acid. $KH_2PO_4$ and $MgSO_4$ at 0.2% and 0.02%, respectively, were effective for the mycelial growth and fruit-body formation, but other inorganic salts used were ineffective. The optimum temperature for mycelial growth and fruit-body formation were $25^{\circ}C$ and $20^{\circ}C$, respectively, and light intensity of $100{\sim}500\;lux$ and pH 6.0 appeared to be effective.

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Feasibility of New Pesticide Development in Korea (우리나라에서의 신농약 개발전망)

  • Park Young-Sun
    • Korean journal of applied entomology
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    • v.22 no.2 s.55
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    • pp.84-97
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    • 1983
  • Under the limited arable land, the enhancement of agricultural productivity is indispensable to provide the food demand which is concomitant with the rapid increase in population. From this viewpoint, the upbringing and dissemination of high-yielding varieties has been promoted continuously and several modifications in cultural practices, including heavy fertilization, dense planting, and early transplanting, also have been gradually developed. However these changes in cultivation have led to the increased outbreak of insect pests and diseases. And this unexpected results have accelerated the number and complexity of pesticides employed as well as their consumption. Even though pesticides are essential materials contributing to the steady production of agricultural crops, large scale consumption of them has given rise to several adverse impacts, such as mammalian hazard and/or environmental contamination. In this respect, recent development of new pesticides has been concentrated on 'safe pesticide', as it were, that has the highly selective properties without unfavorable side influences on other ecosystem. According to literature cited up to now, feasibilities of safe pesticide development would be summarized as two categories. One of them is the development of chemical pesticides, which include the molecular structure modification of established pesticides for increased safety and synthesis of new safe chemicals which can attack the vulnerable point of physio-ecological characteristics in insect pests and diseases. The other is the biological pesticides which comprise natural enemies and microorganisms to act selectively on confined insect pests and diseases, In addition, improvement of physico-chemical properties of available pesticide formulations would be one of the desirable means for safe pesticide development in view of efficacy enhancement and minimization of hazardous properties or safe pesticide development, various approaches are feasible and needed to study, however, long period and much financial outlay are necessary to develop a new item. And under the present situation in Korea, there are many difficulties for performing research on all the possible routes. Therefore, combined pesticides by the reasonable combination of already registered resticides evaluated as the fairly safe pesticides and safe formulation based on their physico-chemical properties would be developed primarily. And many efforts would be given gradually for the development of new chemical and biological pesticides.

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Chemical Components of Seed Oil of Sapium japonicum Pax. et Hoffm. (사람주나무 종실유의 화학적 조성)

  • Choi, Myung-Suk;Yang, Jae-Kyung;Gang, Byeng-Kuk
    • Korean Journal of Medicinal Crop Science
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    • v.8 no.3
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    • pp.274-282
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    • 2000
  • Physico-chemical characteristics and chemical composition of seed oil of Sapium japonicum were determined by various analysis methods. Physio-chemical characteristics of the extracted oil from fresh seed were specific gravity (0.928), refraction index (1.477), acid value (2.30), saponification number (190.0), and iodine value (126.0). Neutral lipid (93%) in seed oil was identified as major components, followed by glycolipid (4.9%) and phospholipid (1.3%). In GC analysis, nine fatty acids were presented in the seed oil. Among fatty acids, predominant fatty acids were oleic acid (45.8%) and linoleic acid (35.6%). The contents of fatty acids of seed oil somewhat varied with their storage period. Composition of fatty acids from lipid fractions which were isolated on silica open column was investigated. Major fatty acids in three lipid fractions were linoleic acid and linolenic acid. The fatty acid contents of fresh seed oil derived from each lipid fraction were generally high comapred to storage seed oil. From the above results, seed oil of Sapium Japonicum could be useful in cosmetics, detergents and a few pharmaceuticals.

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Development of real-time chemical properties analysis technique in paddy soil for precision farming (정밀농업을 위한 토양의 실시간 이화학 성분 분석 기술 개발)

  • Yun, Hyun-Woong;Choi, Chang-Hyun;Kim, Yong-Joo;Hong, Soon-Jung
    • Korean Journal of Agricultural Science
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    • v.41 no.1
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    • pp.59-63
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    • 2014
  • Precision farming aims at reduced environmental impacts with increased productivity. Soils are multi-functional media in which air, water and biota occur together and form an essential part of the landscape with a fundamental role in the environment. The requirement for herbicides and fertilizers can vary within a field in response to spatial differences in soil properties. Near infrared (NIR) spectroscopy is widely used today as a nondestructive analytical technique which is capable of determining a number of physio-chemical parameters. The objectives of this study were to develop optimal models to predict chemical properties of paddy soils by visible and NIR reflectance spectra. Total of 60 soil samples were collected in spring from 20 paddy fields within central regions in Korea. Reflectance spectra, moisture contents, pH, total nitrogen (N), organic matter, available phosphate ($P_2O_5$) of soil samples were measured. The reflectance spectra were measured in wavelength ranges of 400-2,500 nm with 2 nm interval. The method of partial least square (PLS) analysis was used to determine the soil properties. The PLS analyses showed good correlation between predicted and measured chemical properties of paddy soils in the wavelength range of 1,800-2,400 nm. Especially, it showed better performance than the previous results which used the entire wavelength range of the spectrophotometer, without considering the optimal wavelength of each soil properties.

Effect of Supplementation of Complex Probiotics on Performances, Physio-chemical Properties of Meat and Intestinal Microflora in Broiler (복합생균제의 급여가 육계의 생산성, 육의 이화학적 특성 및 장내 미생물에 미치는 영향)

  • Yu, D.J.;Na, J.C.;Kim, T.H.;Kim, S.H.;Lee, S.J.
    • Journal of Animal Science and Technology
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    • v.46 no.4
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    • pp.593-602
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    • 2004
  • A feeding trial was carried out to investigate the effect of supplemental complex probiotics on performances, physio-chemica1 properties of meat and inetestinal microflora in broiler chicks. Four hundred eighty broiler chickens, one days old with mixed sexes were fed one of four diets containing 0, 0.1, 0.2 and 0.4% complex probiotics for 7 weeks. There were four replicates with thirty chicks per pen. Diet contained ME 3,100, 3,l00kcal/kg, and CP 22.0, 20.0% for starting and finishing period, respectively. Body Weight gain of chicks fed the complex probiotics tended to increase from the frist week and all complex probiotics higher than control from the 4th week. Chickens fed the diets containing 0.2% probiotics had higher(P<0.05) than those fed the other levels from the 4th week to 5th week. Feed conversion also improved significantly(P<0.05) in the supplemental 0.2% probiotics from the 4th week to 5th week. In physio-chemica1 properties of meat, carcass rate increased significantly(P<0.05) in the supplemental 0.4% probiotics compared to that of control at 7 weeks overall means and abdominal fat pad rate increased significantly(P< 0.05) in the supplemental 0.2% probiotics compared to that of control. Cooking loss decreased significantly(P<0.05) in the supplemental all probiotics. But shear force increased significantly(P<0.05) in the supplemental 0.4% probiotics. The number of ileum and cecum Lactobacillus spp. tended to increase in the supplemental complex probiotics at 7 week of age, but was not significantly different. As the result, supplemental complex probiotics increased performance and physio-chemica1 properties of meat and the number of intestinal Lactobacillus of broiler chicks.