• Title/Summary/Keyword: physical solubility

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Estimation of Environmental Distribution for Benzoyl peroxide Using EQC Model

  • Kim, Mi-Kyoung;Bae, Heekyung;Kim, Su-Hyon;Song, Sanghwan;Koo, Hyunju;Kim, Hyun-Mi;Lee, Moon-Soon;Jeon, Seong-Hwan;Na, Jin-Gyun;Park, Kwangsik
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.150-151
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    • 2003
  • Benzoyl peroxide is a high production volume chemical, which was produced about 1,375 tons/year in Korea as of 2001 survey. Most of them are used as initiators in polymerization, catalysts in the plastics industry, bleaching agents for flour and medication for acne vulgaris. The substance is one of the sever chemicals of which human and environmental risks are being assessed by National Institute of Environmental Research under the frame of OECD SIDS Program. It has a melting point of 104-106 $^{\circ}C$ and has solubility of 9.1 mg/1 in water at 25 $^{\circ}C$. The substance was readily biodegradable (83 % after 21days) and had toxic effects to aquatic organisms. The range of 72 hr-EbC50 (biomass) for algae was 0.07-0.44 mg/1 and 48 hr-EC50 for daphnia was 0.07-2.91 mg/1. The LC50 of acute toxicity to fish was 0.24-2.0 mg/1. Although the toxic effects of benzoyl peroxide to aquatic organisms were investigated, environmental monitoring data were not studied. In this study, distribution of the chemical among multimedia environment was estimated using EQC model based on the physical-chemical properties to evaluate the risk of benzoyl peroxide in environment. In level I, II calculation the chemical was distributed to soil (68.3 %) and water (28.7 %). In level III calculation it was primarily distributed to soil (99.9 %) and overall residence time of 3.4 years was estimated. Benzoyl peroxide could be persistent in environment.

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The research regarding an information system risk management process characteristics (정보시스템 위험관리 프로세스 특성에 관한 연구)

  • Kim, Tai-Dal;Lee, Hyung-Won
    • The KIPS Transactions:PartD
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    • v.14D no.3 s.113
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    • pp.303-310
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    • 2007
  • Information system failure is various such as program test unpreparedness, physical facilities for damage prevention unpreparedness from simple software error. Although cross is trifling the result causes vast damage. Recently, became difficult by simple outside security system to solve this problem. Now, synthetic countermove establishment and suitable confrontation connected with danger came in necessary visual point about general Information Technology of enterprise. In connection with, in this paper, various informations and system and control about data that can happen information inside and outside considering integrity for IT resource, solubility, confidentiality within organization studied about special quality to model synthetic Risk Management System that can of course and cope in danger.

An Analysis of Korean Elementary School Students' Science Achievement in TIMSS 2011 (TIMSS 2011에 나타난 우리나라 초등학생들의 과학 성취 특성 분석)

  • Kim, Jiyoung;Kim, Soojin
    • Journal of Korean Elementary Science Education
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    • v.32 no.4
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    • pp.423-436
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    • 2013
  • This research purports to analyze released items and G4 students' science achievement from TIMSS 2011 according to their academic achievement levels and gender. By doing so, it aims to draw educational implications for Korea from analyses results. Korea showed a lower rate of students at the advanced international benchmark - the highest achievement level - compared to Singapore. The difference was the smallest in Life Science among three content domains and knowing among three cognitive domains. The results of analysis according to gender showed that male students' achievement was significantly higher in Physical Science and Earth Science, and their achievement was also higher in the cognitive domains of Knowing and Applying. From the analysis of the released items, it was revealed that the students' achievement was low in items related to classification of organisms, functions of heart, matters that combust or emit light, and the concept of rotation. Moreover, students drew some illogical conclusions based on their personal experience. Male students were found to show high achievements in items that were not included in curriculum, constructed-response items in the form of short-answer questions, and multiple-choice items in the Knowing domain. Female students were found to show high achievement in items that were included in curriculum, constructed-response items that require reasons and methods, and items that represent experimental situations. Male students showed high achievement in forces concept and movements concept of bodies in the universe, while female students showed high achievement in solubility concept.

Effects of Extracting Conditions on the Physical Properties of Fish Meal Protein Isolate Film (어분단백질 필름의 물리적 특성에 미치는 어분단백질 추출조건의 영향)

  • 유병진;심재만
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.3
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    • pp.494-499
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    • 2001
  • To determine optimal conditions for preparing protein isolate film from fish meal, the water vapor permeability (WVP), tensile properties and solubility of fish meal proteinisolate (FMPI) film were measured. FMPI was extracted from fish meal under conditions of various extraction times at $60^{\circ}C$. Extracting time little affected to WVP of FMPI film. The film added with glycerol as plasticizer showed higher WVP than sorbitol added. As extraction time increased up to 1 hr, tensile strength and elongation were increased. While in more extracting time than 1 hr, increasing extracting time made tensile strength and elongation showed negative correlations. The correlation of soluble protein amount and tensile strength showed higher value ($r^{2}=0.83$) than that of elongation ($r^{2}=0.62$).

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The Effect of Ultrasound Application to Anionic/Non-ionic Surfactant Aided Soil-washing Process for Enhancing Diesel Contaminated Soils Remediation (디젤오염토양 복원 효율 증진을 위한 음이온/비이온 계면활성제 토양세척공정에 초음파 적용 영향)

  • Cho, Sang-Hyun;Son, Young-Gyu;Nam, Sang-Geon;Cui, Ming-Can;Khim, Jee-Hyeong
    • Journal of Environmental Science International
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    • v.19 no.2
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    • pp.247-254
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    • 2010
  • Ultrasound and Surfactant aided soil washing process has been shown to be an effective method to remove diesel from soils. The use of surfactants can improve the mobility of diesel in soil-water systems by increasing solubility of adsorbed diesel into surfactant micelles. However, a large amount of surfactant is required for treatment. In addition, synthetic surfactants, specially anionic, are more toxic and the surfactant wastewater is hard to treat by conventional wastewater treatments even by AOPs. Ultrasound improves desorption of the diesel adsorbed on to soil. The mechanisms are based on physical breakage of bonds by hot spot, directly impact onto soil particle surface, the fragmentation of long-chain hydrocarbons by micro-jet and microstreaming in the soil pores. The use of ultrasound as an enhancement method in both anionic and nonionic surfactant aided soil-washing processes were studied. And all experiments were examined proceeded under CMC surfactant concentration, frequency 35 khz, power 400 W, Soil-water ratio 1:3(wt%), particle size 0.24 ~ 2mm and initial diesel concentration. 20,000 mg/kg. Combination with ultrasound showed significant enhancements on all the processes. Especially, nonionic surfactant Triton-X100 with ultrasound showed remarkable enhancements and diesel removal rate enhanced by ultrasound helps desorpting of surfactant adsorbed onto soils which prevented decreasing surfactant activity.

Effect of Green Tea Powder on the Sensory Quality of Cooked Rice (분말 녹차가 쌀밥의 관능적 특성에 미치는 영향)

  • Shin Doo-Ho;Lee Yeon-Wha
    • The Korean Journal of Food And Nutrition
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    • v.17 no.3
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    • pp.266-271
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    • 2004
  • In this study, rice was cooked with 0%, 0.5%, 1.0% and 2.0% green tea powder content to improve functionality of cooked rice. The effects of green tea powder content on the physical, texture and sensory characteristics of cooked rice were examined. Moisture contents of cooked rice with green tea powder were decreased with increasing amounts of added green tea powder. Initial pasting temperature of rice powder was showed an increase with increasing amounts of added green tea powder, besides peak viscosity was decreased. The solubility and swelling power were decreased with increasing amounts of added green tea powder. The color of cooked rice was darkened gradually with the increasing amounts of added green tea powder, and showed the dark green. Sensory adhesiveness was gradually decreased with the increasing amounts of added green tea powder, and cohesiveness, gummness, chewiness and hardness were increased. Sensory glassiness, overcook, stickiness and hardness had lower score than control group, but sensory color, flavor and overall acceptability had higher score with addition of 1.0% and 2.0% green tea powder. Concludingly, in items of overall sensory, cooked rice with 1.0% green tea powder showed the best result.

New Whitening agent: Kojyl-APPA

  • Hwang, Jae-Sung;Kim, Duck-Hee;Soomi Anh;Baek, Heung-Soo;Park, Hyunjung -Jin;Lee, Jin-Young;Lee, Byeong-Gon;Ihseop Chang;Kang, Hak-Kee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.27 no.1
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    • pp.119-131
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    • 2001
  • Exposure of the human skin to UV-light can cause sun-tanning, photoaging and even photo-carcinogenesis. Melanin is important in protecting the skin against UV damage, but excessive or uneven melanin production can lead to the formation of freckles and aged spot. Control of hyperpigmentation is becoming even more important as aged population continues to grow. These needs led us to develop effective and safe depigmenting-agent, kojyl 3-aminopropyl phosphate (kojyl-APPA), called Whitegen. The development of whitegen was based on the fact that phosphate group of 3-aminopropyl phosphate can make kojic acid more compatible to the skin membrane and more stable. Instability of kojic acid has been a problem in cosmetic use. The insertion of phosphoester group has been recognized as a powerful tool to improve such physical properties as solubility and stability, because the phosphodiester residue is well characterized as a non-toxic moiety, having a high affinity for cell membranes. Kojyl-APPA showed no tyrosinase inhibition effect compared to kojic acid in vitro, but showed tyrosinase inhibition effect in situ. It means that kojyl-APPA is converted to kojic acid enzymatically in cells. Kojyl-APPA showed the inhibitory activity on melanin synthesis in mouse melanoma and normal humal melnaocytes and also showed long-lasting stability in comparison with its original form (kojic acid). Kojyl-APPA showed depigmenting effects when applied to UVB-induced hyperpigmentated region of guinea pig skin. Based on these results, kojyl 3-aminopropyl phosphate can be used as a safe and effective ingredient for the brightness and cleanness of skin.

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Interactions between Chicken Salt-soluble Meat Proteins and Makgeolli Lees Fiber in Heat-induced Gels

  • Choi, Yun-Sang;Park, Kwoan-Sik;Kim, Hack-Youn;Kim, Hyun-Wook;Song, Dong-Heon;Chung, Hai-Jung;Lee, Ju-Woon;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.31 no.6
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    • pp.817-826
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    • 2011
  • The technological effects of Makgeolli lees fiber (0, 0.5, 1.0, 2.0, and 4.0%) on chicken salt-soluble breast meat proteins in a model system on proximate composition, physicochemical properties, and textural properties were investigated. Makgeolli lees fiber was obtained from Makgeolli brew processing, and the by-products showed good dietary fiber. The moisture and ash contents, water holding capacity, redness, yellowness, hardness, and apparent viscosity of chicken salt-soluble meat protein heat-induced gel systems with Makgeolli lees fiber were all higher than the control without Makgeolli lees fiber. However, protein solubility and electrophoretic patterns did not differ among the control and treatments with Makgeolli lees fiber samples. The chicken salt-soluble protein heat-induced gel systems incorporating Makgeolli lees fiber had improved water holding capacity, textural properties, and viscosity due to Makgeolli lees fiber addition. These results suggest that the addition of 4.0% Makgeolli lees fiber to gel is helpful to improve the physical properties of heat-induced gels.

The Effect of Different Particle Size from PAHs Contaminated Sediment by Ultrasonic Irradiation (PAHs로 오염된 침전물의 초음파 처리시 입자크기가 미치는 영향)

  • Na, Seung-Min;Khim, Jee-Hyeong;Cui, Ming-Can;Ahn, Yun-Gyong;Weavers, Linda K.
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.379-387
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    • 2010
  • Sediments of Little Scioto (LS) River in Ohio was contaminated by poor disposal of creosote from Baker Wood Creosoting Facility. Among the primary compounds of creosote, Polycyclic Aromatic Hydrocarbons (PAHs) are the most common ingredient PAHs are known for toxic, carcinogenic and mutagenic compounds. There are many difficulties to remove the PAHs in nature environment because their characteristics are having a less water-solubility, volatile and low mobility properties as increasing the molecular weight. The generation of hydroxyl radicals (${\cdot}OH$) and hydrogen peroxide ($H_2O_2$) forms as well as high temperature (5000 K) and pressure (1000 atm) by a physico-chemical effects of ultrasound during a cavitation collapse can promote the degradation and desorption of PAHs in sediment And it can also produces shock wave and microjets which are able to change the size and surface of particle in solid-liquid system as one of physical effects. Therefore, we explored to understand the role of particle size, the effect of elimination for PAHs concentration by ultrasound and optimize the conditions for ultrasonic treatment. The condition of various size of particles (> $150{\mu}m$, < $150{\mu}m$) and solid-liquid ratio (12.5g/L, 25g/L) for the treatment was considered and ultrasonic power (430 W/L) with liquid - hexane extraction and microwave extraction method were applied after ultrasound treatment.

Enhancement of antimicrobial properties of shoe lining leather using chitosan in leather finishing

  • Mahmud, Yead;Uddin, Nizam;Acter, Thamina;Uddin, Md. Minhaz;Chowdhury, A.M. Sarwaruddin;Bari, Md. Latiful;Mustafa, Ahmad Ismail;Shamsuddin, Sayed Md.
    • Advances in materials Research
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    • v.9 no.3
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    • pp.233-250
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    • 2020
  • In this study, a chitosan based coating method was developed and applied on the shoe lining leather surface for evaluating its inhibition to bacterial and fungal attacks. At first, chitosan was prepared from raw prawn shells and then the prepared chitosan solution was applied onto the leather surface. Secondly, the characterization of the prepared chitosan and chitosan treated leather was performed by solubility test, ATR-FTIR, XRD pattern, SEM and TGA. Evaluation of antimicrobial efficacy of chitosan was assessed against two gram positive, two gram negative bacteria and a reputed fungi by agar diffusion test. The results of this study demonstrated that chitosan took place in both the surface of collagen fibres and inside the collagen matrix of crust leather. The chitosan showed strong antimicrobial activities against all the tested microorganisms and the inhibition increased with increasing percentage of chitosan. Therefore, the prepared chitosan in this study can be an environment friendly biocide, which functions simultaneously against different spoilage bacteria and fungi on the finished leather surface. Thus by using the prepared chitosan in shoe lining leather, the possibility of microbial attack during shoe wearing can be minimized which is one of the important hygienic requirements of footwear.