• 제목/요약/키워드: physical and chemical effects

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Effects of Extrusion Process Parameters on Puffing of Extruded Pellets (압출성형 공정변수가 압출성형 펠릿의 팽화에 미치는 영향)

  • Kim, Jae-Hyun;Ryu, Gi-Hyung
    • Korean Journal of Food Science and Technology
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    • v.33 no.1
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    • pp.55-59
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    • 2001
  • Pressure-puffing system or extruder has been used to puff rice kernel or rice flour. Most of the study on rice puffing were the effect of process conditions such as moisture content and heating temperature on physical and chemical characteristics of popped rice. The study on mechanism and development of instant puffed rice like popcorn has been limited. Extruded waxy rice pellets were puffed in a microwave oven after drying and conditioning. Extruded pellets were formed with extrusion conditions of $20{\sim}27%$ moisture content, 2.76 MPa $CO_2$ gas injection pressure and 200 rpm screw speed. Under these conditions, puffed waxy rice pellets in microwave oven had low density and soft texture. Density and texture of puffed waxy rice pellet could be optimized by control of moisture content, $CO_2$ gas injection pressure and screw speed that affect significantly when puffing extruded waxy rice pellet.

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A Review of Clouds and Aerosols (구름과 에어로졸 고찰)

  • Yum, Seong Soo;Kim, Byung Gon;Kim, Sang Woo;Chang, Lim Seok;Kim, Seong Bum
    • Journal of Climate Change Research
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    • v.2 no.4
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    • pp.253-267
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    • 2011
  • This study summarizes some important results from the studies on clouds and aerosols, and their effects on climate in the northeast Asia that were made mainly by Korean scientists and some other scientists from around the world. Clouds and aerosols are recognized as one of the most important factors that contributes to uncertainties in climate predictions and therefore become the subject of active research in the western developed countries in recent years. However, the researches on clouds and aerosols are very weakly done in Korea except ground based measurements of aerosol physical, chemical and optical properties. These measurements indicate that aerosol loadings in the northeast Asia are generally much higher than other parts of the world. On the other hand, researches on clouds are few in Korea. Satellite and ground remote sensing, numerical modeling and aircraft in-situ measurements of clouds are highly needed for better assessment of the role of clouds on climate in the northeast Asia.

Effects of Chemical Composition of Ca(OH)2 and Precursors on the Properties of Fast-Curing Geopolymers (Ca(OH)2와 전구체의 화학 조성이 고속경화 지오폴리머의 물성에 미치는 영향)

  • Ko, Hyunseok;Noh, Jung Young;Lim, Hyung Mi
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.690-696
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    • 2019
  • Geopolymer is an alumina silicate-based ceramic material that has good heat-resistance and fire-resistance; it can be cured at room temperature, and thus its manufacturing process is simple. Geopolymer can be used as a reinforcement or floor finish for high-speed curing applications. In this manuscript, we investigate a high-speed curing geopolymer achieved by adding calcium to augment the curing rate. Metakaolin is used as the main raw material, and aqueous solutions of KOH and $K_2SiO_3$ are used as the activators. As a result of optimizing the high bending strength as a target factor for geopolymers with $SiO_2/Al_2O_3$ ratio of 4.1 ~ 4.8, the optimum ranges of the active agent are found to be $0.1{\leq}K_2O/SiO_2{\leq}0.4$ and $10{\leq}H_2O/K_2O{\leq}32.5$, and the optimum range of the curing accelerator is found to be $$0.82{\leq_-}Ca(OH)_2/Al_2O_3{\leq_-}2.87$$. The maximum flexural strength is found to be 1.35 MPa at $Ca(OH)_2/Al_2O_3=2.82$, $K_2O/SiO_2=0.3$, and $H_2O/K_2O=11.3$. The physical and thermal properties are analyzed to validate the applicability of these materials as industrial insulating parts or repairing finishing materials in construction.

Fabrication and Properties of Ti-HA Composites Produced by Pulsed Current Activated Sintering for Biomaterials (통전가압활성소결에 의한 생체재료용 Ti-HA복합재료 제조 및 특성)

  • Woo, Kee Do;Kang, Duck Soo;Kwon, Eui Pyo;Moon, Min Seok;Shon, In Jin;Liu, Zhiguang
    • Korean Journal of Metals and Materials
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    • v.47 no.8
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    • pp.508-515
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    • 2009
  • Ti-6Al-4V biomaterial is widely used as a bone alternative. However, Ti-6Al-4V ELI alloy suffers from numerous problems such as a high elastic modulus and high toxicity. Therefore, non-toxic biomaterials with low elastic moduli need to be developed. Ti-HA(hydroxyapatite) composites were fabricated in the present work by pulsed current activated sintering (PCAS) at $1000^{\circ}C$ under 60 MPa using mixed Ti and HA powders. The effects of HA content on the physical and mechanical properties of the sintered Ti-HA composites have been investigated. X-ray diffraction(XRD) analysis of the Ti-HA composites, including Ti-40 wt%HA in particular, revealed new phases, $Ti_{2}O$, CaO, $CaTiO_3$, and TixPy, formed by chemical reactions between Ti and HA during sintering. The hardness of the Ti-HA composites decreased with an increase in HA content. The corrosion resistance of these composites was observed to be an excellent candidate as a commercial Ti-6Al-4 V ELI alloy. A Ti-5 wt%HA composite fabricated by PCAS is recommended as a new biomaterial, because it offers good corrosion resistance, compressive strength, wear resistance, and biocompatibility, and a low Young's modulus.

Performance Evaluation of PAN Nanofiber Air Filter Fabricated by Electrospinning (전기방사에 의해 제조한 PAN 나노섬유 공기필터 성능평가)

  • Kim, Kyungcheol;Kim, Taeeun;Lee, JungKoo;Ahn, Jiwoong;Park, Sungho;Kim, Hyungman
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.11
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    • pp.885-890
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    • 2015
  • Nanomaterials possess unique mechanical, physical, and chemical properties. They are small, and have an ultrahigh surface area, making them suitable for air filter applications. Electrospinning has been recognized as an efficient technique for fabricating polymer nanofibers. In order to determine the optimum manufacturing conditions, the effects of several electrospinning process parameters on the diameter, orientation, and distribution of polyacrylonitrile (PAN) nanofiber are analyzed. To improve interlaminar fracture toughness and suppress delamination in the form of laminated non-woven fibers by using a heat roller, the performances of filter efficiency and pressure drop achieved with PAN nanofiber air filter are evaluated experimentally.

Effects of Methacrylamide Treatment on Silk Fibers II. Thermal Behavior of Methacrylamide-treated Silk Fibers (견섬유에 대한 메타크릴아미드의 처리효과 II. 메타크릴아미드 처리견의 열적 거동에 관하여)

  • 신봉섭;남중희
    • Journal of Sericultural and Entomological Science
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    • v.34 no.1
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    • pp.49-56
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    • 1992
  • Treatment of vinyl monomers onto silk fiber modifies the properties of the original silk fiber considerably. This field has been the subject of investigation by many workers using chemical and radiation initiation. Many studies on the reaction conditions, polymerization mechanism, physical properties and practical performances of methacrylamide-treated silk fiber have been continued. However, the polymerization mechanism has not been clearly revealed yet and this remains ambiguously whether the grafting is formed on fiber or not. In general, it has been accepted that free radicals were formed and vinyl monomers were polymerized in silk fibroin by graft polymerization mechanism, while active sties were varied by the types of monomer and initiator as well as by the reaction conditions. On the other hand, there is another argument on polymerization mechanism, in which monomers are polymerized and impregnated in the internal side of the fiber by homopolymerization. Though a large number of analytical methods are used to examine the polymerization mechanism of methacrylamide-treated silk fiber, the results on the basis of thermal analysis are merely reported in this paper. In differential scanning calorimetry (DSC) analysis, the thermal decomposition behaviors of the methacrylamie-treated silk fibers were determined and compared to those of the controlled silk fibers. DSC curves obtained from the methacrylamide-treated silk fibers showed double peaks at around 290$^{\circ}C$ (A peak) and 320$^{\circ}C$ (B peak) which are attributed to the thermal decomposition of the methacrylamide polymer and silk fibroin fiber, respectively. The temperature of A and B peak shifted to higher value with the increase of add-on. Also, the moisture regain of the treated silk fibers increased with add-on.

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Physical and Chemical Characteristics of Multi-walled Carbon Nanotube (MWCNT) with Acid-treatment and Coupling Agent on the Properties of Styrene Butadiene Rubber (SBR) (SBR에 산 처리된 MWCNT 및 커플링제 적용 시 발현되는 물리.화학적 특성 연구)

  • Song, Sung-Ho;Jeong, Ho-Kyun;Kang, Yong-Gu;Cho, Choon-Tack
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.108-115
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    • 2010
  • The effects of acid-treated MWCNT and coupling agent on properties of MWCNT/SBR are investigated in this work. The MWCNTs oxidized using sulfuric and nitric acids were analyzed by the Raman scattering and Fourier transformed infrared spectroscopy(FT-IR). The FT-IR results indicate the presence of -COOH groups in the treated samples, and Raman spectroscopy of the acidtreated MWCNTs further corroborates the formation of surface defect due to the introduction of carboxyl groups. And the nanocomposites reinforced with MWCNTs were characterized extensively using the scanning electron microscopy(SEM), electrical conductivity, thermal conductivity, and tensile properties measurements. The results showed that nanocomposites onto acid-treated MWCNTs enhanced mechanical properties compared to those containing MWCNTs without acid treatment. These findings confirmed the improved interfacial interactions between MWCNTs and SBR arising from the coupling agents. But the electrical and thermal conductivity of nanocomposites decreased due to the chopping and formation of surface defects of MWCNTs.

The effects of biomaterials in growing medium on the response of Zelkova serrata in a containerized production system

  • Youn, Woo-Bin;Han, Si-Ho;Seo, Jeong-Min;Aung, Aung;Dao, Huong Thi Thuy;An, Ji-Young;Park, Byung-Bae;Cho, Min-Seok
    • Korean Journal of Agricultural Science
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    • v.46 no.4
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    • pp.781-790
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    • 2019
  • Changes in the physical and chemical properties of soil materials during the nursing process have a great influence on the quality of containerized seedlings and on growth and survival after planting. In this study, the effect of biomaterials and their mixed ratios on the growth of Zelkova serrata seedlings in a containerized seedling production system was investigated. Mushroom sawdust, pine bark, and carbonized rice husk were used as biomaterials. The mixed ratios were 10% and 20% volume ratio of the growing medium volume, including the untreated controls. There was no significant difference in the height growth of the Zelkova serrata seedlings according to the biomaterials. The root collar diameter was the highest with the 20% carbonized rice husk and the lowest with the mushroom sawdust. The difference between the highest quality index and the lowest quality index was 30% in the order of the carbonized rice husk, pine bark, control, and mushroom sawdust, but there was no statistical significance. In this study, if the growing medium mixed with biomaterials does not reduce the seedling growth compared with the control, it is considered that the biomaterial can replace a part of the growing media. Therefore, the results show that some of the growing media can be replaced with carbonized rice husk or pine bark when producing Zelkova serrata seedlings.

Quality Properties of Beef Patties Replaced Tallow with Rice Bran Oil and Olive Oil during Cold Storage (우지방을 현미유와 올리브유로 대체한 우육 패티의 냉장저장 중 품질변화)

  • Seo, Hyun-Woo;Kim, Gap-Don;Jung, Eun-Young;Yang, Han-Sul
    • Food Science of Animal Resources
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    • v.31 no.5
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    • pp.763-771
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    • 2011
  • The effects of replacing tallow with plant oils on the chemical composition, physical properties, fatty acid composition, and sensory properties of beef patties were investigated. Beef patties were produced with seven different formulations: control (tallow, 100%), rice-bran oil replaced (TR) and olive oil replaced (TO) (each at 20%, 40%, and 60% substitution). Fat content of beef patties increased, whereas moisture content decreased with increased TR and TO. Beef patties had increased lightness and yellowness but decreased pH and redness compared to those in the control (p<0.05). The thiobarbituric acid reactive substances (TBARS) values of all beef patties increased during cold storage. The TBARS values in the replaced TR or TO were similar to or lower than those in the control after 3 d. Saturated fatty acid content of beef patties decreased as the level of TR and TO increased, whereas unsaturated fatty acid content increased. Monounsaturated fatty acids were higher in TO and polyunsaturated fatty acids were higher in TR. The overall acceptability scores showed no significant differences between the control and replaced TR or TO over 7 d of storage.

Characterization of Arthrospira platensis Mutants Generated by UV-B Irradiation (자외선 조사에 의해 유도된 미세조류 Arthrospira platensis 변이주의 특성)

  • Park, Hyun-Jin;Kim, Young-Hwa;Lee, Jae-Hwa
    • Applied Chemistry for Engineering
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    • v.23 no.5
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    • pp.496-500
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    • 2012
  • Arthrospira platensis (A. platensis) is an economically important filamentous microalgae. The isolation of mutants by chemical or physical mutagen is a clue for the strain improvement. In this study, effects of ultraviolet-B (UV-B) radiation on A. platensis were investigated. Cells (or microalgae) were exposed to UV-B (15 Watt, 254 nm) for 1, 3, 5, and 10 min, and resulting mutants were designated UM1, UM3, UM5, and UM10, respectively. Especially, the lipid content of UM5 mutant was considerably increased by 8~11 fold compared to that of wild types. Moreover, the carotenoid content and antioxidant enzyme (peroxidase and superoxide dismutase) activity were increased. It was shown that UV-induced mutants can accumulate bioactive compounds, which will be useful for the industrial production of valuable products.