• 제목/요약/키워드: physical and chemical effects

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재활용재료를 포함한 옥상녹화용 인공토양의 성능평가 - 토양배합비가 자생식물 생육에 미치는 영향을 중심으로 - (A Study on Green Roofing Applied Artificial Soil Containing Recycled Materials - Focused on the Effects on the Growth of Plants by Difference of Soil Mixture Ratio -)

  • 김경훈;고정현;김용
    • 한국환경복원기술학회지
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    • 제16권5호
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    • pp.119-130
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    • 2013
  • The objective of this study was to analyze an availability of green roof soil based on the bottom ash soil and compost using sludge derived from food factory as comparing and analysing the growth of native plants. Analysing the physical properties and chemical resistance of 12 different type mixing soils which is mainly used in green roof, selected 4 types of soil, experiments were conducted to compare plant growth. The growth status of the plant showed the most superior of the soil 13(control), next soil 9(Pearlite : Bottom Ash : Compost = 20 : 60 : 20) and soil 10(Pearlite : Zeolite : Compost = 60 : 20 : 20) This result showed that native plants grow well in the soil based on the bottom ash and compost using sludge derived from food factory, and this soil type is determined that is available the green roof soil.

비예혼합 역류화염에서 열전대 측정을 적용하기 위한 복사보정에 관한 연구 (A Study On the Radiation Corrections Applied to Thermocouple Measurements in Non-premixed Counterflow Flames)

  • 오율권;허준영;차경옥
    • Journal of Advanced Marine Engineering and Technology
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    • 제26권2호
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    • pp.209-218
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    • 2002
  • The temperature field of a counterflow non-premixed flame is investigated using thermocouples of two sizes. A thermal balance is performed on the thermocouple in order to calculate the magnitude of the radiation corrections involved. Both the thermocouple wire and bead are separately considered to be the relevant thermal surface to which convective heat transfer takes place, and from which radiation lasses occur. The flame is also simulated by using a detailed chemical kinetic mechanism in a previously developed computer code. The local thermo-physical properties of the gas mixture, required to calculate the corrections, are determined both from the simulation, and by approximating the properties of the mixture as those of molecular nitrogen at the measured temperatures. It is concluded that the thermocouple wire is the appropriate thermal surface to which radiation corrections apply, in the absence of information about the gas mixture, its properties can be reasonably approximated by those of nitrogen rm ($N_2$), and the radiation corrections are very sensitive to misalignments in the temperature and velocity fields.

경유의 윤활특성 (Lubricating Characteristics of Diesel Fuel)

  • 신성철;강익중
    • Tribology and Lubricants
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    • 제16권5호
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    • pp.332-340
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    • 2000
  • The reduction of sulfur content in the diesel fuel has caused the poor lubricity of diesel fuel in the distributor type injection pumps of diesel engines that use the diesel for lubrication of their moving parts. To investigate the reason for poor lubricity of low sulfur diesel fuels, the wear scar diameters by HFRR (High Frequency Reciprocating Rig) were measured on the diesel fuels from Korean markets and the results were compared with their physical and chemical properties. Also, the lubricity change and the improvement effects on lubricity additives for the ultra low sulfur diesel fuel, were made experimentally, that will be regulated to a maximum of 0.005 wt% from about 2005 were evaluated. As a result, a good correlation was found between the wear scar diameter and the polyaromatic compound which includes heterocyclic compound in the diesel fuel. It was also found that the content of polyaromatic compound including heterocyclic compound was affected by the amount of desulfurization treatment fraction. And the lubricity additives with ester base were more effective than that with acid base on the ultra low sulfur diesel fuel. Therefore, it is suggested that the factors affecting the lubricity stated above should be taken into account to improve the lubricity property of the diesel fuel in the refining process.

자주달개비 분석법을 이용한 카펫 방출 휘발성 유기화합물의 생물학적 영향 평가 (Biological Effects of Volatile Organic Compounds from Carpet Materials as Assessed by the Tradescantia Assay)

  • 김진규;신해식;이영엽;이진홍
    • 환경생물
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    • 제25권3호
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    • pp.191-196
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    • 2007
  • 실내 공기는 대기와는 달리 실내 건축 자재에서 유래된 물질로 오염될 수 있다. 본 연구는 실내자재인 카펫에서 방출되는 휘발성 유기화합물의 생물학적 영향을 평가하기 위하여 수행되었다. 카펫과 자주달개비 BNL 4430 꽃차례를 환경노출시험용기에 넣고 일정시간 노출을 실시하였고 흡착관의 VOCs에 대한 화학분석을 실시하였다. 화학분석결과 카펫에서는 12종의 VOCs가 방출되는 것이 확인되었으며 이중 스틸렌$(71.9{\mu}g\;m^{-3})$과 톨루엔$(49.6{\mu}g\;m^{-3})$의 농도가 높았다. 환경노출시험용기에서 카펫에서 방출되는 VOCs에 24시간 노출된 자주달개비 실험군의 미세핵 빈도는 100사분자 당 $7.73{\pm}0.75MCN$으로서 TO-14 표준혼합기체 1ppm에 4시간 노출된 실험군의 미세핵 빈도인 $7.31{\pm}0.70$와 유사한 높은 값을 나타내었다. 반면 표준혼합기체 1ppm에 2시간 노출된 실험군의 경우 미세핵 자연발생 빈도와 유사한 수준을 보였다. 이 같은 결과로부터 카펫에서 방출된 휘발성 유기화합물이 함유되어 있는 실내공기에 장시간 노출될 경우 생물유전독성이 유발된다는 것이 확인되었다. 본 연구에 적용한 생물-화학 병용분석 기법은 실내 공기오염의 생물학적 감시에 매우 효율적임이 입증되었다.

아미노실란으로 개질된 목분/PVC/나노점토 복합재의 기계적 특성 (Mechanical Properties of Aminosilane-Treated Wood Flour/PVC/Nanoclay Composites)

  • 박솔몬;김대수
    • 폴리머
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    • 제36권5호
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    • pp.573-578
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    • 2012
  • 일반적으로 목분/PVC 복합재가 갖는 대부분의 물리적 특성은 소수성인 PVC와 친수성인 목분 사이의 낮은 계면결합력으로 인해 순수한 PVC에 비해서도 낮다. 그러므로 본 연구에서는 목분/PVC의 계면결합력을 향상시키기 위해 세 가지 아미노실란을 각각 사용하여 목분을 개질하였으며, 아미노실란으로 개질된 목분, 무중금속 PVC 컴파운드, 나노점토를 용융혼합하여 환경친화적인 목분/PVC/나노점토 복합재를 제조하였다. 목분의 아미노실란 개질 및 나노점토의 첨가가 복합재의 기계적 특성에 미치는 영향을 조사하였다. 복합재의 기계적 특성은 만능재료시험기, 아이조드 충격시험기, DMA, TMA를 이용하여 조사하였다. 아미노실란으로 개질된 목분을 이용한 복합재의 인장특성은 순수한 목분을 이용한 복합재의 인장특성보다 훨씬 높았다. 또한 적은 양의 나노점토가 복합재의 기계적 특성을 향상시켰다. 아미노실란으로 개질된 목분과 나노점토를 사용함으로써 목분/PVC 복합재의 성능이 크게 향상되었다.

Study of Naturally Occurring Radioactive Material Present in Deep Soil of the Malwa Region of Punjab State of India Using Low Level Background Gamma-Ray Spectrometry

  • Srivastava, Alok;Chahar, Vikash;Chauhan, Neeraj;Krupp, Dominik;Scherer, Ulrich W.
    • Journal of Radiation Protection and Research
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    • 제47권1호
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    • pp.16-21
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    • 2022
  • Background: Epidemiological observations such as mental retardation, physical deformities, etc., in children besides different types of cancer in the adult population of the Malwa region have been reported. The present study is designed to get insight into the role of naturally occurring radioactive material (NORM) in causing detrimental health effects observed in the general population of this region. Materials and Methods: Deep soil samples were collected from different locations in the Malwa region. Their activity concentrations were determined using low-level background gammaray spectrometry. High efficiency and high purity germanium detector capped in a lead-shielded chamber having a resolution of 1.8 keV at 1,173 keV and 2.0 keV at the 1,332 keV line of 60Co was used in the present work. Data were evaluated with Genie-2000 software. Results and Discussion: Mean activity concentrations of 238U, 232Th, and 40K in deep soil were found to be 101.3 Bq/kg, 65.8 Bq/kg, and 688.6 Bq/kg, respectively. The mean activity concentration of 238U was found to be three and half times higher than the global average prescribed by the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR). It was further observed that the activity concentration of 232Th and 40K has a magnitude that is nearly one and half times higher than the global average prescribed by UNSCEAR. In addition, the radioisotope 137Cs which is likely to have its origin in radiation fallout was also observed. It is postulated that the NORM present in high quantity in deep soil somehow get mobilized into the water aquifers used by the general population and thereby causing harmful health problems. Conclusion: It can be stated that the present work has been able to demonstrate the use of low background gamma-ray spectrometry to understand the role of NORM in causing health-related effects in a general population of the Malwa region of Punjab, India.

금속담지 활성알루미나 촉매의 암모니아 저온연소반응 (Catalytic Oxidation of Ammonia over Metal Supported on Alumina at Low Temperature)

  • 임윤희;이주열;박병현
    • 한국응용과학기술학회지
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    • 제30권3호
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    • pp.371-379
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    • 2013
  • In order to improve the selective oxidation reaction of gaseous ammonia at a low temperature, various types of metal-impregnated activated alumina were prepared, and also physical and chemical properties of the conversion of ammonia were determined. Both types of metal (Cu, Ag) impregnated activated alumina show high conversion rate of ammonia at high temperature (over $300^{\circ}C$). However, at lower temperature ($200^{\circ}C$), Ag-impregnated catalyst shows the highest conversion rate (93%). In addition, the effects of lattice oxygen of the developed catalyst was studied. Ce-impregnated catalyst showed higher conversion rate than commercial alumina, but also showed lower conversion rate than Ag-impregnated sample. Moreover, 5 vol.% of Ag activation under hydrogen shows the highest conversion rate result. Finally, through high conversion at low temperature, it was considered that the production of NO and $NO_2$, toxic by-products, were effectively inhibited.

Enhanced Liver Targeting by Synthesis of $N_{\b{1}}-Stearyl-5-Fu$ and Incorporation into Solid lipid Nanoparticles

  • Yu, Bo-Tao;Xun-Sun;Zhang, Zhi-Rong
    • Archives of Pharmacal Research
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    • 제26권12호
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    • pp.1096-1101
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    • 2003
  • To enhance the liver targeting and reduce the side effects of 5-fluorouracil (5-Fu), it was acylated by stearyl chloride to obtain .$\b{N}_{\b{1}}$stearyl-5-Fu (5-FuS). The chemical structure of the prodrug was confirmed by Nuclear Magnetic Resonance and Infrared Spectrometry. 5-FuS was incorporated into solid lipid nanoparticles (SLN), which were prepared by the physical agglomeration method. The mean diameter of 5-FuS-SLN was 240.19 nm and the drug loading was 20.53%. The release characteristics in vitro of 5-FuS-SLN were fitted to the first-order pharmacokinetic model. Compared with 5-Fu injection, a study on the distribution of 5-FuS-SLN in mice showed that 5-FuS-SLN could double 5-Fu concentration in mice livers. The main pharmacokinetic parameters of 5-FuS-SLN in rabbits is shown as follows: $V_d$=0.04336L/kg, $T_{1/2} \beta$=1.2834h, CL=0.1632 L/h. In conclusion, 5-FuS-SLN has significant liver targeting properties. The employment of a prodrug to enhance drug liposoluble properties and the preparation method presented in this paper, seem to be an alternative strategy to the traditional colloidal delivery system.

Tetrahymena sp.의 분리와 물리화학적 요인이 성장에 미치는 영향 (Effects of physical and chemical factors on the growth of Tetrahymena sp. isolate)

  • 김종진;유재근;이형환
    • 미생물학회지
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    • 제26권4호
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    • pp.348-354
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    • 1988
  • 폐수에서 분리한 Tetrahymena sp. 는 크기는 50~$70{\mu}m$이고, 타원형이며, 앞부분은 약간 뽀죽한 형태였다. 구강, Kineto some, 대핵, 수축포와 식포 등을 선명히 광학현미경으로 관찰 할 수 있었다. 이분법에 의하여 세포분열을 했고, 대장균세균을 먹이로 이용했다. 분리한 Tetrahymena sp. 는 $20^{\circ}C$, $25^{\circ}C$, 그리고 pH7에서 9, 그리고 담수에서 증식이 제일 높았다. $Zn^{++}/l$은 0.7mg/l 농도까지는 증식억제를 거의 하지 않았고, $Cd^{++}/l$농도가 0.3mg/l 그리고 $Cu^{++}/l$가 0.1mg/l 이상에서는 증식을 억제하였다.

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정석탈인공정의 정석재로써 폐굴껍질의 재활용에 관한 연구 (A Study on Recycling of Waste Oyster Shells as Seed Crystals in Phosphorous Crystallization Process)

  • 김은호;성낙창;장성호
    • 한국환경보건학회지
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    • 제23권4호
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    • pp.133-138
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    • 1997
  • The technology of removing phosphorous, considered as one of the most important control nutrients causing eutrophication in various water bodies, have been investigated by many researchers. Recently, phosphorous crystallization process is emerging as a new technology for phosphorous removal. In this study, waste oyster shells which can be easily obtained from the ocean, were used as a seed crystal, and their effects of several physical/chemical factors on the phosphorous removal efficiencies were examined by batch tests. Ca$^{2+}$ and pH affected phosphorous crystallization process using waste oyster shells. As alkalinity of wastewater increased, phosphorous removal efficiencies gradually decreased. Phosphorous removal efficiencies were increased, as specific area and contact efficiency per unit area of waste oyster shells were increased. In case of high temperature, phosphorous crystallization process was rapidly advanced and phosphorous removal efficiencies were increased. Dependig on X-ray diffraction analysis, it was showed that generation materials extracted from the surface of waste oyster shells with short reaction time were dominated by $CaHPO_4\cdot 2H_2O$, but progressed to $Ca_5(OH)(PO_4)_3$. The SEM observation reveals that the evident variations were hardly seen, but particle sizes of waste oyster shells were relatively bigger and showed forms of smaller plate than before.

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