• 제목/요약/키워드: physical and chemical effects

검색결과 856건 처리시간 0.026초

상수원 관망 부식 제어를 위한 부식성 수질 관리: 북미지역 관리 사례 및 국외 현황 (The Regulations and Guidelines for Management of Corrosive Water and Pipe Corrosion in Drinking Water Distribution System in North America)

  • 김민희;현승훈;이원석
    • 한국물환경학회지
    • /
    • 제33권3호
    • /
    • pp.359-369
    • /
    • 2017
  • Water distribution systems supply drinking water to consumers' taps. Internal corrosion of metallic pipe used in drinking water distribution systems has reduced water quality and led to increased levels of toxic heavy metals such as lead, copper and nickel. These problems have been experienced to varying degrees by water utilities in many countries. North America has successfully managed and controlled pipe corrosion and corrosive water in water distribution system based on various policies, regulations and rules. Practical and engineering guidelines for evaluation of pipe corrosion and determination of treatment options are also provided to assist drinking water supplies. In addition, the corrosion mechanism in water distribution systems, such as the complex effects of physical and chemical parameters on the corrosion pipes has been improved to accurately predict corrosion rates of metallic pipes in actual water distribution systems. This paper reviews various regulations, policy statement, and treatment produces on controlling corrosion in drinking water distribution systems in US and Canada and then offers suggestion for management of corrosive water and pipe corrosion in drinking water distribution system in Korea.

구형 고분자수지로 활성탄제조 시 운전인자의 영향 (Effect of Operating Parameters on the Physical Properties of Activated Carbon Manufactured with Bead-Type Polymer Resin)

  • 이강춘;윤태경;손장호
    • 청정기술
    • /
    • 제19권3호
    • /
    • pp.279-286
    • /
    • 2013
  • 탄소원으로 구형 고분자수지 중 폴리스티렌-DVB 공중합으로 제조된 양이온교환수지를 사용하여 활성탄제조 시 활성탄의 주요물성인 비표면적과 비용적에 미치는 운전인자의 영향이 실험적으로 연구되었다. 활성탄의 비표면적과 비용적은 탄화공정에서 탄화온도 및 탄화시간이 증가함에 따라 감소하였고, 활성화공정에서는 활성화온도와 활성화시간에 따라 증가하였지만 특정 온도와 시간 이상에서는 감소하였다. 탄화공정에서 승온속도가 증가함에 따라 감소하였지만, 반대로 활성화 후 승온속도에 비례하는 물성을 보였다. 2가이온으로 포화된 수지로 제조된 활성탄은 새 수지로 제조된 활성탄에 비해 낮은 비표면적을 보였다.

Postmortem Aging of Beef with a Special Reference to the Dry Aging

  • Khan, Muhammad I.;Jung, Samooel;Nam, Ki Chang;Jo, Cheorun
    • 한국축산식품학회지
    • /
    • 제36권2호
    • /
    • pp.159-169
    • /
    • 2016
  • Animal muscles are stored for specific period (aging) at refrigerated temperatures, during and after which the living muscles start to convert into meat and thus, attain certain superior properties in the final product. Proteolysis, lipolysis, and oxidation are the major biochemical processes involved during the postmortem aging of meat that affect the tenderness, juiciness, and flavor, as well as sometimes may introduce certain undesirable traits. This review analyzes the role of pre- and post-mortem factors that are important for aging and their effect on the chemical and physical changes in the “dry- and wet-aged meat.” Thus, if the meat processing manufacturers optimize the effects of aging for specific muscles, the palatability, color, and the shelf life of the aged meat products could be significantly enhanced.

A Numerical Model for the Freeze-Thaw Damages in Concrete Structures

  • Cho Tae-Jun
    • 콘크리트학회논문집
    • /
    • 제17권5호
    • /
    • pp.857-868
    • /
    • 2005
  • This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

인공풍화 실험을 이용한 보존처리제의 물성 변화 연구 (A Study on the Change of Conservation Materials Properties Using Artificial Weathering Test)

  • 도민환;한민수;이장존;전병규;송치영
    • 보존과학연구
    • /
    • 통권29호
    • /
    • pp.149-162
    • /
    • 2008
  • Because stone cultural heritages in Korea are mostly situated outdoors without any notable protection, there are severe damages from physical, chemical and biological weathering. And this in turn causes deformation and structural damage. To counteract this problem and increase durability, various kinds of conservation materials are used in the conservation and restoration treatment. However, there are not many practical and technological experiments on this subject. Accordingly this research is for analysis of effect for treatment to make use a resin of the ethyl silicate for the granite in Mt. Nam of Gyeongju. It takes a long time to confirm the test result regarding durability and side effects of the conservatives after treatment. So we built up an artificial environment through freezing and melting test, and evaluated the conservation materials. As a result of this experiment, porosity and absorptivity was increased in accordance with processing of freezing and melting test. But other things such as elastic wave speed, elastic modulus, uniaxial compressive strength and tensile strength was decreased. It will make a plan to form a method of research systematically for mechanism and element of weathering and to elicit a correlation among experiment of artificial weathering and practical natural weathering from next research.

  • PDF

Cyopreservation and its clinical applications

  • Jang, Tae Hoon;Park, Sung Choel;Yang, Ji Hyun;Kim, Jung Yoon;Seok, Jae Hong;Park, Ui Seo;Choi, Chang Won;Lee, Sung Ryul;Han, Jin
    • Integrative Medicine Research
    • /
    • 제6권1호
    • /
    • pp.12-18
    • /
    • 2017
  • Cryopreservation is a process that preserves organelles, cells, tissues, or any other biological constructs by cooling the samples to very low temperatures. The responses of living cells to ice formation are of theoretical interest and practical relevance. Stem cells and other viable tissues, which have great potential for use in basic research as well as for many medical applications, cannot be stored with simple cooling or freezing for a long time because ice crystal formation, osmotic shock, and membrane damage during freezing and thawing will cause cell death. The successful cryopreservation of cells and tissues has been gradually increasing in recent years, with the use of cryoprotective agents and temperature control equipment. Continuous understanding of the physical and chemical properties that occur in the freezing and thawing cycle will be necessary for the successful cryopreservation of cells or tissues and their clinical applications. In this review, we briefly address representative cryopreservation processes, such as slow freezing and vitrification, and the available cryoprotective agents. In addition, some adverse effects of cryopreservation are mentioned.

Biological Pretreatment of Softwood Pinus densiflora by Three White Rot Fungi

  • Lee, Jae-Won;Gwak, Ki-Seob;Park, Jun-Yeong;Park, Mi-Jin;Choi, Don-Ha;Kwon, Mi;Choi, In-Gyu
    • Journal of Microbiology
    • /
    • 제45권6호
    • /
    • pp.485-491
    • /
    • 2007
  • The effects of biological pretreatment on the Japanese red pine Pinus densiflora, was evaluated after exposure to three white rot fungi Ceriporia lacerata, Stereum hirsutum, and Polyporus brumalis. Change in chemical composition, structural modification, and their susceptibility to enzymatic saccharification in the degraded wood were analyzed. Of the three white rot fungi tested, S. hirsutum selectively degraded the lignin of this sortwood rather than the holocellulose component. After eight weeks of pretreatment with S. hirsutum, total weight loss was 10.7%, while lignin loss was the highest at 14.52% among the tested samples. However, holocellulose loss was lower at 7.81 % compared to those of C. lacerata and P. brumalis. Extracelluar enzymes from S. hirsutum showed higher activity of ligninase and lower activity of cellulase than those from other white rot fungi. Thus, total weight loss and changes in chemical composition of the Japanese red pine was well correlated with the enzyme activities related with lignin- and cellulose degradation in these fungi. Based on the data obtained from analysis of physical characterization of degraded wood by X-ray Diffractometry (XRD) and pore size distribution, S. hirsutum was considered as an effective potential fungus for biological pretreatment. In particular, the increase of available pore size of over 120 nm in pretreated wood powder with S. hirsutum made enzymes accessible for further enzymatic saccharification. When Japanese red pine chips treated with S. hirsutum were enzymatically saccharified using commercial enzymes (Cellulclast 1.5 L and Novozyme 188), sugar yield was greatly increased (21.01 %) compared to non-pre treated control samples, indicating that white rot fungus S. hirsutum provides an effective process in increasing sugar yield from woody biomass.

Modeling of Co(II) adsorption by artificial bee colony and genetic algorithm

  • Ozturk, Nurcan;Senturk, Hasan Basri;Gundogdu, Ali;Duran, Celal
    • Membrane and Water Treatment
    • /
    • 제9권5호
    • /
    • pp.363-371
    • /
    • 2018
  • In this work, it was investigated the usability of artificial bee colony (ABC) and genetic algorithm (GA) in modeling adsorption of Co(II) onto drinking water treatment sludge (DWTS). DWTS, obtained as inevitable byproduct at the end of drinking water treatment stages, was used as an adsorbent without any physical or chemical pre-treatment in the adsorption experiments. Firstly, DWTS was characterized employing various analytical procedures such as elemental, FT-IR, SEM-EDS, XRD, XRF and TGA/DTA analysis. Then, adsorption experiments were carried out in a batch system and DWTS's Co(II) removal potential was modelled via ABC and GA methods considering the effects of certain experimental parameters (initial pH, contact time, initial Co(II) concentration, DWTS dosage) called as the input parameters. The accuracy of ABC and GA method was determined and these methods were applied to four different functions: quadratic, exponential, linear and power. Some statistical indices (sum square error, root mean square error, mean absolute error, average relative error, and determination coefficient) were used to evaluate the performance of these models. The ABC and GA method with quadratic forms obtained better prediction. As a result, it was shown ABC and GA can be used optimization of the regression function coefficients in modeling adsorption experiments.

Consumption and Production of NO from European Forest Soils: Effects of Forests and Textures

  • Kim, D.S.;Dijk, S.M.Van;Meixner, F.X.
    • Journal of Korean Society for Atmospheric Environment
    • /
    • 제24권E1호
    • /
    • pp.12-23
    • /
    • 2008
  • Relationship between the optimum soil water content and clay content on soil samples from mid-latitude European forest was tested. Soil samples from 4 different experimental sites (two forest sites in the Netherlands and a Danish forest) were collected, and analyzed for the soil physical and chemical characteristics. Water retention curves for the soil samples were determined according to the standard procedure ISO 11274, and pF decreased with increase in soil water contents. NO is simultaneously produced and consumed by microbiological processes, which comprise of nitrification and denitrification. NO consumption and production rates were determined from the soil samples and compared to their corresponding water retention curves in order to find the optimum soil water content and matric potential for maximum NO release from mid-latitude soils. NO consumption rate coefficient (k) in Hollandse Hout was significantly lower than those in other soil sites. Maximum NO production was observed at an intermediate soil moisture ($0.2{\sim}0.3kg/kg$) in all the soil samples. Resulting from the NO consumption and production rates for the soils, the empirical NO fluxes of the different soils were calculated in the laboratory.

The Influence of H+ and Cl- Ions on the Corrosion Inhibitive Effect of Poly(para-aminophenol) for Iron in Hydrochloric acid

  • Manivel, P.
    • Corrosion Science and Technology
    • /
    • 제16권4호
    • /
    • pp.187-193
    • /
    • 2017
  • Polymer amines are found to show distinct corrosion inhibition effects in acidic media. The functional groups of organic compounds have a wide role in the physical and chemical properties, for the inhibition efficiency with respect to steric factors, aromaticity, and electron density. The influence of $H^+$ ions and $Cl^-$ ions on the corrosion inhibitive effect of poly(p-aminophenol) for iron in hydrochloric acid was studied using electrochemical methods such as impedance, linear polarization, and Tafel polarization techniques. The experiments were conducted with and without the inhibitor, poly(p-aminophenol). The concentration range of $H^+$ ions and $Cl^-$ ions are from 1 M to 0.05 M and 1 M to 0.1 M, respectively. With the inhibitor poly(p-aminophenol), this study shows that inhibition efficiency decreases with the reduction of $H^+$ ion and $Cl^-$ ion concentrations in aqueous solution. Further, it reveals that the adsorption of an inhibitor on the surface of iron is dependent on the concentrations of $H^+$ and $Cl^-$ ions in the solution and the adsorption of inhibitor on the iron surface through the cationic form of amine.