• Title/Summary/Keyword: physical and chemical effects

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Studies on it's Practical Application to Auto Pneumatic Tyre and Manufacture of CBR (cis-1,4-polytutadiene Rubber) (Part. 3) On the Blend of Diene rubber and Turfdene rubber (CBR의 제조(製造) 및 이를 자동차(自動車) Tyre에 활용(活用)하는데 관(關)한 연구(硏究)(제3보(第三報)) Diene rubber와 Turfdene rubber와의 blend에 관(關)하여)

  • Lee, Hyun-O;Lee, Young-Kil
    • Elastomers and Composites
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    • v.7 no.1
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    • pp.21-37
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    • 1972
  • We have studied the blending effects of Diene NF 35R and Turfdene 1000R at various blending ratios 100/0, 70/30, 50/50, 30/70, 0/100, and of carbon black NAF and ISAF at various compounding ratios of 55 PHR, 65PHR, 75PHR for tyre tread rubber. As the results, it was found that; 1. For tyre tread rubber, as the blending ratio, Diene NF 35R/Turfdene 1000R, indicated 30/70, the physical properties we examined were most excellent. 2. Excellent result was obtained in case of carbon black compounding ratio of 63PHR. The compounding of ISAF made better result than that of HAF for tensile strength, tearing strength, and abrasion quantity. 3. Heat buildup obtained from compounding carbon black HAF indicated low temperature than that from compounding carbon black ISAF. As the compounding amount of carbon black increased, the heat buildup improved, and as the blending amount of Diene NF 35R decreased, the heat buildup dropped. 4. Carbon black was more efficient to Turfdene 1000R than to Diene NF 35R. 5. In this pysical properties, mooney viscosity, and mooney scorch time, as the compounding amount of carbon black increased, the values of mooney viscosity increased, but that of mooney scorch time dropped.

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Preparation and Effects of Low Foaming Acidic Degreasing Agents for Aluminum (알루미늄용 저기포성 산성탈지제의 제조와 그의 탈지효과)

  • Ha, Kyung-Jin;Park, Hong-Soo;Bae, Jang-Soon;Kim, Young-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.71-77
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    • 1997
  • Low foaming acidic degreasing agent(LFADAs) were prepared by blending sorbitol, n-octanoic acid, MJU-100A, Tetronix T-701, Na-dioctyl sulfosuccinate, Demol C, and phosphoric acid. The physical properties of LFADAs tested with aluminum specimen showed the following results ; when 3wt% LFADA-6 was performed at $70^{\circ}C$, the degreasing rate was 95% which is comparitively good, and the percentage of etching was 0.275% which was found to be less than that of commercialized product. When 20wt% of LFADA-6 was added at $65^{\circ}C$, the percentage of derusting was 92% and the good defoaming effect proved by following low foaming power tests respectively : Ross and Miles, and Ross and Clark methods.

Synthesis, Characterization and Correlation Analysis in Styryl 6-Methoxy-2-Naphthyl Ketones (Styryl-6-Methoxy-2-Naphthyl Ketone 유도체의 합성 및 특성 분석)

  • Thirunarayanan, G.
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.115-124
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    • 2007
  • A series of α, β-unsaturated ketones are synthesized by Crossed - Aldol condensation reaction, from ecofriendly 6-methoxy-2-naphthyl ketones and substituted benzaldehydes under solvent free conditions using silica-sulfuric acid as a catalytic reagent. The yields of ketones are more than 90% and the catalyst was reusable for further run. There is no appreciable decrease in the yield of product and the activity of catalyst. These chalcones were characterized by their physical constants and spectral data (IR, 1H-, 13C-NMR and Mass). These spectral data are subjected to correlate various Hammett substituent constants with single and multiparameter correlation equations. From the results of statistical analysis the influence of electronic effects of substituents on the spectral data of the ketones were explained.

Development of a Novel Bioreactor System for the Treatment of Gaseous Benzene

  • Yeom, Sung-Ho;Daugulis, Andrew J.;Yoo, Young-Je
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.73-76
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    • 2000
  • A novel, continuous bioreactor system combining a bubble column (absorption section) and a two-phase bioreactor (degradation section) has been designed to treat a gas stream containing benzene. The bubble column contained hexadecane as an absorbent for benzene, and was systemically chosen considering physical, biological, environmental, operational and economic factors. This solvent has infinite solubility for benzene and very low volatility. After absorbing benzene in the bubble column, the hexadecane served as the organic phase of the two-phase partitioning bioreactor, transferring benzene into the aqueous phase where it was degraded by Alcaligenes xylosoxidans Y234. The hexadecane was then continuously recirculated back to the absorber section for the removal of additional benzene. All mass transfer and biodegradation characteristics in this system were investigated prior to operation of the integrated unit, and these included: the mass transfer rate of benzene in the absorption column, the mass transfer rate of benzene from the organic phase into the aqueous phase in the two-phase bioreactor, the stripping rate of benzene out of the two-phase bioreactor, etc. All of these parameters were incorporated into model equations, which were used to investigate the effects of operating conditions on the performance of the system. Several experiments were conducted to show the feasibility of this system. This process is believed to be very practical for the treatment of high concentrations of gaseous pollutants.

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Studies on it's Practical Application to Auto Pneumatic Tyre and Manufacture of CBR (Part 2.) On the Blend of Diene Rubber and SBR (CBR의 제조(製造) 및 이를 자동차(自動車) tyre에 활용(活用)하는데 관(關)한 연구(硏究) (제2보(第二報)) Diene rubber와 SBR와의 blend에 관(關)하여)

  • Lee, Hyan-O;Lee, Young-Kil
    • Elastomers and Composites
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    • v.6 no.2
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    • pp.47-63
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    • 1971
  • We have studied the blending effects of Diene 33R and styrenebutadiene rubber at various blending ratios of 100/0, 70/30, 50/50, 30/70, 0/100, and of carbon black HAF and ISAF at various compounding ratios of 55 PHR, 65 PHR, 75 PHR for tyre tread rubber. As the results, it was found that ; 1. For tyre tread rubber, when the blending ratio, Diene NF 35R/SBR 1778, indicated 30/70, the physical properties we examined were most excellent. 2. Excellent result was obtained in case of carbon black compounding ratio of 65 PHR. The compounding of ISAF made better result than that of HAF for abrasion quantity, tearing strength, and tensile strength. 3. Heat buildup obtained from compounding carbon black HAF indicated low temperature than that from compounding carbon black ISAF. As the compounding amount of carbon black increased, the heat buildup improved. And as the blending amount of Diene NF 35R decreased, the heat buildup dropped. 4. Carbon black was more efficient to SBR than to Diene Rubber. 5. It is a shortage that elongation revealed low price.

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Changes in Physical Properties of Dredged Soils by Drying (건조에 의한 준설 매립 지반에 물리적 특성변화)

  • Yonn Yong-Han;Kim Won-Tae
    • Journal of the Korean Institute of Landscape Architecture
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    • v.34 no.2 s.115
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    • pp.36-43
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    • 2006
  • This study was carried out to determine the ways in which drying improves and develops dredged soils which exist widely in the lowlands of Korea. Before drying there were large variations in the fundamental physico-chemical properties of dredged soils collected from different places. In the sample soils, saturated hydraulic conductivity decreased gradually with an increase in bulk density with the exception that in air-dried soils a reverse trend was observed. Also in the sample soils, the sedimentation volume and the consistency limits decreased gradually with the decrease in soil water content after the air-drying treatment. The porosity of the sample soils decreased from $0.67{\sim}0.87m^3/m^3\;to\;0.58{\sim}0.66m^3/m^3$ and the liquid-phase range decreased from $0.41{\sim}0.83m^3/m^3\;to\;0.29{\sim}0.71m^3/m^3$. The solid-phase range of sample soils increased $0.13{\sim}0.33m^3/m^3\;to\;0.24{\sim}0.37m^3/m^3$ same as above with air-drying treatment. In conclusion the air-drying treatment caused an irreversible effect on some physical properties. Accordingly, these facts indicate that the effects of air-drying treatment on these properties are considered to be resulted from irreversible changes in the structural status of the sample soils.

Defect Chemistry of the Mixed Conducting Cage Compound Ca12Al14O33

  • Janek, J.;Lee, D.K.
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.99-105
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    • 2010
  • The electrical transport properties of mayenite ($Ca_{12}Al_{14}O_{33}$ or $12CaO{\cdot}7Al_2O_3$; mostly abbreviated as $C_{12}A_7$) can be controlled in a wide range by varying the oxygen deficiency: At high temperatures mayenite becomes either an oxygen solid electrolyte, a mixed ionic/electronic conductor or an inorganic electride with metal-like properties upon chemical reduction (removing oxygen). The underlying defect chemistry can be understood on the basis of a relatively simple model-despite the complex cage structure: A point defect model based on the assumption that the framework $[Ca_{12}Al_{14}O_{32}]^{2+}$ acts as a pseudo-donor describes well the high temperature transport properties. It accounts for the observed conductivity plateau at higher oxygen activities and also describes the experimentally observed oxygen activity dependence of the electronic conductivity with -1/4 slope at temperatures between 800 and $1000^{\circ}C$. Doping effects in mayenite are still not well explored, and we review briefly the existing data on doping by different elements. Hydration of mayenite plays a crucial role, as Mayenite is hygroscopic, which may be a major obstacle for technical applications.

Electro-chemical Removal Properties of Water Pollutants by Ag-ACF from Piggery Waste

  • Oh, Won-Chun;Bae, Jang-Soon;Ko, Young-Shin
    • Carbon letters
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    • v.7 no.2
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    • pp.105-113
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    • 2006
  • The electro-chemical removal (ECR) of water pollutants by metal-ACF electrodes from wastewater was investigated over wide range of ECR time. The ECR capacities of metallic ACF electrodes were related to physical properties such as adsorption isotherm, surface area and pore size and to reaction time. Surface morphologies and elemental analysis for the metal supported ACFs after electro-catalytic reaction were investigated by scanning electron microscopy (SEM) and energy disperse X-ray (EDX) to explain the changes in adsorption properties. The IR spectra of metallic ACFs for the investigation of functional groups show that the electro-catalytic treatment is consequently associated with the removal of pollutants with the increasing surface reactivity of the activated carbon fibers. The metal-ACFs were electro-catalytically reacted to waste water to investigate the removal efficiency for the COD, T-N, $NH_4$-N, $NO_3$-N and $NO_2$-N. From these removal results of the piggery waste using metallic ACFs substrate, satisfactory removal performance was achieved. The removal efficiency of the metallic ACFs substrate was mainly determined by the properties of the material for adsorption and trapping of organics, and catalytic effects.

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Estimation of the Relative Risk of the Elderly with Different Evacuation Velocity in a Toxic Gas Leakage Accident (독성물질 누출 시 대피 속도 차이에 따른 고령자의 상대적 위험도 산정)

  • Lee, H.T.;Kwak, J.;Park, J.;Ryu, J.;Lee, J.;Jung, Seungho
    • Journal of the Korean Society of Safety
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    • v.34 no.6
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    • pp.13-21
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    • 2019
  • Leakage accidents in businesses dealing with hazardous chemicals can have a great impact on the workers inside the workplace, as well as residents outside the workplace. In fact, there were cases where hazardous chemicals leaked from many businesses. As a result, the Chemicals Control Act(CCA) was enacted in 2015, the Ministry of Environment introduced an Off-site Risk Assessment(ORA). The purpose of the ORA is to secure safety from the installation of the design of the workplace facilities so that chemical accidents of hazardous chemical handling facilities do not cause human or physical damage outside the workplace. In general, the ORA qualitatively determines where a protected facility is within the scope of the accident scenario. However, elderly who belong to the sensitive group is more sensitive than the general group under the same chemical accident effect, and the extent of the damage is serious. According to data from the Korea National Statistic Office, the number of elderly people is expected to increase steadily. Therefore, a quantitative risk analysis considering the elderly is necessary as a result of a chemical accident. In this study, accident scenarios for 14 locations were set up to perform emergency evacuation due to toxic gas leakage of Cl2(Chlorine) and HF(Hydrogen Fluoride), and the effects of exposure were analyzed based on the evacuation velocity difference of age 20s and 60s. The ALOHA(Areal Locations of Hazardous Atmospheres) program was used to calculate the concentration for assessing the effects. The time of exposure to toxic gas was calculated based on the time it took for the evacuation to run from the start point to the desired point and a methodology was devised that could be applied to the risk calculation. As a result of the study, the relative risk of the elderly, the sensitive group, needs to be determined.

The Differences in Chemical Composition, Physical Quality Traits and Nutritional Values of Horse Meat as Affected by Various Retail Cut Types

  • Seong, Pil Nam;Park, Kyoung Mi;Kang, Geun Ho;Cho, Soo Hyun;Park, Beom Young;Chae, Hyun Seok;Ba, Hoa Van
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.1
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    • pp.89-99
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    • 2016
  • The effects of retail cut type on chemical, quality and nutritional characteristics of horse meat were studied. Jeju female breed horses (n = 9) at 32-mo-old were slaughtered and the carcasses at 24 h post-mortem were fabricated into 10 retail cuts including: tender-loin, loin, strip-loin, shoulder-chuck-roll, shoulder-clod, top-round, outside-round, brisket, short-plate-brisket, and shank. The results revealed that all of parameters (chemical, meat quality and nutritional composition) examined significantly (p<0.05) differed between the cuts. The chemical composition range (minimum to maximum) of cuts was found as such: moisture 65.06% to 71.69%; protein 19.07% to 21.28%; collagen 1.40% to 2.45%; fat 2.56% to 12.14% and cholesterol 55.76 to 79.50 mg/100 g. Shoulder-chuck-roll had the highest pH and water-holding capacity, while top-round had the highest cooking loss. Shear force ranged between the cuts from $2.80kg/cm^2$ to $4.98kg/cm^2$. The Cu, Fe, and Zn contents ranged between the cuts from 1.52 mg/kg to 2.75 mg/kg, 21.25 mg/kg to 30.85 mg/kg, and 16.51 mg/kg to 40.42 mg/kg, respectively. Additionally, most of the cuts studied showed favorable polyunsaturated fatty acid/saturated fatty acid, n-3/n-6 and essential amino acid/non-essential amino acid ratios.