• 공업화학
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• 제3권3호
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• pp.422-429
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• 1992

본 연구는 고무와 황동피복 코드간의 접착력 향상을 위하여 사용되는 resorcinol formaldehyde(RF) resin과 hexamethoxymethylmelamine(HMMM)이 고무 컴파운드내에서 나타내는 morphology와 접착특성에 대하여 고찰하였다. 가황후 resin은 구형의 형태로 시편 전체에 고르게 분포되어 있었고 그의 입경은 약 $2000{\AA}$정도였다. 코드와 함께 가황시킨 시편에서 코드 주위에 존재하는 resin함량이 감소한 것으로 보아 resin이 코드쪽으로 이동이 있었던 것으로 생각된다. 또한 모듈러스는 methylene donor인 HMMM의 양이 많을수록 증가하였으며, 접착층이 더 두껍게 형성되었다. 접착력은 열 노화에 의하여 상실되며 이는 대부분 초기에 발생함을 알 수 있었다. 접착컴파운드에서 가장 유리한 RF resin과 HMMM의 비는 물성, 접착층의 안정성, 열노화특성 등을 고려할 때 1 : 0.9이었다.

• 대한방사선기술학회지:방사선기술과학
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• 제44권4호
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• pp.335-342
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• 2021

Studies on the side effects of contrast agents are being discussed based on various cases, but studies analyzing the chemical structure of the underlying contrast agents are difficult to understand as the manufacturers have not disclosed them. Therefore, in this study, the chemical structure of the contrast medium was analyzed using ¹H-NMR spectrometer for Omnipaque contrast medium prepared from Iohexol, which is a nonionic iodide contrast medium, Xenetix contrast medium from Iobitridol, and Iomeron contrast medium from Iomeprol. As a result, it was found that the Omnipaque contrast medium of Iohexol had 6 carboxyl groups, 3 carbonyl groups, 4 amine groups, 1 methyl group, and 2 cyano groups. It was found that the Xenetix contrast medium of the iobitridol formulation had 6 carboxyl groups, 3 carbonyl groups, 2 amine groups, and 4 cyano groups. It was found that the Iomeron contrast agent of the Iomeprol formulation had 5 carboxyl groups, 3 carbonyl groups, 4 amine groups, 1 methyl group, and 2 cyano groups. As shown in this study, the chemical structure of the non-ionic monomer contrast agent increases its affinity with water by binding a number of hydroxyl groups (OH) to the carboxyl group. It is necessary to accurately identify each of these factors and analyze the physical and chemical changes of the contrast medium according to various environmental factors.

• 센서학회지
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• 제26권2호
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• pp.96-100
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• 2017

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively studied as the active material in ammonia gas sensor because of its fast response time, high conductivity and environmental stability. It is well known that a post annealing process for organic devices based on PEDOT:PSS significantly increases the device performance. In this study, we propose the solvent annealing of PEDOT:PSS and investigated its effects. As a results, post solvent annealing on PEDOT:PSS lead to the surface chemical and physical properties change. These changes result in improved conductivity of the PEDOT:PSS. In additional, ammonia sensitivity of solvent annealed PEDOT:PSS become higher than pristine polymer film. The enhancement is mainly caused by the depletion of gas barrier PSS and structural re-forming PEDOT networks. We believe that the post solvent annealing is a promising method to achieve highly sensitivity PEDOT:PSS films for applications in efficient, low-cost and flexible ammonia gas sensor.

• Korean Chemical Engineering Research
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• 제50권1호
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• pp.167-172
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• 2012

탄성체로써 EPDM 이오노머와 결정성 보강 고분자로써 폴리아미드-6를 이용하는 새로운 형태의 열가소성 탄성체를 제조하여 이들의 열적 성질을 고찰하였다. 특히 산화아연을 이용하여 말레인화 EPDM으로부터 EPDM 이오노머를 제조할 때 중화도의 영향과 블렌드 중 폴리아미드-6 함량의 영향을 살펴보았다. 중화와 블렌드 공정은 이축압출기를 이용하였다. 말레인화 EPDM의 중화는 냉각 결정화 온도를 상승시켰다. 폴리아미드-6의 높은 결정성은 보강재 효과를 보였다. 블렌드에서 말레인화 EPDM과 폴리아미드-6 사이의 이미드 형성으로 폴리아미드-6의 분산이 양호하게 나타났다. EPDM 이오노머와 폴리아미드-6로 제조한 열가소성 탄성체는 균형적인 기계적 물성과 향상된 내열성을 나타내었다.

• 한국식품영양과학회지
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• 제41권11호
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• pp.1565-1570
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• 2012

본 연구는 제과분야에서의 쌀가루의 이용도를 높이기 위하여 쌀가루를 이용하여 쿠키를 제조하였으며, 유화제인 sodium stearoyl lactylate(SSL), sugar ester(SE), diacetyl tartaric ester of monoglyceride(DATEM)를 3, 6 및 9% 첨가한 쌀가루의 호화특성과 반죽 및 쌀쿠키의 품질특성을 측정하였다. RVA 측정 결과, 유화제를 첨가한 쌀가루의 최고점도는 감소하였으며 유화제 중 DATEM 첨가에 의한 감소폭이 가장 작았다. 반죽의 경도는 유화제의 첨가량이 증가함에 따라 증가하였으며 DATEM을 첨가 시 경도가 가장 크게 증가하였다. 또한 쌀쿠키의 경도는 SSL 및 SE 첨가에 의해서는 증가하였고 DATEM의 첨가는 상대적으로 낮은 경도를 보였다. 반죽 및 쌀쿠키의 밀도는 모두 SSL과 SE 첨가에 의해서 증가하였으나 DATEM은 반죽 및 쌀쿠키의 밀도를 감소시켰고, 퍼짐성의 결과에서도 DATEM에 의해 쌀쿠키의 퍼짐성은 낮은 값을 보였다. 이 결과를 통해 쌀쿠키 제조 시 유화제의 사용으로 쿠키의 물성을 조절할 수 있는 것을 확인하였으며, SSL이나 SE와 비교했을 때, DATEM의 첨가는 쌀가루의 수분과의 작용을 보다 용이하게 하여 반죽의 경도를 높이고 쌀쿠키의 밀도 및 경도를 감소시켜 부드러운 쌀쿠키의 물성을 나타내는데 효과적인 것으로 확인되었다.

• 펄프종이기술
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• 제46권6호
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• pp.94-102
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• 2014

The physical and chemical properties of recycled fibers from mixed waste paper are more and more deteriorated because of unknown history of recycling times. In order to improve the mechanical properties of liner paper, the recycled fibers from wasted cotton clothes were used in papermaking process, and their applicabilities were evaluated in several points of fiber modification. Thus, two kinds of fiberizing methods from waste cotton clothes were considered by using rotary sandpaper and grinder mill. Finally, the rotary sandpaper method was relatively desirable in preserving longer fiber length and fibrillated fiber surface. The recycled cotton fibers by swelling treatment with NaOH and bleaching with reductive chemicals were mixed with OCC fibers, and the handsheets were prepared to basis weight of $80g/m^2$ and evaluated the mechanical properties of paper. The fibrous properties showed outstanding results in freeness and WRV improvements by alkali treatment and high brightness by reductive bleaching treatment. The physical and mechanical properties of sheet by mixing OCC fibers and recycled cotton fibers were also highly improved in tensile, burst strength and specially folding resistance.

• Safety and Health at Work
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• 제14권1호
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• pp.1-9
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• 2023

Background: Firefighting involves exposure of firefighters to risks related to this activity, serious injuries, and occupational diseases are recorded. There are other consequences such as thermal and emotional stress. This systematic review is proposed in order to analyze the risks and consequences faced by these workers and thus provide elements to improve safety management systems in institutions. Method: A descriptive observational study of systematic literature review on the risks and consequences of exposure to firefighters' activity was proposed, and the information was analyzed and described based on the available data and according to the variables determined. Results: The studies showed data on mechanical, physical, chemical, psychosocial risks, workers' perception and resilience, and epidemiological data. Information related to firefighters' activity on falls and slips, exposure to noise, and high concentrations of carbon monoxide is detailed. In addition, the relationship between burnout, cognitive, and physical fatigue as adverse effects on health and performance is mentioned. Conclusions: Among the preventive measures, the use of personal protective equipment is suggested, incorporation in prevention programs of information on exposure to risk factors, as well as the implementation of models that can predict the perception of workers, additionally, the generation of management systems with safety climate models for fire departments.

• Journal of Forest and Environmental Science
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• 제31권1호
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• pp.14-23
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• 2015

In this study, we investigated the effects of three land uses on soil properties in two soil layers; surface soil (0~15 cm) and subsoil (15~30 cm). Soil samples were collected from planted forest, barren lands and cultivated lands from different areas in Chittagong Cox's Bazar and analyzed for some physical and chemical properties. Results showed that soil textural class varied from sandy clay loam in planted forest and barren land site to sandy loam in cultivated soils. Maximum water holding capacity was higher in forest followed by barren land and the lowest in cultivated lands. At both soil depths, soils of cultivated land showed the highest values of bulk density (1.42 to $1.50g\;cm^{-3}$), followed by barren lands (1.37 to $1.46g\;cm^{-3}$) and the least (1.32 to $1.45g\;cm^{-3}$) in forest soils. Total porosity decreased with depth ranging from 40.24% to 41.53% in subsoils and from 42.04 to 43.23% in surface soil of cultivated and of planted forest sites respectively. The result further revealed that organic carbon (OC) and total nitrogen (TN) contents were higher in the planted forest soil than in other two land uses. The soils of all land uses under study are acidic in nature and the lowest pH was found in both surface and subsoils of barren land. Cultivated soil contained the highest amount of available P, Ca, Mg and K in both surface soil and subsoils. In contrast, barren site had the lowest contents of available P, Ca, Mg and K in both layers. The soil organic carbon (SOC) and total N storage were higher in planted forest than in barren and cultivated land uses.

• Bulletin of the Korean Chemical Society
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• 제29권3호
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• pp.627-640
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• 2008

The geometrical structures, atomic charges, and relative energies of tetracoordinated Pd complexes [PdCl3Z (Z = Cl-, Br-, OH?-, H2O, NH3, PH3), PdCl2Z2 (Z = Br-, OH?-, H2O, NH3, PH3), PdZ?2X (Z = Cl-, OH?-, H2O, NH3, PH3; X = oxalate, O2-?CCO2-), and PdZ2Y (Z = Cl?-, OH?-, H2O, NH3, PH3; Y = succinate, CO2-?CHCHCO2-?)] and the ligand exchange reactions of the Pd complexes were investigated using the ab initio second order Mller-Plesset perturbation (MP2) and Density Functional Theory (DFT) methods. The geometrical characteristics of the tetracoordinated Pd(II) complexes with mono- and bidentate ligands, the effects of the atomic charges for the charged and uncharged ligands, the (dz2-p ) interactions between the dz2-orbital of Pd(II) and the p -orbital of bidentates, and the relative stabilities between the isomers of PdCl2Z2 and PdZ2Y were investigated in detail. The potential energy surfaces for the ligand exchange reactions used for the conversions of {[PdCl2(NH3)2] + H2O} to {[PdCl(NH3)2(H2O)]+ + Cl?-?} and {[PdCl2(PH3)2] + H2O} to {[PdCl(PH3)2(H2O)]+ + Cl?-?]} were investigated. The geometrical structure variations, molecular orbital variations (HOMO and LUMO), and relative stabilities for the ligand exchange processes were also examined quantitatively.

• 전자공학회논문지
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• 제51권3호
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• pp.177-184
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• 2014

화학기상증착의 텅스텐 실리사이드 듀얼 폴리 게이트 구조에서 플로린이 게이트 산화막에 미치는 영향을 전기적 물리적 측정 방법을 사용하여 연구하였다. 플로린을 많이 함유한 텅스텐 실리사이드 NMOS 트랜지스터에서 채널길이가 감소함에 따라 게이트 산화막 두께는 감소하여 트랜지스터의 롤업(roll-off) 특성이 심화된다. 이는 게이트 재 산화막 열처리 공정에 의해 수직방향으로의 플로린 확산과 더불어 수평방향인 게이트 측면 산화막으로의 플로린 확산에 기인한다. 채널길이가 짧아질수록 플로린의 측면방향 확산거리가 작아져 수평방향 플로린 확산이 증가하고 그 결과 게이트 산화막의 두께는 감소하게 된다. 반면에 PMOS 트랜지스터에서는 P형 폴리를 만들기 위한 높은 농도의 붕소가 플로린의 게이트 산화막으로의 확산을 억제하여 채널길이에 따른 산화막 두께 변화 특성이 보이지 않는다.