• 제목/요약/키워드: physical and chemical effects

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소결 분위기와 조성이 $TiB_2$-AlN-BN 복합체의 반응 가압 소결에 미치는 영향 (Effect of Atmosphere and Composition on the Fabrication of $TiB_2$-AlN-BN Composites by Reactive Hot Pressing)

  • 이기민;김형종;최헌진;이준근
    • 한국세라믹학회지
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    • 제37권7호
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    • pp.645-650
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    • 2000
  • Effects of the chemical composition and sintering atmosphere on the formation of reaction phases and physical properties of reactive hot-pressed TiB2-AlN-BN composites were investigated. At N2 atmosphere, TiN was formed by the reaction between Ti and N2, which inhibited the densification and results in inferior mechanical-and electrical properties of the composites. However, at Ar atmosphere, enhanced densification and physical properties of composites were obtained due to that the TiN formation reaction was excluded. Densification of the composites was also hindered by BN, therefore, inferior mechanical-and electrical properties of composites were obtained with amount of BN in the starting materials. At Ar atmosphere, TiB2-AlN-BN composites having 318 MPa of flexural strength, 3.5 MPa.m1/2 of fracture toughness and 276$\mu$Ω.cm of electrical resistivity were fabricated from mole ratio 1:2:1.6 of Ti-Al-BN mixtures.

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고무조성물의 물리적 성질에 영향을 미치는 주요인자에 대한 통계학적 해석 (Statistical Analysis of Main Factors With Affecting the Physical Properties of Rubber Compounds)

  • 이석;박남국
    • Elastomers and Composites
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    • 제32권1호
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    • pp.20-28
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    • 1997
  • This study have Investigated the effect of various factors related to the physical properties of vulcanizated rubber compounds. rubber type, carbon black type and carbon black loading were selected as main factors and evaluation were tested by tables of orthogonal arrays with 3 factors and 3 levels. rubber types have affected cure time, tensile strength, and $T_g$ as main factor and carbon black loading have affected viscosity, scorch time, maximum torque, hardness, 300% modulus, rebound, heat build-up, $0\;&\;60^{\circ}C$ tangent delta, PICO and CUT/CHIP loss as main factor but the effects of carbon black type have affected only bound rubber content.

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Characterization of Clay Minerals in Ranch Pasture

  • Kang, Sangjae;Jang, Jeonghun;Park, Nayun;Park, Junhong;Choi, Seyeong;Park, Man;Lee, Changhee;Lee, Donghoon;Zhang, Yongseon
    • 한국토양비료학회지
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    • 제49권1호
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    • pp.53-59
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    • 2016
  • This study deals with the distribution of the clay minerals separated from clay fractions of ranch pastures in Korea and their chemical and mineralogical properties. Crystalline phases of the clay minerals were identified by powder X-ray diffraction (XRD) pattern and FT-IR spectra, and their relative chemical compositions were also analyzed by X-ray flourescence spectrometry (XRF). Primary minerals consisted mainly of quartz and mica and chlorite and kaolinite along with a trace of swelling micas were identified as secondary clay minerals. However, the relative content of these clay minerals was different with the locations, which led to significant effects on physical and chemical properties of soils like inorganic elemental composition. In particular, $SiO_2$ content was higher in Gochang ranch pasture than in other ranch pasture. Infrared (IR) spectra did not indicate any significant differences in organic functional groups among the locations. This study clearly showed that ranch pastures had different relative content of clay minerals and chemical properties depending on the location and consequently that those properties are worthy to be taken into account for soil amendment.

Physical and Mechanical Properties of Light Red Meranti Treated with Boron Preservatives

  • Man Djun LEE;Ridge Wei Cheong TANG;Zeno MICHAEL;Miqdad KHAIRULMAINI;Azmi ROSLAN;Ahmad Faidzal KHODORI;Hazim SHARUDIN;Pui San LEE
    • Journal of the Korean Wood Science and Technology
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    • 제52권2호
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    • pp.157-174
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    • 2024
  • This study investigates the influence of varying concentrations of boric acid (BA) preservative on the physical and mechanical properties of light red meranti (LRM) found in Sarawak. LRM or Shorea leprosula samples were treated with various concentrations of BA via the dip diffusion method using American Society for Testing and Materials (ASTM) standards. The physical property, particularly the retention rate and mechanical properties, bending strength, modulus of elasticity (MOE), tensile and compression strength parallel to grain of impregnated and control samples were tested to determine the effects of BA preservative. The retention rate was found to increase with increasing BA concentration and higher surface area to volume ratio. The mechanical properties in terms of the MOE and tensile strength parallel to grain were found to be greater than those of the control samples, whereas the bending strength and tensile strength parallel to grain were lower. Amongst the results, only the retention rate and MOE showed significant interaction effects at 5% level of significance between all factors tested (samples size and BA concentration for retention rate and BA concentration for MOE).

Study on simultaneous heat and mass transfer during the physical vapor transport of Hg2Br2 under ㎍ conditions

  • Kim, Geug Tae
    • 한국결정성장학회지
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    • 제29권3호
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    • pp.107-114
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    • 2019
  • A computational analysis has been carried out to get a thorough and full understanding on the effects of convective process parameters on double-diffusive convection during the growth of mercurous bromide ($Hg_2Br_2$) crystals on earth and under ${\mu}g$ conditions. The dimensional maximum magnitude of velocity vector, ${\mid}U{\mid}_{max}$ decreases much drasticlly near Ar = 1, and, then since Ar = 2, decreases. The ${\mu}g$ conditions less than $10^{-2}g$ make the effect of double-diffusion convection much reduced so that adequate advective-diffusion mass transfer could be obtained.

Quality Comparisons of Tomatoes Irradiated with Light, Treated with Ethylene, and Stored in Darkness

  • Lee, Gwi Hyun;Bunn, Joe M.;Han, Young J.
    • Agricultural and Biosystems Engineering
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    • 제1권2호
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    • pp.81-87
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    • 2000
  • Quality characteristics of tomatoes irradiated with light (red light of far-red light followed two days later with a red light treatment), treated with ethylene, and stored in darkness were evaluated by subjective sensory and objective physical and chemical evaluations. Overall and individual liking evaluations and sensory evaluations were made by an untrained panel of eighteen people. A rankin gof treatments for consumer (panelist) acceptability was also conducted by the panel. Physical and chemical evaluations included surface color measurement (L*, a*, and b*), mechanical puncturing (firmness), soluble solids content (SSC), titratable acidity(TA), and tomato juice pH. Sensory data showed that outside color, inside color, and flavor of tomatoes treated with red light (R) and far-red light/red light (FR/R) were scored significantly higher than those of tomatoes treated with ethylene and those kept in darkness. The L* values for tomatoes treated with R and FR/R were lower (more darkening) than those for tomatoes treated with ethylene and those stored in darkness. Tomatoes treated with FR/R had the highest A* values, followed by those irradiated with R, treated with ethylene, and kept in darkness, respectively. Sensory values for firmness were similar for tomatoes treated with R, FR/R, and ethylene. Treatments had no significantly different effects on sweetness and acidity. There were no significantly different effects between treatments for pH, SSC, TA, and SSC/TA. From observations made during the study, it was suggested that R irradiation stimulated red color development in tomatoes after it had been delayed by FR irradiation. Consumer acceptability for tomatoes with either R or FR/R treatment was significantly higher than that for tomatoes treated with ethylene or stored in darkness. panelists' overall liking scores correlated well with all sensory variables except acidity, and also correlated highly with inside color, flavor, and sweetness (P<0.001). Overall liking versus flavor had the most pronounced relationship (r=0.78, P<0.001).

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세라믹 막여과 정수처리 공정에서 유입수질 및 막여과유속이 막오염 형성에 미치는 영향 (Effects of membrane fouling formation by feed water quality and membrane flux in water treatment process using ceramic membrane)

  • 강준석;박서경;이정준;김한승
    • 상하수도학회지
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    • 제32권2호
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    • pp.77-87
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    • 2018
  • In this study, the effects of operating conditions on the formation of reversible and irreversible fouling were investigated in the filtration using ceramic membrane for water treatment process. The effect of coagulation pretreatment on fouling formation was also evaluated by comparing the performance of membrane filtration both with and without addition of coagulant. A resistance-in-series-model was applied for the analysis of membrane fouling. Total resistance (RT) and internal fouling resistance (Rf) increased in the membrane filtration process without coagulation as membrane flux and feed water concentrations increased. Internal fouling resistance, which was not recovered by physical cleaning, was more than 70% of the total resistance at the range of the membrane flux more than $5m^3/m^2{\cdot}day$. In the combined process with coagulation, the cake layer resistance (Rc) increased to about 30-80% of total resistance. As the cake layer formed by coagulation floc was easily removed by physical cleaning, the recovery rate by physical cleaning was 54~90%. It was confirmed from the results that the combined process was more efficient to recover the filtration performance by physical cleaning due to higher formation ratio of reversible fouling, resulted in the mitigation of the frequency of chemical cleaning.

지상 및 미소중력 환경에서 물리적 승화법 공정에 미치는 불순물의 영향 분석: 염화제일수은에 대한 응용성 (Numerical Analysis for Impurity Effects on Diffusive-convection Flow Fields by Physical Vapor Transport under Terrestrial and Microgravity Conditions: Applications to Mercurous Chloride)

  • 김극태;권무현
    • 공업화학
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    • 제27권3호
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    • pp.335-341
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    • 2016
  • 본 연구에서는 지상 및 미소중력환경하에서 물리적 승화법 공정에서의 확산-대류유동에 미치는 불순물의 영향을 이론적으로 $Hg_2Cl_2-I_2$ 시스템에 적용하여 규명하는 것이다. 이론적 해석은 증기상에서 확산-대류 흐름, 열 및 물질전달을 속도 벡터 흐름, 유선, 온도, 농도 분포를 통하여 제시된다. 결정 영역에서의 전체 몰플럭스는 중력가속도와 성분 $I_2$, 불순물에 상당히 민감하게 반응한다. 성분 $I_2$을 증가시켰을 때, 농도 대류효과는 확산-대류 유동흐름을 안정화시키는 경향이 있다. 지상중력가속도의 0.001환경에서는 유동흐름은 1차원포물선의 흐름 구조를 나타내며, 확산지배형태를 보여주고 있다. $10^{-3}$지상중력가속도 이하에서는 대류 영향은 무시할 수 있다.

Optimization of Bio-based Succinic Acid Production from Hardwood Using the Two Stage pretreatments

  • Jung, Ji Young;Jo, Jong Soo;Kim, Young Wun;Yoon, Byeng Tae;Kim, Choon Gil;Yang, Jae Kyung
    • Journal of the Korean Wood Science and Technology
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    • 제41권2호
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    • pp.111-122
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    • 2013
  • The steam explosion-chemical pretreatment is a more effective wood pretreatment technique than the conventional physical pretreatment by accelerating reactions during the pretreatment process. In this paper, two-stage pretreatment processes of hardwood were investigated for its enzymatic hydrolysis and the succinic acid yield from the pretreated solid. The first stage pretreatment was performed under conditions of low severity to optimize the amount of solid recovery. In the second stage pretreatment washed solid material from the first stage pretreatment step was impregnated again with chemical (alkaline or chlorine-based chemicals) to remove a portion of the lignin, and to make the cellulose more accessible to enzymatic attack. The effects of pretreatment were assessed by enzymatic hydrolysis and fermentation, after the two stage pretreatments. Maximum succinic acid yield (16.1 g $L^{-1}$ and 77.5%) was obtained when the two stage pretreatments were performed at steam explosion -3% KOH.