• Title/Summary/Keyword: physical and chemical changes

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Biodegradation of Diesel in Sea Water by Rhodococcus fascians Isolated from a Petroleum-contaminated Site (유류 오염 토양에서 분리된 Rhodococcus fascians를 이용한 해수에서의 디젤유의 분해)

  • Koo, Ja-Ryong;Moon, Jun-Hyung;Yun, Hyun-Shik
    • KSBB Journal
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    • v.24 no.5
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    • pp.453-457
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    • 2009
  • Contamination of marine environment with hazardous and toxic chemicals is more common these days. Bioremediation is the application of microorganism or microbial processes to degrade environmental contaminant. Because of low water solubility and volatility of diesel, bioremediation is more efficient than physical and chemical methods. The objective of this study is biodegradation of diesel in sea water by using Rhodococcus fascians which is isolated petroleum-contaminated soil. R. fascians was cultured on sea water containing diesel to determine the diesel degradability. Changes in biodegradability of diesel with various inoculum sizes, diesel concentrations, initial pH, and culture temperature were analyzed by TPH analysis using gas chromatography. The inoculum size 2% was effective for biodegrdation of diesel in sea water by R. fascians. When diesel concentration was 5%, the growth of cell was inhibited by the toxicity of diesel. The optimal temperature and initial pH for degradation of diesel in sea water were $27^{\circ}C$ and pH 8.

Durability of the Expanded Rice Hull as a Hydroponic Culture Medium (양액재배용 팽연화 왕겨의 적정 사용기간)

  • 임상현;김경희;안문섭;유근창
    • Journal of Bio-Environment Control
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    • v.10 no.2
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    • pp.106-110
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    • 2001
  • In an effort to evaluate the economic value and durability of the expanded rice hull as substrates, changes in the physical and chemical properties of material and plant growth in that substrate were studied. Using and electron microscope, the structure of used and new expanded rice hull substrate was examined. Considerable decomposition was found in the substrate which had been used one to three times. Compactness and lowered porosity in the used substrates were probably caused by decomposition. The results of cation analysis showed the possible destruction of cell wall of rice hulls. Abundant $Ca^{2+}$ in the substrates used for two to three times also indicated the possibility of decomposition. In tomato yield comparison, 15.2% more yield of tomato fruit in a new substrates indicated the negative effects of decomposition of one-time used substrates. Yield decreased in the substrates used for three times. if perlite substrates is used for three years before renewal and the cost of the perlite renewal is counted. 65.3% saving in the cost will be realized with the use of an expanded rice hull substrate. Another positive effect of the expanded rice hull substrate is the decrease of environmental contamination.n.

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Effect of Fermentation Vessel on Quality of Anchovy Soy Sauce (발효 담금 용기에 따른 어간장의 숙성 중 품질변화)

  • 정순경;이광수;조성환
    • Food Science and Preservation
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    • v.11 no.2
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    • pp.233-239
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    • 2004
  • Anchovy soy sauce containing anchovy sauce was ripened in different vessels at 30$^{\circ}C$ for 4 months and measured in physical, chemical, microbiolgical and sensory quality attributes. The used vessels include glass, polypropylene (PP), polyethylene terephthalate (PET), stainless, and onggi (Korean earthenware) with 628 mL. Compared to the other vessels, onggi gave the highest moisture loss, maintained consistently higher microbial counts in total aerobic bacteria, lactic acid bacteria and yeasts, and attained high protease activity in the soy sauce product. Even with high moisture loss the onggi vessel did not produce the higher product salt content than the other vessels because there was salt diffusion outward through the container wall. All of these changes of the product in onggi resulted in lower pH, higher acidity and higher amounts of free amino acids and nucleotides after 4 month period, which was desirable for sensory quality.

Characterization of LaCoO3 Perovskite Catalyst for Oxygen Reduction Reaction in Zn-air Rechargeable Batteries (아연-공기전지용 페롭스카이트 산화물 촉매의 산소환원반응 특성)

  • Sun, Ho-Jung;Cho, Myung-Yeon;An, Jung-Chul;Eom, Seungwook;Park, Gyungse;Shim, Joongpyo
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.436-442
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    • 2014
  • $LaCoO_3$ powders synthesized by Pechini process were pulverized by planetary ball-milling to decrease particle size and characterized as a catalyst in alkaline solution for oxygen reduction and evolution reaction (ORR & OER). The changes of physical properties, such as particle size distribution, surface area and electric conductivity, were analyzed as a function of ball-milling time. Also, the variations of the crystal structure and surface morphology of ball-milled powders were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The electrochemically catalytic activities of the intrinsic $LaCoO_3$ powders decreased with increasing ball-milling time, but their electrochemical performance as an electrode improved by the increase of the surface area of the powder.

Study of the Crystal Structure of a Lyocell Precursor for Carbon Fibers (탄소섬유용 리오셀 전구체의 결정구조에 관한 연구)

  • Park, Gil-Young;Kim, Woo-Sung;Lee, Su-Oh;Hwang, Tae-Kyung;Kim, Yun-Chul;Seo, Sang-Kyu;Chung, Yong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.5
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    • pp.36-42
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    • 2019
  • In this study, the pre-treatment of lyocell fabrics was performed using phosphoric acid (PA) as a phosphorus flame retardant and melamine resin (MR) as a cross-linking agent to fabricate carbon fabrics using lyocell fibers. The physical and chemical changes were investigated by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD) and weight analysis. We confirmed that the weight yield of the carbon fabrics compared to the untreated fabrics increased by 14.7%, and width and length yield of the fabrics increased by 15% and 15.5%, respectively. This may be due to the effect of promoting the dehydration reaction of cellulose, forming char on the fiber surface, which induces a crosslinking reaction in the cellulose molecule and stabilizes the structure upon pyrolysis.

Effect of Cooking Conditions on Quality Changes of Braised Kidney Beans during Storage (가열조리조건에 따른 강낭콩조림의 저장 중 품질변화)

  • Chung, Sun-Kyung;Lee, Dong-Sun;Lyu, Eun-Soon
    • Food Science and Preservation
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    • v.14 no.2
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    • pp.142-147
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    • 2007
  • We optimized braising time to improve the storage quality of braised kidney beans. The beans were prepared with different heating times between 25 and 50 min. and then stored at $10^{\circ}C$ for 20 day. Physical, chemical, microbiological, and organoleptic quality indices were monitored throughout storage. Longer braising times yielded products with lower concentrated brine coverage. Bis resulted in higher soluble contents and slightly lower water activities. Excessive heating time exposed the kidney beans to air and caused rapid microbial growth on the surfaces of the beans, which negatively affected product quality. The longest heating time of 50 min. also resulted in a large increase in product hardness. A braising time of 30 min. was best for preservation, as good sensory quality was mainatained.

Study on the characterization of dissolved organic matters in Nakdong River (낙동강의 용존 유기물질 특성에 관한 연구)

  • Heo, Seong-Nam;Park, Jeong-Min;Im, Tae-Hyo;Shin, Chan-Ki
    • Journal of environmental and Sanitary engineering
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    • v.22 no.3
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    • pp.13-26
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    • 2007
  • Changes in the characteristics of dissolved organic matter was studied at selected stations in the Nakdong river basin using physical and chemical methods. Characteristics of dissolved organic matters were analysed and assessed. Production of disinfection byproducts were also investigated. 1. Result of relatedness study among each items of analyses showed that relatedness on BOD values were highest with cattle excrement treatment facilities where there is no synthetic organic materials and relatedness on $COD_{Mn}$ were highest at the mainstream Nakdong river. In case of $COD_{Cr}$ (which has more oxidative power than $COD_{Mn}$), the values were higher in the sidestreams indicating the higher content of recalcitrant compounds. The relatedness values for the $UV_{254}$ also showed higher values in the sidestreams and treatment facilities than mainstream indicating the presence of organic aromatic compounds. 2. Ratio of DOC on total organic carbon were higher in the mainstream which is attributable to the influent particulate organic materials produced by agricultural activities. The values were 10-15% higher in the mainstream compared with sidestreams. 3. Result of biodegradability test indicate that concentrations of recalcitrant DOC were higher in the sidestreams than in the mainstream. The values of recalcitrant DOC were higher with the forest stream indicating the effect of soil oriented humic substances. 4. Result of THM production test carried out at 10 stations in the Nakdong river show that $CHCl_3$ was detected with the highest value and the value was highest at Waekwan station.

Physical Property of Carbon Fiber Reinforced Thermoplastic Polymer based Composites by Repeating Processing of PP Composition (PP 복합 조성물의 반복 가공에 의한 열가소성 폴리머 탄소섬유 강화 복합재료의 물리적 특성 변화 연구)

  • Jin-Woo Lee;Jae-Young Lee;Seoung-Bo Shin;Jae-Hyung Park;Hyun-Ju Park;Kyung-Hun Oh;Jin-Hyuk Huh;Yun-Hae Kim;Ji-Eun Lee
    • Composites Research
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    • v.37 no.2
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    • pp.68-75
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    • 2024
  • Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

A Study on the Characteristics of Residual Stress in the Manufacturing Process of AISI 1536V and AISI A387 (제조공정에 따른 강종별 잔류응력 특성에 관한 연구; AISI 1536V, AISI A387)

  • Hwang, Sung-Kug;Moon, Jeong-Su;Kim, Han Joo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.9
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    • pp.100-106
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    • 2020
  • This study analyzes the residual stress of AISI 1536V for an engine shaft of the shipbuilding industry and AISI A387 for a reactor shell of the chemical refining industry by the hole drilling method with a strain gauge rosette, which transforms fine mechanical changes into electrical signals. Tensile residual stress is generated in the forging and heat treatment process because specimens are affected by thermal stress and metal transformation stress. In the heat treatment process, the residual stress of AISI A387 is almost 170% the yield strength at 402 MPa. Since during the machining process, variable physical loads are applied to the material, compressive residual stress is generated. Under the same condition, the mechanical properties greatly affect the residual stress during the machining process. After the stress-relieving heat treatment process, the residual stress of AISI A387 is reduced below the yield strength at 182 MPa. Therefore, it is necessary to control the temperature, avoid rapid heat change, and select machining conditions depending on the mechanical properties of materials during manufacturing processes. In addition, to sufficiently reduce the residual stress, it is necessary to study the optimum condition of the stress-relieving heat treatment process for each material.

Preparation and Reactivity of ZnO-Al$_2$O$_3$ Desulfurization Sorbents for Removal H$_2$S ($H_2S$제거를 위한 ZnO-$Al_2O_3$ 탈황제의 제조 및 반응특성 연구)

  • 박노국;이종욱;류시옥;이태진;김재창
    • Journal of Energy Engineering
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    • v.11 no.2
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    • pp.136-141
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    • 2002
  • Advanced zinc-based sorbents, ZA, for Hot Gas Desulfurization (HGD) process in Integrated Gasification Combined Cycle (IGCC) systems were formulated with $Al_2$O$_3$ as support to enhance the reactivity and their reactive characteristics was also investigated in this study. Changes in the physical and chemical properties of the sorbents based on both the mole ratios of ZnO/Al$_2$O$_3$ and the calcination temperatures were examined by a XRD. The results obtained in our desulfurization-regeneration cycle tests demonstrated that degradation of sorbents due to the heat generation could be improved through the optimization of the $Al_2$O$_3$ contents and of the calcination temperatures. From the durability study it is concluded that the prepared ZA sorbents with additives have the desirable features for HGD.