• Title/Summary/Keyword: physical and chemical changes

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Geographical features and types and changes of agricultural land uses in North Korea

  • Lee, Kyo-Suk;Ryu, Jin-Hee;Lee, Dong-Sung;Hong, Byeong-Deok;Seo, Il-Hwan;Kim, Sung Chul;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.46 no.1
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    • pp.205-217
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    • 2019
  • The aim of this study was to identify land resources because food production and supply in North Korea have been at risk due to variations in its seasonal climate. More than three-fifths of the soils are locally derived from the weathering of granitic rocks or various kinds of schists developed from crystalline rocks. Well-developed reddish brown soils derived from limestone are found in the North Hwanghae province and in the southern part of the South Pyeongan province. Additionally, a narrow strip of similarly fertile land runs through the eastern seaboard of the Hamgyong and Kangwon Provinces. The loss of clay particles and organic matter are major causes of degradation in the soil physical and chemical properties in North Korea. 75% of the areas converted from forests became croplands, and 69% of the land converted to croplands came from forests. The net forest loss was quite small from the 1990s to the 2000s. However, deforestation in areas with a slightly lower elevation and gentler slope between 1997 and 2014 led to severe soil erosion resulting in a drastic change in the physical and chemical properties of the soil which influenced cropland stability and productivity. Therefore, the drastic changes in land cover as well as in the physical and chemical properties of the soil caused by various geographical features have seriously influenced the productivity of crops in North Korea.

Solid Dispersion of an HIV Protease Inhibitor

  • Park, Jae-Hyeon;Lee, Sung-Hack;Lee, Yong-Hee;Kim, Ae-Ri
    • Journal of Pharmaceutical Investigation
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    • v.41 no.2
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    • pp.75-82
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    • 2011
  • LB71350 is an HIV protease inhibitor with poor aqueous solubility and extensive first pass effect. The purpose of the present study was to test the feasibility of solid dosage form of LB71350 with improved bioavailability utilizing solid dispersion. Three different compositions with varying ratio of (LB71350: Gelucire 44/14: Tween 20) were studied. Capsule filling of these solid dispersion compositions was tested using a semi-automatic capsule filling system. Oral bioavailability in dog was tested. Chemical and physical stability at 4, 25 and $40^{\circ}C$ was monitored by HPLC assay, dissolution test, powder XRD and microscopy. The capsule filling system yielded uniform products of drug loading up to 10%. Oral bioavailability in dog was improved compared to the aqueous suspension of crystalline LB71350. Capsules were chemically stable for up to 6 months at $40^{\circ}C$. However, there were temperature and composition dependent physical changes. Decrease in dissolution rates after storage at $40^{\circ}C$ was due to the polymorphic change. In conclusion, manufacturing process, bioavailability, and physico-chemical stability have been considered to propose a solid dispersion capsule formulation for the HIV protease inhibitor with poor physico-chemical properties. A new less soluble crystalline form identified during the physical stability test warrants further study.

Effect of Cross-Linking Characteristic on the Physical Properties and Storage Stability of Acrylic Rubber

  • Seong-Guk Bae;Min-Jun Gim;Woong Kim;Min-Keun Oh;Ju-Ho Yun;Jung-Soo Kim
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.136-141
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    • 2023
  • Polyacrylic rubber (ACM) is well known for its excellent heat resistance and chemical stability. Additionally, its performance can be readily manipulated by modifying its functional groups, rendering it highly attractive to various industries. However, extreme climate changes have necessitated an expansion of the operating temperature range and lifespan of ACM products. This requires the optimization of both the compounding process and functional-group design. Hence, we investigated the relationship between the cross-linking system and mechanical properties of an ACM with a carboxylic cure site. The crosslink density is determined by chemical kinetics according to the structure of additives, such as diamine crosslinkers and guanidine accelerators. This interaction enables the manipulation of the scotch time and mechanical properties of the compound. This fundamental study on the correlation analysis between cross-linking systems, physical properties, and storage stability can provide a foundation for material research aimed at satisfying the increasingly demanding service conditions of rubber products.

Changes in the Chemical Structure and the Thermal/Physical Properties of Fluoropolymer Films Induced by Gamma Irradiation under Various Environments (다양한 환경에서 감마선으로 조사된 불소고분자 필름들의 구조 및 열적/물성 변화)

  • Choi, Ji Sun;Sohn, Joon-Yong;Shin, Junhwa
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.457-463
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    • 2014
  • In this study, the changes in the chemical structure and the physical property of fluoropolymer films (PTFE, FEP, PFA, PVDF, and ETFE) induced by $Co^{60}$ gamma ray in air, $N_2$, and vacuum environments were investigated. FTIR spectra of the irradiated fluoropolymers indicate that the oxidation proceeded by the reaction of radicals generated by irradiation with oxygen in air. The changes in the heat of fusion and the degree of crystallinity of the irradiated fluoropolymers were investigated using DSC and the results indicate that the scission and crosslinking reactions of the irradiated fluoropolymers were largely influenced by the chemical structure. It was also found that the mechanical property of the irradiated fluoropolymer films under an air atmosphere was significantly decreased.

The Soil Improvement and Plant Growth on the Newly-Reclaimed Sloped land VI. Relationship between annual change of soil phsico-chemical properties and yield of silage corn (신개간경사지 토양개량과 작물생육에 관한 연구 VI. 토양의 물리화학성 년차간 변화가 옥수수 청예수량에 미치는 영향)

  • 허봉구;김무성
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.1
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    • pp.22-29
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    • 1991
  • This study was experimented to obtain the basic information on the changeable aspect and improvement of soil fertility in newly-reclaimed sloped land. Silage corn was cultivated under the six different treatments for 4 years. The relation between the amount or ratio of annual changes of soil physico-chemical properties and yield of silage corn were analyzed. Soil bulk density was decreased in 3rd year at topsoil, but that decreased in 4th year at subsoil. Soil organic matter also decreased in 2nd year at topsoil, and decreased continuously at subsoil. Bulk density and hardness of soil depths showed significant negative simple correlation with dry matter yield and cation exchange capacity showed positive. Correlation coefficient of chemical properties with dry matter yield were low. The range of annual changes of moisture percent, hardness and organic matter were wider than the other properties. The significantly different of physical properties were higher than the chemical properties, and those of topsoil were higher than subsoil. According to multiple regression between yield and physico-chemical properties of subsoil, bulk density and cation exchange capacity were in the greatest contribution at the variations, but bulk density was greatest at the ratios.

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Development of Soil Organic Carbon Storage Estimation Model Using Soil Characteristics (토양 특성을 이용한 토양유기탄소저장량 산정 모형 개발)

  • Lee, Taehwa;Kim, Sangwoo;Shin, Yongchul;Jung, Younghun;Lim, Kyoung-Jae;Yang, Jae E;Jang, Won Seok
    • Journal of The Korean Society of Agricultural Engineers
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    • v.61 no.6
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    • pp.1-8
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    • 2019
  • Carbon dioxide is one of the major driving forces causing climate changes, and many countries have been trying to reduce carbon dioxide emissions from various sources. Soil stores more carbon dioxide(two to three times) amounts than atmosphere indicating that soil organic carbon emission management are a pivotal issue. In this study, we developed a Soil Organic Carbon(SOC) storage estimation model to predict SOC storage amounts in soils. Also, SOC storage values were assessed based on the carbon emission price provided from Republic Of Korea(ROK). Here, the SOC model calculated the soil hydraulic properties based on the soil physical and chemical information. Base on the calculated the soil hydraulic properties and the soil physical chemical information, SOC storage amounts were estimated. In validation, the estimated SOC storage amounts were 486,696 tons($3.526kg/m^2$) in Jindo-gun and shown similarly compared to the previous literature review. These results supported the robustness of our SOC model in estimating SOC storage amounts. The total SOC storage amount in ROK was 305 Mt, and the SOC amount at Gyeongsangbuk-do were relatively higher than other regions. But the SOC storage amount(per unit) was highest in Jeju island indicating that volcanic ashes might influence on the relatively higher SOC amount. Based on these results, the SOC storage value was shown as 8.4 trillion won in ROK. Even though our SOC model was not fully validated due to lacks of measured SOC data, our approach can be useful for policy-makers in reducing soil organic carbon emission from soils against climate changes.

Changes of Physicochemical Parameters During the Aerobic Composting Process of Swine Manure (돈부의 호기성 퇴비화 단계별 물리.화학적 성상 변화)

  • 김태일;정광화;최기춘;류병희;곽정훈;전병수;박치호;김형호;한정대
    • Journal of Animal Environmental Science
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    • v.3 no.1
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    • pp.13-18
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    • 1997
  • This study was conducted to investigate the physicochemical changes during the aerobic composting of swine manure mixed with bulking agent, sawdust(v/v, 1:1), in a full-scale composting plant using rectangular escalator-aginated bed composting system. Physical and chemical properties were analyzed on the samples which were collected at 5, 15, and 25 day of composting, curing and final step. The results of this study were summarized as follows; 1. Moisture and K2O content, and pH of final step were higher than those of 5th day of composting (p<0.05). 2. Ammonium nitrogen, total organic corbon and organic matter content, and electrical conductivity(EC) were significantly decreased (p<0.05) but nitrate nitrogen, ash and P2O5 content increased(p<0.05) throughout the aerobic composting process. 3. Total organic carbon per total nitrogen(C/N) and total organic matter per total nitrogen(OM/N) ratio were significantly decreased throughout the aerobic composting process(p<0.05). 4. Physical and chemical properties of swine manure were varied by aerobic fermentation using rectangular escalor-aginated bed composting system.

Changes in Physical, Chemical, and Biological Traits During Composting of Spent Coffee Grounds (커피찌꺼기 퇴비화 과정의 물리, 화학 및 생물학적 변화)

  • Shin, Ji-Hwan;Park, Seung-Hye;Kim, A-Leum;Son, Yi-hun;Joo, Se-hwan
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.178-187
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    • 2020
  • BACKGROUND: Spent coffee grounds are the most valuable resource for agriculture and industry. However, it is almost thrown untreated into landfills or incineration. Composting is an efficient process for converting spent coffee to fertilizer. METHODS AND RESULTS: Composting was conducted in the compost pile (40 ㎥) equipped with a forced aeration system. Physical and chemical properties containing temperature, pH, electrical conductivity, and moisture were measured through the composting period. Moreover, biological changes were examined for the composting phase using Illumina Miseq sequencing of the 16S rRNA gene. We found 7-14 phyla comprising 250-716 species from a variety phase of compost. During the composting period, Firmicutes were dominated, followed by Actinobacteria and Proteobacteria. CONCLUSION: The result indicated that the use of spent coffee improved the quality of organic fertilizer and changed the microbial communities, unique to the thermal composting stage, which could enhance the composting process. These findings suggest that spent coffee composted material can provide a significant amount of nutrients, thereby supporting plant growth.

Fire Effects on Soil Physical and Chemical Properties following the Forest Fire in Kosung (산불이 산림토양의 이화학적 성질에 미치는 영향)

  • 이원규;김춘식;차순형;김영걸;변재경;구교상;박재욱
    • The Korean Journal of Ecology
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    • v.20 no.3
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    • pp.157-162
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    • 1997
  • Changes on soil physical and chemical properties following the forest fire in Kosung area in Kangwon province were examined. Twenty seven sampling plots[16 burned (8 low intensity fire, 8 high intensity fire) and 11 unburned plots] from Pinus densiflora community were chosen and soil samples from three depths(0-5, 5-15, 15-25 cm) under the forest floor were collected. Forest fire in the area affected soil chemical properties. Soil pH, available phosphorus, base saturation, K, Ca, and Mg on the surface soil(0-5cm) in the burned areas compared with the unburned areas were increased, while soil properties on the subsurface soil(5-25 cm) were not changed. Organic matter, total nitrogen, available phosphorus, and exchangeable cations following the high in tensity fire on the surface soil were generally lower than those in the low intensity fire areas. This indicates that these nutrients on high intensity fire areas may be volatilized. The results suggest that the fire effects on soil chemical properties were confined mainly to the surface soil and were different between the high and the low intensity fire types.

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Effects of Vessel on the Quality Changes during Fermentation of Kochujang (고추장의 숙성 중 발효 용기가 품질변화에 미치는 영향)

  • Chung Sun-Kyung;Kim Young-Sook;Lee Dong Sun
    • Food Science and Preservation
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    • v.12 no.3
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    • pp.292-298
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    • 2005
  • Kochujang(Korean red pepper paste) of 600 g was fermented in the different types of vessels (glass, polypropylene(PP), polyethylene terephthalate(PET), stainless steel and Korean porcelain called onggi) with 627 mL of volume during 4 months. The quality changes were monitored for physical, chemical and microbiological attributes. Onggi which had high porosity in the micro-structure provided kochujang with higher microbial counts of aerobic bacteria, lactic acid bacteria and yeasts than those of the other containers. Compared to kochujang fermented in the other containers, kochujang in Onggi showed higher protease activity, amino type nitrogen, and free amino acid content. The kochujang in Onggi also attained higher acidity, lower pH and higher reducing sugar concentration than those in the other containers. All changes were completed 2 or 3 months. Onggi showed water loss and salt increase of the kochujang comparable to those in the other vessels, which was from gradual clogging of the micropores during storage. All physical, chemical and microbiological changes made the kochujang in Onggi attain the sensory quality significantly better than those fermented in the other vessels.