• Title/Summary/Keyword: physical & mechanical property

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Properties of Bacterial Cellulose Cultured in Different Carbon Sources (탄소원에 따른 Bacterial Cellulose 의 물성)

  • Park, Sang-Min;Yoon, Sang-Jun;Son, Hong-Joo;Lee, Chung-Yeol;Kim, Hong-Sung
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.522-526
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    • 2010
  • Bacterial cellulose is produced by the bacterium Gluconacetobacter xylinus, which forms a nanofibrous pellicle in its culture medium. We studied properties of the bacterial cellulose such as crystallinity, viscosity, morphology, and mechanical properties according to the carbon source. Static cultures of Gluconacetobacter sp. V6 were performed in three kinds of media: standard Hestrin-Schramm medium, and modified medium with either glycerol or molasses as carbon sources. Cell growth and cellulose yield were increased in the glycerol and molasses media. The culture in the glycerol medium improved the physical properties of cellulose such as crystallinity, intrinsic viscosity, and breaking stress. However, the culture in the molasses medium decreased crystallinity, crystallite size, and intrinsic viscosity of cellulose. In summary, the cellulose yield was remarkably improved in the molasses medium, but with inferior structural properties.

Study on the Physical Properties of Polyurethane Foam Synthesized by Castor Oil Based Polyol (피마자유 기반 폴리올에 따른 폴리우레탄 폼의 물성 변화 연구)

  • Lee, Sunghyun;Kim, Kwangin;Oh, Jeongseok;Yun, Mijung;Kim, Sangbum
    • Journal of the Korean Institute of Gas
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    • v.16 no.5
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    • pp.66-75
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    • 2012
  • Polyurethane foams were synthesized by substituting a portion of petroleum base polyether polyol with castor oil-derived polyol(COP). Contact angle tester and surface tensionmeter were used to examine the compatibility of petroleum base polyether polyol and COP. To investigate the optimum content of COP and surfactant, the content of COP has been changed from 0 wt% to 80 wt%. From the results of polyurethane foams synthesized by surfactant L-580K, DC-5950 and BF-2470, the best mechanical properties was observed when the content of COP was 30wt% and surfactant BF-2470.

A Study on the Formulation and Mechanical Properties of AN-based Composite Solid Propellant for an Application to Gas Generators (기체발생기용 질산암모늄 산화제 기반 복합고체추진제의 조성 및 기계적 물성)

  • Park, Jeong;Kim, Jeong-Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.5
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    • pp.1-6
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    • 2009
  • A development of a composite solid propellant is carried out for an application to gas generators as an energy source of rocket system. With HTPB as a propellant binder which has 80% of particle loading ratio, a favorable rheology, and moderate curing properties at the range of $-50^{\circ}{\sim}70^{\circ}C$, AN is selected as the first kind of oxidizer having the characteristics of a low flame temperature, minimal particle residual as well as nontoxic products. AP is the second oxidant for ballistic property control. A series of experiments for the improvement of physical properties were conducted and resulted in the propellant formulation having 30% of strain rate at 8 bar of max. stress.

Effects of Polyurethane Coatings on 304 Stainless Steel Formed by Thermoset for Safety Management of Industrial Disaster (산업 재해의 안전관리를 위한 열경화에 의한 304 스테인레스 스틸에 대한 폴리우레탄 도료의 영향)

  • Kim, Ki-Jun;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.317-322
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    • 2012
  • The microstructures were examined by SEM, FT-IR spectra, tensible properties mole % of [NCO/OH], and particle size analyzer. Growing concerns in the environment-friendly industries have led to the development of solvent-free formulations that can be cured. We had synthesized the polyurethane resin having the ability to protect stainless steel against corrosion. Compared with general packing materials and coatings, this resin is highly stronger in intensity and longer durability. Polyurethane resins were composed of polyols, IPDI, silicone surfactant, catalyst and crosslink agent. Moreover, thermal fillers such as $Al_2O_3$, fume silica and $ZrO_2$ not only accelerated the curing rate but also improved the physical property as thermal barriers. The rigid segments of polyurethane in mechanical properties were due to crosslink agent and the increase of [NCO/OH]. In conclusion, the polyurethane microstructure with crosslink agent can be good material for themoset coating of metal substrates such as stainless steel.

THREE DIMENSIONAL FINITE ELEMENT ANALYSIS OF MANDIBULAR STRESSES OF COMPLETE DENTURE OCCLUSION (하악 총의치 교합형태에 따른 하부조직에 미치는 교합력 양태의 3차원적 유합요소법 해석)

  • Lee Young-Soo;Yoo Kwang-Hee
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.2
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    • pp.286-318
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    • 1992
  • The objective of preventive dentistry is the maintenance of a healthy dentition for the life of a patient. Unfortunately, if an individual has not received the benefit of a comprehensive program of preventive dentistry and has finally reached the edentulous state, as a consequence, he receives a set of complete denture. Dentures are mechanical devices and subject to the principles of mechanics. In some cases, the general health and nutritional status of the patient are felt to be the causative factors. But, the most important thing in residual ridge resorption is felt to be caused by the unequal distribution of functional forces. This study was to analyze mandibular stresses of complete denture occlusion by three dimensional finite element method. The results were as follows ; 1. As deformation and stress distribution of the complete denture of the mandible were concentrated on the upper lingual side of the mandible, alveolar ridge resorption of the mandible occurred from lingual side to labio-buccal side. 2. Analyzing by three dimensional F. E. M., the mandible is a very effective form for tolerating stress and deformation biomechanically. 3. According to the concentration of stress distibution in the upper buccal side of the lower posteriors, buccal shelf area must be a primary stress bearing area in the lower complete denture. 4. Lower complete denture moved horizontally to the balancing side under lateral occlusal force. 5. Bilateral balanced occlusion should be constructed in the complete denture for denture stability, especially in the protrusive movement. 6. Physical property of the denture base material was as important for stress distribution in the denture base as or even more than that in the mandible. 7. Impression technique is very important because of most of stress was concentrated between them due to close contact of the mandible and the denture base.

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Solid State Cesium Ion Beam Sputter Deposition

  • Baik, Hong-Koo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.5-18
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    • 1996
  • The solid state cesium ion source os alumino-silicate based zeolite which contains cerium. The material is an ionic conductor. Cesiums are stably stored in the material and one can extract the cesiums by applying electric field across the electrolyte. Cesium ion bombardment has the unique property of producing high negative ion yield. This ion source is used as the primary source for the production of a negative ion without any gas discharge or the need for a carrier gas. The deposition of materials as an ionic species in the energy range of 1.0 to 300eV is recently recognized as a very promising new thin film technique. This energetic non-thermal equilibrium deposition process produces films by “Kinetic Bonding / Energetic Condensation" mechansim not governed by the common place thermo-mechanical reaction. Under these highly non-equilibrium conditions meta-stable materials are realized and the negative ion is considered to be an optimum paeticle or tool for the purpose. This process differs fundamentally from the conventional ion beam assisted deposition (IBAD) technique such that the ion beam energy transfer to the deposition process is directly coupled the process. Since cesium ion beam sputter deposition process is forming materials with high kinetic energy of metal ion beams, the process provider following unique advantages:(1) to synthesize non thermal-equilibrium materials, (2) to form materials at lower processing temperature than used for conventional chemical of physical vapor deposition, (3) to deposit very uniform, dense, and good adhesive films (4) to make higher doposition rate, (5) to control the ion flux and ion energy independently. Solid state cesium ion beam sputter deposition system has been developed. This source is capable of producing variety of metal ion beams such as C, Si, W, Ta, Mo, Al, Au, Ag, Cr etc. Using this deposition system, several researches have been performed. (1) To produce superior quality amorphous diamond films (2) to produce carbon nitirde hard coatings(Carbon nitride is a new material whose hardness is comparable to the diamond and also has a very high thermal stability.) (3) to produce cesiated amorphous diamond thin film coated Si surface exhibiting negative electron affinity characteristics. In this presentation, the principles of solid state cesium ion beam sputter deposition and several applications of negative metal ion source will be introduced.

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Effect of AP Particle Size on the Physical Properties of HTPB/AP Propellant (AP 입자가 HTPB/AP 추진제의 물리적 특성에 미치는 효과)

  • Yim, Yoo Jin;Park, Eun Ji;Kwon, Tae Ha;Choi, Seong Han
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.1
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    • pp.14-19
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    • 2016
  • The viscosity and mechanical property of HTPB/AP composite solid propellant are profoundly affected by particle size of AP. In HTPB/AP propellant formulated by two mode of AP size such as $190{\mu}m$ and $7{\mu}m$, the propellant was found to be much less viscose at end of mix when coarse/fine AP ratio is ranged from 70/30 to 60/40 due to high solid packing fraction. It was shown that the toughness of tensile strength test for HTPB/AP propellant increased with the increase in coarse AP. Considering both lower viscosity and better tensile strength, the optimum ratio of AP coarse/fine was estimated to be 70/30.

A Study of Property F.R.P Structure Strength According to the Direction of Lay-up in the Small Ship (적층 방향에 따른 F.R.P 구조강도특성에 관한 연구)

  • 고재용;배동균;윤순동
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2002.11a
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    • pp.101-105
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    • 2002
  • FRP(Fiber glass reinforced plastics) is compound with materials, which are created to combine each other materials, of which nature of mechanical and chemical are different. Even though the weight and the thickness are identic, its physical figure of characteristic changes with consisting of lay-up and work situation. It is also a method of creating after manufacturing of mould. It has feature that manufacturing of FRP runs parallel design of material with design of structure simultaneously. The rule of FRP structure is distinguished from the length of a ship and it is hard to catch the feature of structure mechanics due to identical formula and figure used for it regardless of the shape of a ship or the speed. This studying, basing on a small FRP ship, will show te fundamental data needed to design of structure analysing the feature of intensity with direction, the method of Lay-up, and the characteristic of materials of FRP.

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Characteristics of Molecular Band Energy Structure of Lipid Oxidized Mammalian Red Blood Cell Membrane by Air-based Atmospheric Pressure Dielectric Barrier Discharge Plasma Treatment

  • Lee, Jin Young;Baik, Ku Youn;Kim, Tae Soo;Jin, Gi-Hyeon;Kim, Hyeong Sun;Bae, Jae Hyeok;Lee, Jin Won;Hwang, Seung Hyun;Uhm, Han Sup;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.262.1-262.1
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    • 2014
  • Lipid peroxidation induces functional deterioration of cell membrane and induces cell death in extreme cases. These phenomena are known to be related generally to the change of physical properties of lipid membrane such as decreased lipid order or increased water penetration. Even though the electric property of lipid membrane is important, there has been no report about the change of electric properties after lipid peroxidation. Herein, we demonstrate the molecular energy band change in red blood cell membrane through peroxidation by air-based atmospheric pressure DBD plasma treatment. Ion-induced secondary electron emission coefficient (${\gamma}$ value) was measured by using home-made gamma-focused ion beam (${\gamma}$-FIB) system and electron energy band was calculated based on the quantum mechanical Auger neutralization theory. The oxidized lipids showed higher gamma values and lower electron work functions, which implies the change of surface charging or electrical conductance. This result suggests that modified electrical properties should play a role in cell signaling under oxidative stress.

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Preparation of EMI Shielding Sheet by PVD Method and Its Characteristic of EMI Shielding Efficiency (PVD법을 이용한 전자파 차폐용 시트 제조 및 차폐효율 특성)

  • Chae, Seong-Jeong;Hong, Byung-Pyo;Lee, Byoung-Soo;Byun, Hong-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.527-531
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    • 2010
  • The optimized sheet for EMI shielding was prepared by metal power with Fe series. Then various metal powders were deposited on the sheet by PVD method. Moreover, the PVdF nanofiber membrane was used to compare the characteristic of EMI shielding efficiency of various metal powders. The electrical property was measured by the 4-point probe method. The result from EDS confirmed that the metal powder existed on the sheet. EMI shielding efficiency was analysed by EMI shielding measurement apparatus. The lowest electrical resistance, $641.95{\Omega}{wcdot}cm$, was obtained with $1000\;{\AA}$ deposition of Cu on the sheet. It was revealed that the EMI shielding efficiency increased with increase of the metal deposition thickness. The sheet deposited by Cu with $1000\;{\AA}$ showed the highest EMI shielding efficiency, 32.5 dB.