• Title/Summary/Keyword: photopotential

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Corrosion Protection of STS304 Steel with Photo-Functional Material $TiO_2$ Coating (광기능성 재료 $TiO_2$ 피막에 의한 STS304강의 방식)

  • NAM KI-WOO;LEE SUNG-YEON;AHN SEOK-HWAN;KIM JONG-SOON
    • Journal of Ocean Engineering and Technology
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    • v.17 no.3 s.52
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    • pp.52-56
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    • 2003
  • This study investigates the photoelectrochemical behavior of STS304 steel with TiO2 thin films coating, applied by sol-gel mehod, for the purpose of cathodic photoprotection of the steel corrosion. One time TiO2-coated STS304 steel, adapted with two kinds of TiO2 sol solution, has the most dominant photopotential abilities, which was -200mV vs. SCE and -500mV vs. SCE under illumination with 40 W fluorescent lamp, respectively. That had yielded more negative values than the corrosion potential of the bare metal(-130mv vs.SCE). The bleaching of TCE was confirmed on TiO2-coated STS304 steel under UV-illumination with 20W Black-light. This Study concluded that Ti02-coated STS304 exhibited both a cathodic photoprotection effect against corrosion and a photocatalytic self-cleaning effect.

Protection of STS304 Steel with Photo-Functional Material $TiO_2$ Coating (광기능성 재료 $TiO_2$ 피막에 의한 STS304강의 방식)

  • Nam, Ki-Woo;Lee, Sung-Yeon;Ahn, Seok-Hwan;Kim, Jong-Soon;Park, In-Duck
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.10a
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    • pp.307-311
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    • 2002
  • This study was investigated the photoelectrochemical behavior of STS304 steel with $TiO_2$ thin films coating, applied by sol-gel method, for the purpose of cathodic photoprotection of the steel corrosion. One time $TiO_2$-coated STS304 steel adopted two kinds of $TiO_2$ sol solution has the most dominant photopotential abilities, which was -200mV vs. SCE and -500mV vs. SCE under illumination with 40W fluorescent lamp, respectively. That was more negative than the corrosion potential of the bare metal(-150 mV). The bleaching of TCE was confirmed on $TiO_2$-coated STS304 under UV-illumination with 20 W Black-light. This Study was concluded that $TiO_2$-coated STS304 exhibited both a cathodic photoprotection effect against corrosion and photocatalytic self-cleaning effect.

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The optimum conversion efficiency in nile blue arabinose system by photogalvanic cell

  • Lal, Mohan;Gangotri, K.M.
    • Advances in Energy Research
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    • v.3 no.3
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    • pp.143-155
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    • 2015
  • The Nile blue has been used as a photosensitizer with Arabinose as a reductant in photogalvanic cell for optimum conversion efficiency and storage capacity. Reduction cost of the photogalvanic cell for commercial utility. The generated photopotential and photocurrent are 816.0 mV and $330.0{\mu}A$ respectively. The maximum power of the cell is $269.30{\mu}W$ where as the observed power at power point is $91.28{\mu}W$. The observed conversion efficiency is 0.6095% and the fill factor 0.2566 has been experimentally found out at the power point of the photogalvanic cell, whereas the absolute value is 1.00. The photogalvanic cell so developed can work for 120.0 minutes in dark if it is irradiated for 200.0 minutes that is the storage capacity of photogalvanic cell is 60.00%. The effects of different parameters on the electrical output of the photogalvanic cell have been observed. A mechanism has also been proposed for the photogeneration of electrical energy.