• 제목/요약/키워드: photo-journal

검색결과 3,008건 처리시간 0.026초

Fluorescent Probes for Analysis and Imaging of Monoamine Oxidase Activity

  • Kim, Dokyoung;Jun, Yong Woong;Ahn, Kyo Han
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1269-1274
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    • 2014
  • Monoamine oxidases catalyze the oxidative deamination of dietary amines and amine neurotransmitters, and assist in maintaining the homeostasis of the amine neurotransmitters in the brain. Dysfunctions of these enzymes can cause neurological and behavioral disorders including Parkinson's and Alzheimer's diseases. To understand their physiological roles, efficient assay methods for monoamine oxidases are essential. Reviewed in this Perspective are the recent progress in the development of fluorescent probes for monoamine oxidases and their applications to enzyme assays in cells and tissues. It is evident that still there is strong need for a fluorescent probe with desirable substrate selectivity and photophysical properties to challenge the much unsolved issues associated with the enzymes and the diseases.

엘리베이터 회생전력을 이용한 하이브리드 태양광 연계형 인버터에 관한 연구 (A Study on Hybrid type Grid-Connected PV Inverter using Elevator Regeneration Power)

  • 조수억
    • 전기학회논문지
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    • 제65권10호
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    • pp.1682-1687
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    • 2016
  • Approximately 520thousand elevators are operating now in Korea, about 40% ~ 60% of the elevator power is generated. In this paper, by using the method of adding regeneration power of the elevator to the grid-tied photo voltaic inverter, PV generation that was dependant on the solar radiation was significantly improved. In order to confirm this, the regeneration power of the elevator has been simulated in 12% of the rating load, and measured the regeneration power of the elevator in the actual condition to assess the differences of it. The 5[kW] hybrid grid-tied photo voltaic invertor has been fabricated to conduct an experiment for the confirmation of the proposing method. The effectiveness of the proposing method has been reassured with the result of experiment that include the transfer interface part of the regeneration power of the elevator.

Deuterium-labeling Toward Robust Function of Organic Molecules: Enhanced Photo-stability of Partially Deuterated 1', 3', 3'-Trimethyl-6-nitrospiro[2H-1- benzopyran-2, 2'-indoline]

  • Kawanishi, Yuji;Inoue, Kyoko;Ohta, Shin-Ichi;Miyazawa, Akira
    • Rapid Communication in Photoscience
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    • 제3권4호
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    • pp.64-66
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    • 2014
  • Synthesis of a deuterium-labeled derivative of nitrospirobenzopyran (NSP), one of representative photochromic compounds, has been described. Four deuteriums were successfully introduced on 1-methyl and ${\alpha}$-methyne relative to spiro-carbon in the title compound with more than 95atom%D purity. Main photodegraded products of NSP were two oxindoles in acetonitrile, and additional products were formed in poly(isobutyl-methacrylate) films possibly due to restricted molecular motion in polymer matrix. Quantitative HPLC analysis revealed that partial introduction of deuterium to NSP brought a noticeable isotope effect, recognizable enhancement in photo-resistivity of NSP, i.e.,8.3% in solutions and 29% in polymeric films.

Hydrophilic Modification of Poly(ethylene oxide) by UV Irradiation

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • 한국염색가공학회지
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    • 제21권5호
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    • pp.16-20
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    • 2009
  • Films of Poly(ethylene oxide), PEO, were modified to impart hydrophilicity via UV irradiation. The UV irradiation treatment produced new photo-oxidized groups of carbonyl and ether groups as indicated in ATR and ESCA analysis. It was found that water contact angle decreased from $15^{\circ}C$ to $10^{\circ}C$ and total surface energy of PEO increased from 54.2 mN/m to 76.6 mN/m with increasing UV energy, which was attributed to significant contribution of acid base interaction of the photo-oxidized PEO rather than nonpolar interaction originating from the dominant increase in Lewis acid parameter. The increased hydrophilicity and surface energy were also proved by the decreased water wetting time.

Nano-Optical Investigation of Enhanced Field at Gold Nanosphere-Gold Plane Junctions

  • Ahn, Sung-Hyun;Park, Won-Hwa;Kim, Zee-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2200-2202
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    • 2007
  • The local field distribution around gold nanosphere-gold plane junction has been studied using the finitedifference time-domain (FDTD) electrodynamics calculation procedure. We find that both the in-plane and out-of-plane polarized excitation produce enhanced field strong enough to explain the observed SERS activities of the junctions. Comparison with a simple dipole-image dipole model shows that the enhanced field primarily originates from the multipole-image multipole interaction, which indicates that the detailed fine-structures of the nanoparticles also play a significant role in the SERS activities as well.

Photoisomerization and Photo-induced Optical Anisotropy of Polymethacrylate Containing Aminonitroazobenzene

  • Park, Dong-Hoon;Cho, Kang-Jin
    • Fibers and Polymers
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    • 제2권1호
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    • pp.123-130
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    • 2001
  • Photoresponsive side chain copolymer and homopolymer containing an aminonitroazobenzene were synthesized for studying photoisomerization behavior and photo-induced anisotropy. Trans-to-cis photoisomerization was observed under the exposure of a circularly polarized visible light with UV-Vis absorption spectroscopy. Reorientation of polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532nm. Polarized absorption spectroscopy was employed to investigate the anisotropy of the polymer film during irradiationg of the excitation light. Layers of two photosensitive polymers were used for aligning liquid crystal(LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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포토레지스트 공급용 미소유량계 개발 (Development of Micro-flowmeter for Supplying Photo-resist)

  • 김신호;정선환;최성대
    • 한국공작기계학회논문집
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    • 제16권5호
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    • pp.198-204
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    • 2007
  • This study was carried out to develope a flow control system using to supply PR(photo-resist) in the semi-conductor manufacturing process. The features of this system are to be able to measure the high viscosity and micro-flow. To meet above study object some ideas was induced to design a new concept valve with new material, multi-cross wheel, and new sealing method etc.. As the evaluations on the developed micro-flowmeter it was enough satisfied to use at the IT industries such as photo-resist process.

다중 Gate 및 Channel 구조를 갖는 CMOS 영상 센서용 Floating-Gate MOSFET 소자의 제작 및 특성 평가 (Fabrication and Characterization of Floating-Gate MOSFET with Multi-Gate and Channel Structures for CMOS Image Sensor Applications)

  • 주병권;신경식;이영석;백경갑;이윤희;박정호
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제50권1호
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    • pp.17-22
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    • 2001
  • The floating-gate MOSFETs were fabricated by employing 1.5 m n-well CMOS process and their optical-electrical properties were characterized for the application to CMOS image sensor system. Based on the simulation of energy band diagram and operating mechanism of parasitic BJT were proposed as solutions for the increase of photo-current value. In order to realize them, MOSFETs having multi-gate and channel structures were fabricated and 60% increase in photo-current was achieved through enlargement of depletion layer and parallel connection of parasitic BJTs by channel division.

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A New Diarylethene with Donor-acceptor Group for Reversible Photo-induced Electrochemical Switching

  • Kim, Eun-Kyoung;Kim, Mi-Young;Kim, Kyong-Tae
    • Bulletin of the Korean Chemical Society
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    • 제29권4호
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    • pp.827-832
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    • 2008
  • A new diarylethene compound with donor and acceptor substituent was synthesized from 2,3-bis(2-methylbenzo[b]thiophene-3-yl)hexafluorocyclopentene (BTF) over 5 steps. The donor-acceptor structured BTF compound (TBTFE) showed spectral change to a longer wavelength through photochromism with a high cyclization quantum yield (0.56). The 3,4-ethylenedioxythiophene (T) and carboethoxy (E) groups directly connected to BTF unit promoted electrical change accompanied with the photoisomerization of the BTF unit. Photo-induced electrical switching was achieved from a photocell containing TBTFE doped polymer film, which showed reversible and stable current change over repeated cycles by the alternative UV/Vis irradiation, as estimated by the I-V plot.

Poly(vinyl)cinnamate막을 이용한 A-TN-LCD의 전기광학 특성 (Investigation of Electro-optical Characteristics in A-TN-LCD on Poly(vinyl)cinnamate Surfaces)

  • 서대식;박지호;이보호
    • E2M - 전기 전자와 첨단 소재
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    • 제10권6호
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    • pp.576-580
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    • 1997
  • In this paper, the viewing angle characteristics of amorphous (a) - twisted nematic (TN)-liquid crystal display (LCD) on poly(vinyl)cinnamate (PVC) surface with UV (ultraviolet) light irradiation were investigated. It was found that the threshold voltage increases with increasing the polymerization of PVC surfaces. We observed that the domain size of a-TN-LCD decreases with increasing the photo polymerization by increasing UV light irradiation time on PVC films. Also, we observed that the viewing angle of a-TN-LCD increased with increasing the photo polymerization on PVC surfaces. Finally, we consider that the viewing angle of a-TN-LCD on PVC surfaces is large compared to a-TN-LCD on polyimide (PI) surface.

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