• Title/Summary/Keyword: photo-journal

Search Result 3,008, Processing Time 0.031 seconds

Photopatternability of Poly(vinylcarbazole) Bearing Cinnamate Pendants and Its Blends with a Soluble Poly(p-phenylene vinylene) Derivative

  • Yu, Young-Jun;Lee, Seung-Hun;Choi, Dong-Hoon;Jin, Jung-Il;Tessler, Nir
    • Macromolecular Research
    • /
    • v.15 no.2
    • /
    • pp.142-146
    • /
    • 2007
  • Poly[(1-(9-carbazoly1)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination $(\lambda=254nm)$. Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.

Hydrogen-Dependent Catalytic Growth of Amorphous-Phase Silicon Thin-Films by Hot-Wire Chemical Vapor Deposition (HWCVD를 이용한 Amorphous Si 박막 증착공정에서 수소량에 따른 박막성장 특성)

  • Park, Seungil;Ji, Hyung Yong;Kim, MyeongJun;Kim, Keunjoo
    • Current Photovoltaic Research
    • /
    • v.1 no.1
    • /
    • pp.27-32
    • /
    • 2013
  • We investigated the growth mechanism of amorphous-phase Si thin films in order to improve the film characteristics and circumvent photo-degradation effects by implementation of hot-wire chemical vapor deposition. Amorphous silicon thin films grown in a silane/hydrogen mixture can be decomposed by a resistive heat filament. The structural properties were observed by Raman spectroscopy, FTIR, SEM, and TEM. The electrical properties of the films were measured by photo-conductivity, dark-conductivity, and photo-sensitivity. The contents of Si-H and $Si-H_n$ bonds were measured to be 19.79 and 9.96% respectively, at a hydrogen flow rate of 5.5 sccm, respectively. The thin film has photo-sensitivity of $2.2{\times}10^5$ without a crystalline volume fraction. The catalyst behavior of the hot-wire to decompose the chemical precursors by an electron tunneling effect depends strongly on the hydrogen mixture rate and an amorphous Si thin film is formed from atomic relaxation.

1,8-Naphthyridine Modified Naphthalimide Derivative: Ratiometric and Selective Sensor for Hg2+ in Organic Aqueous Solution

  • Shi, Yong Gang;Duan, Yu Lian;Chen, Jian Hua;Wu, Xiang Hua;Zhou, Ying;Zhang, Jun Feng
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.1
    • /
    • pp.63-67
    • /
    • 2013
  • A bottom-modified (4-position) naphthalimide derivative 1 with 1,8-naphthyridine as binding site has been designed and synthesized. Compound 1 is the first 1,8-naphthyridine-modified naphthalimide-based sensor that can detect $Hg^{2+}$ selectively with respect to ratiometric fluorescent change and blue shift in organic aqueous solution. The Job's plot and FAB mass indicate that 1 formed a 1:1 complex with $Hg^{2+}$. A top-modified naphthalimide derivative 2 with 1,8-naphthyridin as binding site has also been synthesized for comparison.

Improved Photo Degradation of Rhodamine B Dye using Iron Oxide/Carbon Nanocomposite by Photo-Fenton Reaction

  • Kim, Min-Il;Im, Ji-Sun;In, Se-Jin;Kim, Hyuk;Kim, Jong-Gyu;Lee, Young-Seak
    • Carbon letters
    • /
    • v.9 no.3
    • /
    • pp.195-199
    • /
    • 2008
  • A nanocomposite consisting of $Fe_3O_4$ and MWCNT was produced via sol-gel technique using $FeCl_3$ along with MWCNT by calcination at $300^{\circ}C$. The degradation effect of rhodamine B dye has been investigated under UV illumination in a darkroom. The degradation reaction was studied by monitoring the discoloration of dye as a function of irradiation time using UV-visible spectrophotometeric technique. The $Fe_3O_4$-MWCNT samples have continuous degradation ability under the UV illumination with the first order kinetics and the dye removal was better than in the pristine $Fe_3O_4$. The resultant composite catalyst was found to be efficient for the photo-Fenton reaction of the dye.

Fabrication, Optoelectronic and Photocatalytic Properties of Some Composite Oxide Nanostructures

  • Zou, C.W.;Gao, W.
    • Transactions on Electrical and Electronic Materials
    • /
    • v.11 no.1
    • /
    • pp.1-10
    • /
    • 2010
  • This is an overview paper reporting our most recent work on processing and microstructure of nano-structured oxides and their photoluminescence and photo-catalysis properties. Zinc oxide and related transition metal oxides such as vanadium pentoxide and titanium dioxide were produced by a combination of magnetron sputtering, hydrothermal growth and atmosphere controlled heat treatment. Special morphology and microstructure were created including nanorods arrays, core-brushes, nano-lollipops and multilayers with very large surface area. These structures showed special properties such as much enhanced photoluminescence and chemical reactivity. The photo-catalytic properties have also been promoted significantly. It is believed that two factors contributed to the high reactivity: the large surface area and the interaction between different oxides. The transition metal oxides with different band gaps have much enhanced photoluminescence under laser stimulation. Use of these complex oxide structures as electrodes can also improve the energy conversion efficiency of solar cells. The mixed oxide complex may provide a promising way to high-efficiency photo emitting materials and photo-catalysts.

a-Si:H Image Sensor for PC Scanner

  • Hur, Chang-Wu
    • Journal of information and communication convergence engineering
    • /
    • v.5 no.2
    • /
    • pp.116-120
    • /
    • 2007
  • In this paper, the image sensor using the a-Si:H TFT is proposed. The optimum amorphous silicon thin film is deposited using plasma enhanced chemical vapor deposition (PECVD). TFT and photodiode both with the thin film are fabricated and form image sensor. The photodiode shows that $I_{dark}\;is\;{\sim}10^{-13}\;A,\;I_{photo}\;is\;{\sim}10^{-9}\;A\;and\;I_{photo}/I_{dark}\;is\;{\sim}10^4$, respectively. In the case of a-Si:H TFT, it indicates that $I_{on}/I_{off}\;is\;10^6$, the drain current is a few ${\mu}A\;and\;V_{th}\;is\;2{\sim}4$ volts. For the analysis on the fabricated image sensor, the reverse bias of -5 volts in ITO of photodiode and $70 {\mu}sec$ pulse in the gate of TFT are applied. The image sensor with good property was conformed through the measured photo/dark current.

A Study for Degradation Mechanism of Plastic Materials (플라스틱 소재의 탈변색 열화 메커니즘 분석)

  • Youn, Hyung-Joon;Jung, Won-Wook;Byun, Doo-Jin;Choi, Gi-Dae
    • Journal of Applied Reliability
    • /
    • v.7 no.4
    • /
    • pp.173-181
    • /
    • 2007
  • Out door exposure to daylight and weather climate conditions can cause adverse effect on the properties of automotive plastic materials. The effects of sunlight exposure, especially ultra violet (UV) radiation, can break down the chemical bonds in a polymeric material. This degradation process is called photo-degradation and ultimately leads to color changes, cracking, chalking, the loss of physical properties and deterioration of other properties. To explore the effect of sunlight exposure on the automotive materials, this study investigated photo-oxidation degree and surface property change of molding parts by analytical methods. For the further study, accelerated weathering test methods are proposed, which can correlate with out door weathering, to predict long term performance of automotive plastic materials.

  • PDF

The Position Decision Comparison Experiment of Hall and Photo Sensors in the Linear Stage (홀 센서와 포토 센서를 이용하는 선형 스테이지에서 위치결정 비교 실험)

  • Cha, Young-Youp
    • Journal of Institute of Control, Robotics and Systems
    • /
    • v.21 no.2
    • /
    • pp.157-161
    • /
    • 2015
  • For machining systems having a high precision positioning with a long stroke, it is necessary to examine the repeatability of reference position decisions. Though ball-screw driven linear stages equipped with encoders have high precision feed drivers and a long stroke, they have some limitations for reference position decisions if they have not been equipped accurate home sensors. High precision machining technology has become one of the most important aspects of the development of a precision machine. Such a machine requires high precision positioning as well as high speed on a large workspace. This study is performed to experimentally compare the repeatability for home position decisions in the case of photo sensors and hall sensors as a home switch of the ball-screw driven linear stage.

What You Hear is What You See\ulcorner

  • Moon, Seung-Jae
    • The Journal of the Acoustical Society of Korea
    • /
    • v.21 no.1E
    • /
    • pp.31-41
    • /
    • 2002
  • This study aims at investigating the relationship between voice and the image information carried within the voice. Whenever we hear somebody talking, we form a mental image of the speaker. Is it accurate? Is there a relationship between the voice and the image triggered by the voice? To answer these questions, speech samples form 8 males and 8 females were recorded. Two photos were taken for each speaker: the whole body photo (W) with physical characteristics present, and the face close-ups (F) without much physical details revealed. 361 subjects were asked to match the voices with the corresponding photos. The results showed that 5 males and 5 f3males (with W) and 2 males and 4 females (with F) were correctly identified. More interestingly, however, even in the mismatches, there was a strong tendency for participants to agree on which voice should correspond to which photo. The participants also agreed much more readily on their favorite voice than on their favorite photo. It seems voice does carry certain information about the physical characteristics of the speaker in a consistent manner. These findings have some bearings on understanding the mechanism of speech production and perception as well as on improving speech technology.

Development of Build-up Printed Circuit Board Manufacturing Process Using Rapid Prototyping Technology and Screen Printing Technology (쾌속조형과 스크린 인쇄기술을 이용한 빌드업인쇄회로기판의 제조공정기술개발)

  • 조병희;정해도;정해원
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.17 no.2
    • /
    • pp.130-136
    • /
    • 2000
  • Generally, the build-up printed circuit board manufactured by the sequential process with etching, plating, drilling etc. requires many types of equipments and lead time. Etching process is suitable for mass production, however, it is not adequate for manufacturing prototype in the developing stage. In this study, we introduce a screen printing technology to prototyping a build-up printed circuit board. As for the material, photo/thermal curable resin and conductive paste are used for the formation of dielectric and conductor. The build-up structure is made by subsequent processes such as the formation of liquid resin thin layer, the solidification by UV/IR light, and via filling with conductive paste. By use of photo curable resin, productivity is greatly enhanced compared with thermal curable resin. Finally, the basic concept and the possibility of build-up printed circuit board prototyping are proposed in comparison with to the conventional process.

  • PDF