• Title/Summary/Keyword: photo-journal

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Photoinitiator-free Photo-reactive Coloration of Wool Fabrics Using C.I. Reactive Black 5

  • Dong, Yuanyuan;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.24 no.2
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    • pp.97-105
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    • 2012
  • Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/$cm^2$. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.

The High Efficiency of Amorphous-Si Solar Cells Prepared by Photo-CVD System (광(光) CVD 법(法)에 의한 a-Si 태양전지(太陽電池)의 고효율화에 관한 연구(硏究))

  • Kim, Tae-Seoung
    • Solar Energy
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    • v.5 no.2
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    • pp.46-53
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    • 1985
  • Hydrogenated amorphous silicon solar cells which are fabricated by photo-chemical vapor deposition (photo-CVD) system has been investigated. In the photo-CVD system which consists of three separate reaction chambers, low-pressure mercury lamp has been used as a light source. The main reactant ($Si_2H_6/He$) gases which are premixed with a small amount of mercury vapor in a mercury-vaporizer kept at $50^{\circ}C$ have been used. Using $C_2H_2$ and $SiH_2(CH_3)_2$ as the carbon source, p-type wide band gap a-SiC:H films have been obtained. The result has been found that the undoped layers of the pin/substrate solar cells are influenced by the residual impurities, such as phosphorus and boron during the deposition process. By minimizing the effect of the impurities in the i-layer and optimizing conditions at the p-layer and p/i interface, the energy conversion efficiency of 9.61 % under AM-1 ($100mW/Cm^2$) has been achieved for pin/substrate solar cells illuminated through their p-layers, using the three separate reaction chamber apparatus. It is expected that a-SiC:H solar cells with the energy conversion efficiency over 10% have been fabricated by Photo-CVD method.

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Accuracy Assessment Geoposition of Airborne Line-Scanner Image (라인방식 디지털 항공 카메라영상의 위치 정확도 평가)

  • Cho, Han-Kun;Wie, Gwang-Jae;Choi, Yun-Soo;Lee, Sang-Jin
    • Spatial Information Research
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    • v.19 no.1
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    • pp.51-59
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    • 2011
  • We produced true ortho images after interpolating occlusion areas and relief displacement of building as well as producing ortho-images to use backward image of ADS which is a aerial digital camera of line type. Also, I was able to produce high quality ortho-images using a small mount of Ground Control Points(GCP) relatively to compare to frame type camera from the evaluation of horizontal position accuracy using ground check points, photo control points for the verification of ortho-images and true-ortho images. Also, I was able to verify the effectiveness in interpolating occlusion areas cause the length overlap was 100% when producing true-ortho images of line type camera.

A Study on the design of Database for photograph of Road Facilities (도로시설물 관리를 위한 Photo Database 설계에 관한 연구)

  • 엄우학;정동훈;김정현;김병국
    • Spatial Information Research
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    • v.11 no.1
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    • pp.33-40
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    • 2003
  • For effective management of information about establishment and repair of road and road facilities, we built GPS-Van mapping system that CCD Cameras, GPS receivers and INS are integrated and using it surveyed test area. Suggested a scheme that possible put acquired data into photo database systematically. Prototype of road facilities management system using the database shows us that extraction of qualitative information and management are possible through relation attribute information. And it raise cognitive faculty of user about objects using field photographs.

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A Study of Fabrication Techniques of Thin film Photo-Electric Energy Conversion Elements (박막 광전에너지 변환소자의 개발에 관한 연구)

  • 성영권;민남기;성만영;김승배
    • 전기의세계
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    • v.25 no.5
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    • pp.63-69
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    • 1976
  • Among various types of photo-electric energy conversion element which can transfer solar energy into electric energy through the photo voltaic effect, Si solar cells were investigated on photoelectric characteristics, improvements of its efficiency and economical evaluation for its production cost. To study the above subjects, we decided best conditions on fabricating of thin film Si solar cell by epitaxial growth and knew that the thin solar cell by epitaxial growth was more efficient than that by diffusion process. And also higher photo voltaic output was obtained as a effect of SiO as antireflection coating by several methods, i.e. vacuum evaporating techniques of electrode to decrease the contact resistance and to form best ohmic contact, and concentration techniques of sun's ray by lenz or both-sided illumination through special structure for reflection using mirrors.

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Macroscopic Nonlinear Optical Properties of Tricyanopyrrolidene Chromophore Containing Amorphous Polycarbonate: Effect of Molecular Lateral Moiety in the Conjugative Structure

  • Cho, Min-Ju;Lee, Sang-Kyu;Jin, Jung-Il;Choi, Dong-Hoon
    • Macromolecular Research
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    • v.14 no.6
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    • pp.603-609
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    • 2006
  • Tricyanopyrrolidene chromophores were prepared in order to compare their macroscopic nonlinear optical (NLO) properties with a conjugated structure through the long molecular axis. A thiophene or phenyl ring was tethered to an ethylenic bond; it may act as a lateral moiety to disrupt the planarity of a chromophore and lessen the electrostatic interaction. Thin film composites of these chromophores dissolved in amorphous polycarbonate (APC) were fabricated. Real time pole and probe method was employed to investigate the change of electro-optic (EO) signal during poling. The EO properties and their relaxation behaviors of the guest-host systems containing newly synthesized chromophores were investigated in detail.

Synthesis and Characterizations of Bis-Spiropyran Derivatives

  • Lee, Sungmin;Ji, Seungwook;Kang, Youngjong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3740-3744
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    • 2012
  • We synthesized three different derivatives of bis-spiropyran using simple organic reactions with high yields. BSP1, a derivative of bis-spiropyran having a connection at the position 6' and BSP2, a derivative of bis-spiropyran having a connection at the position 5 and BSP3, a derivative of bis-spiropyran containing a dithienylethene group between two spiropyran moieties were synthesized. The optical properties of BSPs were characterized. UV-Vis spectra showed that BSPs exhibit reversible photo-isomerization and the efficiency of photo-isomerization is highly dependent on the position of nitro group. BSPs having nitro group at para position of hydroxy group showed the higher efficiency of photo-isomerization that the one having nitro group at ortho position. The optical microscope images obtained under ultraviolet or visible light exposure demonstrated that the formation of nanorods can be reversibly controlled by optical signal.

Preparation of Colour Filter Photo Resists for Improving Colour Purity in Liquid Crystal Displays by Synthesis of Polymeric Binder and Treatment of Pigments

  • Yoon, Chun;Choi, Jae-Hong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1821-1826
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    • 2009
  • Liquid crystal display (LCD) devices contain a colour filter which can visualise colour images by transmitting or absorbing light. Colour properties of LCD mainly depend on colour materials such as pigments and polymeric binders. In this paper, colour properties were studied to improve colour quality of LCD. Generally, the colour properties can be classified into three categories which are colour purity, brightness and contrast ratio. For this study, photo resists were prepared by treatment of pigments and synthesis of polymeric binder. The treated pigments were dispersed and formulated with additives for preparing a photo resist that could be used for manufacturing colour filters. As a result of what we studied, type, mixture ratio and concentration of pigments were very important to improve colour purity of LCD device.

Ellipso-Microscopic Observation of Titanium Surface under UV-Light Irradiation

  • Fushimi, K.;Kurauchi, K.;Nakanishi, T.;Hasegawa, Y.;Ueda, M.;Ohtsuka, T.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.265-270
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    • 2016
  • The ellipso-microscopic observation of a titanium surface undergoing anodization in $0.05mol\;dm^{-3}$ of $H_2SO_4$ was conducted. During irradiation by ultra-violet (UV) light with a wavelength of 325 nm, the titanium surface allowed for the flow of a photo-induced current and showed up as a bright, patch-like image on an ellipso-microscopic view. The brightness and patch-pattern in the image changed with flowing photo-induced current. The changes in the brightness and the image corresponded to the formation and/or degradation of titanium oxide due to the photo-electrochemical reaction of the oxide. An in situ monitoring using the ellipso-microscope revealed that the film change was dependent on the irradiation light power, by UV-light increases the anodic current and results in the initiation of pitting at lower potentials as compared with the non-irradiated condition.

Photo-triggered Theranostic Nanoparticles in Cancer Therapy

  • Abueva, Celine DG.
    • Medical Lasers
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    • v.10 no.1
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    • pp.7-14
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    • 2021
  • In cancer therapy, it is often desirable to use precision medicine that involves treatments of high specificity. One such treatment is the use of photo-triggered theranostic nanoparticles. These nanoparticles make it possible to visualize and treat tumors specifically in a controlled manner with a single injection. Several novel and powerful photo-triggered theranostic nanoparticles have been developed. These range from small organic dyes, semiconducting and biopolymers, to inorganic nanomaterials such as iron-oxide or gold nanoparticles, carbon nanotubes, and upconversion nanoparticles. Using photo-triggered theranostic nanoparticles and localized irradiation, complete tumor ablation can be achieved without causing significant toxicity to normal tissue. Given the great advances and promising future of theranostic nanoparticles, this review highlights the progress that has been made in the past couple of years, the current challenges faced and offers a future perspective.