• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1997년도 춘계학술대회 논문집
• /
• pp.116-119
• /
• 1997

We investigated new type non-robbing liquid crystal (LC) alignment techniques in the cell with slanted non-polarized ultraviolet (UV) irradiation on polyimide (Pl) film. It is shown that the uniform alignment for nematic (N) LC is obtained by using slanted non-polarized UV irradiation on Pl surface. We successfully obtained that the pretilt ang1e of NLC is generated about 3 degree in the LC cells by using slanted non-polarized UV irradiation with 70 degree on Pl surface. We consider that the pretilt angle generation for NLC is attributed to interaction between the LC molecular and the PI surface. We conclude that the uniform LC alignment is attributed to anisotropic dispersion force effect due to photo depolymerization of polymer on Pl surface.

• Bulletin of the Korean Chemical Society
• /
• 제23권4호
• /
• pp.587-592
• /
• 2002

Photocrosslinkable chalcone-epoxy compound comprising 1,3-bis-(4-hydroxy-phenyl)-propenone was synthe-sized for fabricating the photo-alignment layer of liquid crystals. Chalcone group was introduced into the main chain unit of the epoxy oligomer. We observed a photodimerization behavior and an optical anisotropy of this material by irradiation of a linearly polarized UV(LP-UV) light. With a trace amount of cationic photoinitiator (TRS-HFA), polymerization of epoxy groups was also conducted at the similar wavelength range used for photodimerization. Linearly polarized UV irradiation on the chalcone-epoxy films with cationic photoinitiator induced optical anisotropy of the film and the resultant film can be used for alignment layers for low molecular weight nematic liquid crystals.

• 태양에너지
• /
• 제5권2호
• /
• pp.28-34
• /
• 1985

There are two kinds of irradiation intensity deviation, depending on time and position, on illuminated plane when thermal performance of solar collector is tested by using solar simulator. In this study we measured only position deviation of irradiation intensity using 45-cds photosensors and data acqusition system and found the point of average value. By this result we can improve the accuracy of irradiation measurement in indoor test of solar collector.

• 상하수도학회지
• /
• 제18권3호
• /
• pp.392-400
• /
• 2004

This research uses the $TiO_2$/UV process to verify the most suitable condition and possibility to dispose dyeing wastewater that contains pigment and a large amount of pollutants. For this, this research has enforced experiments that compare photo adsorption, photolysis, and photo catalyst oxidation reaction, and also evaluated and analyzed the change of pH and $TiO_2$ dosage, irradiation rates of ultraviolet rays and the dosage change and injection method of $H_2O_2$. According to the results of the dyeing wastewater experiment of storehouse catalyst that uses the new form of $TiO_2$, the photo catalyst oxidation reaction proved to be more effective than photo adsorption and photolysis; 35%, 21% in the case of $TCOD_{cr}$ and 39%, 28% in the case of chromaticity. Taking into consideration the reaction time, amount of photo catalyst reaction and irradiation amount of ultraviolet rays, the decomposition efficiency of pH change proved to be most effective at pH 4. On the whole, the acidity area proved to be effective in dyeing water exclusion than neutral and alkalinity areas. Having evaluated the influence of $TiO_2$ dosage, not only does the decomposition efficiency continuously improve as the $TiO_2$ dosage increases but the shielding effect does not occur also when the $TiO_2$ is at a fixed state. The influence of ultraviolet irradiation amount concluded in the result that as the ultraviolet irradiation amount increases the decomposition efficiency continually increased, but in the case of chromaticity when the irradiation amount was higher than 37.8mW/cm2 the removal efficiency is slowed remarkably. The influence of $H_2O_2$ dosage evaluation reached the results that although the decomposition efficiency increases with the increase of $H_2O_2$ dosage, when above 150mg (total dosage: 1200mg) $H_2O_2$ consumes OH radical itself and reduces the decomposition efficiency. Also in the case of the $H_2O_2$ injection method rather than injecting in the whole amount of $H_2O_2$ (1200mg) needed at the beginning all at once, injecting divided quantities of $H_2O_2$ whenever the electric current density falls below 10mgfl reduces the wases of OH radical due to an excess of $H_2O_2$ and in tum heightens the decomposition efficiency.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
• /
• pp.197-198
• /
• 2000

A surface-assisted photo-control of the liquid crystal (LC) alignment has been achieved by modifying the topmost surface of the polyimide film with photo-reactive molecules. Recently, photo-alignment technique using a thin film of poly(vinyl cinnamates) have been reported. However their commercial potentiality is limited by their low thermal stability. To enhance thermal stability, we synthesized the chalcone derivatives as the photo-reactive molecules and introduced the materials on the surface-modified polyimide film.. We identified that the photo-chemical reaction of the chalcone derivatives occur in few minutes with irradiation of UV light. The photo-alignment characteristics of the modified polyimide films treated by polarized UV light and their LC cells are investigated as a function of exposure dose.

• 한국재료학회지
• /
• 제19권9호
• /
• pp.481-487
• /
• 2009

The photocatalysts of Fe-ACF/$TiO_2$ compositeswere prepared by the sol-gel method and characterized by BET, XRD, SEM, and EDX. It showed that the BET surface area was related to adsorption capacity for each composite. The SEM results showed that ferric compound and titanium dioxide were distributed on the surfaces of ACF. The XRD results showed that Fe-ACF/$TiO_2$ composite only contained an anatase structure with a Fe mediated compound. EDX results showed the presence of C, O, and Ti with Fe peaks in Fe-ACF/$TiO_2$ composites. From the photocataytic degradation effect, $TiO_2$ on activated carbon fiber surface modified with Fe (Fe-ACF/$TiO_2$) could work in the photo-Fenton process. It was revealed that the photo-Fenton reaction gives considerable photocatalytic ability for the decomposition of methylene blue (MB) compared to non-treated ACF/$TiO_2$, and the photo-Fenton reaction was improved by the addition of $H_2O_2$. It was proved that the decomposition of MB under UV (365 nm) irradiation in the presence of $H_2O_2$ predominantly accelerated the oxidation of $Fe^{2+}$ to $Fe^{3+}$ and produced a high concentration of OH radicals.

• 전기학회논문지
• /
• 제57권5호
• /
• pp.803-807
• /
• 2008

A making process of DSC(dye sensitized solar cell) was presented. In general, Photo electrodes of DSC was made by using colloid paste of nano $TiO_2$ and processing of Doctor-blade printing and high temperature sintering for porous structure. These methods lead to cracks on $TiO_2$ surface and ununiform of $TiO_2$ thickness. This phenomenon is one factor that makes low efficiency to cells. After $TiO_2$ printing on TCO glass, a physical vibration was adapted for reducing ununiform of $TiO_2$ thickness. And a thermal treatment at low temperature(under $75^{\circ}C$) was adapted for reducing cracks on $TiO_2$ surface. In this paper, we have designed and manufactured an ultrasonic circuit (100W, frequency and duty variable) and a thermal equipment. Then, we have optimized forcing time, frequency and duty of ultrasonic irradiation and thermal heating for surface treatment of photo-electrode of DSC. In I-V characteristic test of DSC, ultrasonic and thermal treated DSC shows 19% improved its efficiency against monolithic DSC. And it shows stability of light-harvesting from drastically change of light irradiation test.

• Journal of Photoscience
• /
• 제7권1호
• /
• pp.5-8
• /
• 2000

Irradiation of 2'-bromobenzanilide in acetonitrile containing sodium hydroxide under nitrogen leads to the formation of the intramolecular photosubstituted product, 2-phenylbenzoxazole (45 %) along the minor photoreduced and photo-Fries type product. The photoreaction of 2'chlorobenzanilide under the same condition as above gives the photo-Fries type reaction product, 2-amino-3-chlorobenzophenone (22%) with minor product, 2-phenylbenzoxazole. The photoreaction of 2'-chlorobenzanilide in acetonitrile produces a photocyclized product, phenanthridone (19%) along with minor products, 2-phenylbenzoxazole, benzanilide, 2-amino-3-chlorobenzophenone, and 4-amino-3-chlorobenzophenone, while that of 2'-bromobenzanilide produces photosubstituted product, 2- phenylbenzoxazole.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
• /
• pp.668-671
• /
• 2009

Photosensitive polyimide containing methoxy cinnamate derivatives as a photo-alignment layer is investigated. The anisotropy of alignment layer was induced by irradiation linearly polarized UV (LPUV). We studied the effect of the methoxy cinnamate groups on alignment LCs.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1999년도 추계학술대회 논문집
• /
• pp.533-536
• /
• 1999

In this study, we investigated pretilt angle generation and liquid crystal alignment by UV light irradiation during imidization of polyimide. Generated pretilt angle of NLC by using in-situ UV photo-alignment method was smaller than that of the conventional UV photo-alignment method. Also, generated pretilt angle of NLC tends to increase by annealing. We found that in-situ UV photo-alignment method has higher thermal stability of LC alignment, but it has a disadvantage to control pretilt angle.