• 제목/요약/키워드: photo-irradiation

검색결과 325건 처리시간 0.026초

비편광 UV조사에 의한 광배향 VA-LCD의 전기광학특성 (Electro-optical properties of photo-aligned VA-LCD by irradiation of unpolarized UV light.)

  • 박두석;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.545-548
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    • 1999
  • The electro-optical characteristics of photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) with non-polarized ultraviolet (UV) light irradiation of 45\`on homeotropic polyimide (Pl) surface were investigated. LC alignment on photo-aligned VA-LCD is attributed to photo-depolymerized reaction of the polymer with non-polarized UV light irradiation on PI surface. We had good voltage-transmittance (V-T) characteristics of photo-aligned VA-LCD. The response time of photo-aligned VA-LCD was slower than that of the rubbing-aligned VA-LCD. Finally, we suggest that the slow response time of photo-aligned VA-LCD depends on the LC domain.

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PM4Ch 표면을 이용한 광배향 TN-LCD의 전기광학특성 (Electro-optical (EO) characteristics of photo-aligned TN-LCD on PM4Ch surfaces)

  • 황정연;박상건;박태규;서대식;서동학
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1765-1767
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    • 1999
  • We synthesised a photo-alignment material of PM4Ch (poly(4-methacryloylloxychalcone)). The electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PM4Ch surface were investigated. The uniform alignment of NLC with polarized UV light irradiation on PM4Ch surface was measured. Also, We had The excellent voltage-transmittance characteristics of photo-aligned TN-LCD. The low threshold voltage of photo-aligned TN-LCD was measured. Moreover, the fast response time of photo-aligned TN-LCD on PM4Ch was successfully achieved. Finally The reduction DC voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on photo-dimerized PM4Ch surface.

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Thermal and Photochemistry of Methyl Iodide on Ice Film Grown on Cu(111)

  • Sohn, Young-Ku;White, John M.
    • Bulletin of the Korean Chemical Society
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    • 제30권7호
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    • pp.1470-1474
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    • 2009
  • Thermal and photochemistry of methyl iodide ($CH_3I)\;adsorbed\;on\;D_2O$ ice film on Cu(111) at 100 K were studied using temperature-programmed desorption (TPD) time-of-flight mass spectrometry (TOF-MS), X-ray and ultraviolet photoelectron spectroscopies. On the basis of TPD, multilayer and monolayer $CH_3I$ molecules desorb from $D_2O$ ice layer at 120 and 130 K, respectively. Photo-irradiation at 100 K exhibits dramatic changes in the TPD and I $3d_{5/2}\;XPS\;of\;CH_3I$ on ice film, due to a dramatic dissociation of $CH_3I$. The dissociation is likely activated by solvated electrons transferred from the metal substrate during photo-irradiation. No other photo-initiated reaction products were found within our instrumental detection limit. During photo-irradiation, the $CH_3I$, $CH_3$ and I could be trapped (or solvated) in ice film by rearrangement (and self-diffusion) of water molecules. A newly appeared parent molecular desorption peak at 145 K is attributed to trapped $CH_3I$. In addition, the $CH_3$ and I may diffuse through ice and chemisorb on Cu(111), indicated by TPD and I $d_{5/2}$ XPS taken with photo-irradiation time, respectively. No molecular ejection was found during photo-irradiation at 100 K. The work functions for $CH_3I/Cu(111),\;D_2O/Cu(111)\;and\;CH_3I/D_2$O/Cu(111) were all measured to be about 3.9 eV, 1.0 eV downward shift from that of clean Cu(111).

PCEMA 광폴리머의 광중합 작용을 이용한 액정배향 (Liquid crystal alignment by photo-dimerization reaction of PCEMA photo polymer)

  • 황정연;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.541-544
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    • 1999
  • We synthesised a novel photo-alignment material of PCEMA (poly(cinnamolyethyl methacrylate)) on photo-dimerization reaction. Next we investigated the electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PCEHA surface. The excellent voltage-transmittance characteristics of photo-aligned TN-LCD on PCEMA surface were obtained. The threshold voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on PCEMA surface. Also, the response time of photo-aligned TN-LCD on PCEMA surface is almost the same as rubbing-aligned TN-LCD.

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폴리이미드막에 직선편광된 자외선조사를 이용한 TN-LCD의 전기광학특성의 평가 (Electro-optical performance of TN-LCD using linearly polarized UV light irradiation on po1ymide surface)

  • 서대식;이창훈;이정호;문학룡
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.109-112
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    • 1998
  • In this paper, we studied on electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-LCD. We obtained that uniform LC alignment in TN-LCD with linearly polarized ultraviolet (LPUV) light irradiation on polyimide (PI) surface increases according to increasing irradiation time for 10 to 60 min. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with UV light irradiation time of 60 min were almost same in comparison with conventional TN-LCD were observed. From the results, we suggest that photo-aligned TN-LCD with LPUV light irradiation on PI surface is useful in applying LCD as for rubbing-free treatment method.

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Polyethylene Glycol에 의한 수록한지(手漉韓紙)의 광(光) 변색(變色) 억제(抑制) (Control of the Photo-induced Discoloration of the Handmade Korean Paper with Polyethylene Glycol)

  • 전철;박수안
    • 한국산림과학회지
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    • 제89권2호
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    • pp.161-166
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    • 2000
  • 지류문화재의 소재로 주로 사용되어온 수록한지를 네 종류로 구분하고 이를 PEG 분자량과 농도별에 따른 광 변색 억제 효과를 태양의 분광분포와 거의 흡사한 xenon arc 등(燈)을 조사(照射)해 시험한 바 다음과 같이 요약할 수 있었다. 1) Polyethylene glycol을 분산제로 사용한 미 표백 한지는 광 조사 이후 PEG 분자량과는 관계없이 10시간까지는 백색도가 급속히 떨어지는 경향을 보였으나 그 이후부터는 점진적으로 향상되는 경향을 나타내 광 변색 억제의 효과가 있음을 알 수 있었다. 2) 약품 표백을 실시한 한지는 20시간 이후부터 백색도가 증가하는 현상이 나타나 시간이 지체될 뿐 변색 억제의 효과는 있음을 알 수 있었다. 3) 황단규근(黃團葵根)을 분산제로 사용해 초지(秒紙)한 한지(韓紙)는 PEG 400-20%에 침지했을 때 백색도가 가장 낮았으나 광 조사 후는 백색도 차가 가장 적어 광 변색 억제효과가 가장 컸음을 알 수 있었다. 4) 광 열화에 의한 표면현상으로 제일 먼저 나타나는 황변(黃變) 현상을 PEG 침지로써 억제할 수 있음을 b*+값이 감소하는 것으로 알 수 있었고 명도 저하 역시 L* 값의 증가로 상당량 억제할 수 있음을 알 수 있었다.

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Ellipso-Microscopic Observation of Titanium Surface under UV-Light Irradiation

  • Fushimi, K.;Kurauchi, K.;Nakanishi, T.;Hasegawa, Y.;Ueda, M.;Ohtsuka, T.
    • Corrosion Science and Technology
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    • 제15권6호
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    • pp.265-270
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    • 2016
  • The ellipso-microscopic observation of a titanium surface undergoing anodization in $0.05mol\;dm^{-3}$ of $H_2SO_4$ was conducted. During irradiation by ultra-violet (UV) light with a wavelength of 325 nm, the titanium surface allowed for the flow of a photo-induced current and showed up as a bright, patch-like image on an ellipso-microscopic view. The brightness and patch-pattern in the image changed with flowing photo-induced current. The changes in the brightness and the image corresponded to the formation and/or degradation of titanium oxide due to the photo-electrochemical reaction of the oxide. An in situ monitoring using the ellipso-microscope revealed that the film change was dependent on the irradiation light power, by UV-light increases the anodic current and results in the initiation of pitting at lower potentials as compared with the non-irradiated condition.

Hydrophilic Modification of Poly(ethylene oxide) by UV Irradiation

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • 한국염색가공학회지
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    • 제21권5호
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    • pp.16-20
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    • 2009
  • Films of Poly(ethylene oxide), PEO, were modified to impart hydrophilicity via UV irradiation. The UV irradiation treatment produced new photo-oxidized groups of carbonyl and ether groups as indicated in ATR and ESCA analysis. It was found that water contact angle decreased from $15^{\circ}C$ to $10^{\circ}C$ and total surface energy of PEO increased from 54.2 mN/m to 76.6 mN/m with increasing UV energy, which was attributed to significant contribution of acid base interaction of the photo-oxidized PEO rather than nonpolar interaction originating from the dominant increase in Lewis acid parameter. The increased hydrophilicity and surface energy were also proved by the decreased water wetting time.

경사진 자외선 조사를 이용한 TN-LCD의 전기광학 특성 (Electro-optical performance of TN-LCD wish oblique UV light irradiation on polyimide surface)

  • 서대식;박두석;한정민;황율연;박태규
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.113-116
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    • 1998
  • In this paper, we studied the electro-optical(EO) performance of photo-aligned twisted nematic(TN)-liquid crystal display(LCD) with oblique non-polarized ultraviolet(UV) light irradiation on polyimide(Pl) surface. We observed that the voltage-transmittance and response time characteristics of photo-aligned TN-LCD is almost same compared to conventional TN-LCD. Also, we observed that the voltage-holding-ratio(VHR) of photo-aligned TN-LCD is almost same compared to conventional TN-LCD.

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광 CVD에 의한 비정질 실리콘 박막 특성 향상 (The improvement of characteristics for hydrogenated amorphous silicon thin films by photo-induced CVD)

  • 김용상;이성규;전명철;박진석;한민구
    • E2M - 전기 전자와 첨단 소재
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    • 제7권2호
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    • pp.94-99
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    • 1994
  • The purpose of this work is to investigate the interface characteristics of hydrogenated amorphous silicon thin films prepared by PECVD and photo-induced CVD and to examine the annealing effects of ultraviolet irradiation on hydrogenated amorphous silicon thin films which were degraded by visible light illumination. The interface layer thickness of films deposited by photo-induced CVD was about 600-900.angs. while that by PECVD was about 1000-1300.angs.. These results can show that the quality of interface layer in photo induced CVD film is better than that in PECVD sample. The electrical properties are improved by ultraviolet irradiation on visible light soaked a-Si:H films using photo-CVD light sources, probably due to the fact that UV generates phonons in a-Si:H films and anneal the meta stable defects.

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