• 제목/요약/키워드: phosphorescent material

검색결과 107건 처리시간 0.03초

습식 이온 도핑 p-i-n 구조 유기 발광 소자 (Solution Processable Ionic p-i-n OLEDs)

  • 한미영;오승석;박병주
    • 한국전기전자재료학회논문지
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    • 제22권11호
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    • pp.974-979
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    • 2009
  • We studied solution-processed single-layered phosphorescent organic light-emitting diodes (PHOLEDs), doped with ionic salt and treated with simultaneous electrical and thermal annealing. Because the simultaneous annealing causes the accumulation of salt ions at the electrode surfaces, the energy levels of the organic molecules are bent by the electric fields due to the adsorbed ions, i.e., the simultaneous annealing can induce the proper formation of an ionic p-i-n structure. As a result, an ionic p-i-n PHOLED with a peak luminescence of over ${\sim}35,000\;cd/m^2$ and efficiency of 27 cd/A was achieved through increased and balanced carrier-injections.

이중 도핑을 이용한 고효율 적색 인광 유기발광소자 (High Efficiency Red Phosphorescent Organic Light Emitting Devices Using the Double Dopant System)

  • 장지근;신현관;김원기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.351-352
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    • 2008
  • A new high efficient red PhOLED using a host of $Bebq_2$ and double dopants of $(pq)_2$Ir(acac) and SEC-R411 have been fabricated and evaluated. The device doubly doped with $(pq)_2$Ir(acac) and SFC-R411 showed the current efficiency improvement of 22% under a luminance of 10000 cd/$m^2$ in comparision with the device singly doped with SFC-R411. The luminance, current efficiency and central wavelength of the doubly doped device were 9300 cd/$m^2$ at 7V, 11.1 cd/A under a luminance of 10000 cd/$m^2$ and 625 nm, respectively.

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플라스틱 기판을 이용한 고분자 청색 유기발광다이오드의 발광 특성 (Emission Characteristics of Polymer Blue Organic Light Emitting Devices on the Plastic Substrates)

  • 정재훈;문대규
    • 한국전기전자재료학회논문지
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    • 제26권9호
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    • pp.682-685
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    • 2013
  • We have fabricated blue phosphorescent organic light-emitting devices (OLEDs) on a plastic substrate. The solution coated poly (9-vinylcarbazole) (PVK) host doped with Bis (3,5-difluoro-2-(2-pyridyl)phenyl_(2-carboxypyridyl)irdium(III) (FIrPic) guest molecules was used as an hole transporting emission layer. The device structure was ITO/PVK:FIrpic (50 nm, xwt%)/TAZ 50 nm)/LiF (0.5 nm)/Al (100 nm). The concentration of FIrpic molecule was varied from 1 wt% to 10 wt%. The OLED on plastic substrate exhibited maximum current efficiency of 18 cd/A with 5 wt% FIrpic molecules were doped into the PVK layer.

Xe EEFL의 혼합가스에 따른 전기 광학적 특성 (Electrical and Optical properties of Xe EEFL by mixed gas)

  • 김남군;이성진;양종경;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1568-1569
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    • 2007
  • TFT-LCD used in display area is not a light-emissive device itself but TFT-LCD can overcome through the employ of the backlight unit (BLU). BLU is very important device in TFT-LCD system. However, the old-fashion BLU of CCFL type is crucible to the health due to the contained material, mercury (Hg). Moreover, strong temperature dependency of lamp employed with Hg becomes the other disadvantage in practical usage. To solve these problems, Hg-Free lamp with strong thermal resistance property is required to displace the Hg lamp. We studied optical and electrical properties of Xe-Ne-He mixed gas that is dependent on change of mixed ratio and pressure. In our results, the designed lamp without the phosphorescent material has the lowest firing voltage at xe 50%(Ne:He=9:1).

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새로운 이리듐 화합물을 이용한 적색 인광 유기 발광 다이오드 (Red Electrophosphorescent Organic Light-emitting Diodes Based on New Iridium Complexes.)

  • 공두원;김준호;이금희;윤승수;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.73-74
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    • 2006
  • New iridium complexes that have carbonyl group were synthesized and demonstrated various red light emission in organic light-emitting diodes (OLEDs). The maximum luminance of $57000{\sim}15300\;cd/m^2$ at 15 V and the luminance efficiency of 22.8~5.6 cd/A at $20\;mA/cm^2$ were achieved respectively. The peak wavelength of the electroluminescence were at 570~604 nm and the device also showed a stable color chromaticity with various voltages.

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정공수송층이 역구조 OLED의 전기 및 광학적 특성에 미치는 영향 (Effect of Hole Transport Layer on the Electrical and Optical Characteristics of Inverted Organic Light-Emitting Diodes)

  • 임세진;문대규
    • 한국전기전자재료학회논문지
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    • 제36권4호
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    • pp.397-402
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    • 2023
  • We have developed inverted green phosphorescent organic light emitting diodes (OLEDs) using 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC) and bis(carbazole-9-yl)biphenyl (CBP) hole transport layers. The driving voltage, current efficiency, power efficiency, and emission characteristics of devices were investigated. While the driving voltage for the same current density was about 1~2 V lower in the devices with the TAPC layer, the maximum luminance was higher in the device with the CBP layer. The maximum current efficiency and power efficiency were 3.2 and 2.7 times higher in the device with the CBP layer, respectively. The higher efficiency in the CBP device resulted from the enhanced hole-electron balance although weak parasitic recombination takes place in the CBP hole transport layer.

$CsN_3$ as an air stable and low temperature evaporable novel n doping material for high efficiency and low driving voltage in organic light-emitting diodes

  • Lee, Jun-Yeob;Yook, Kyoung-Soo;Jeon, Soon-Ok;Joo, Chul-Woong;Lee, Tae-Woo;Noh, Tae-Yong;Yang, Haa-Jin;Kang, Sung-Kee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1319-1322
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    • 2008
  • $CsN_3$ was developed as a novel n doping material with air stability and low deposition temperature. Evaporation temperature of $CsN_3$ was similar to that of common hole injection material and it worked well as a n dopant in electron transport layer. Driving voltage was lowered and high power efficiency was obtained in green phosphorescent devices by using $CsN_3$ as a dopant in electron transport layer. It could also be used as a charge generation layer in combination with $MoO_3$. In addition, n doping mechanism study revealed that $CsN_3$ is decomposed into Cs and $N_2$ during evaporation. This is the first work reporting air stable and low temperature evaporable n dopant in organic light-emitting diodes.

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Salen-Aluminum Complexes as Host Materials for Red Phosphorescent Organic Light-Emitting Diodes

  • Bae, Hye-Jin;Hwang, Kyu-Young;Lee, Min-Hyung;Do, Young-Kyu
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3290-3294
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    • 2011
  • The properties of monomeric and dimeric salen-aluminum complexes, [salen(3,5-$^tBu)_2$Al(OR)], R = $OC_6H_4-p-C_6H_6$ (H1) and R = [salen(3,5-$^tBu$)AlOPh]C$(CH_3)_2$ (H2) (salen = N,N'-bis-(salicylidene)-ethylenediamine) as host layer materials in red phosphorescent organic light-emitting diodes (PhOLEDs) were investigated. H1 and H2 exhibit high thermal stability with decomposition temperature of 330 and $370^{\circ}C$. DSC analyses showed that the complexes form amorphous glasses upon cooling of melt samples with glass transition temperatures of 112 and $172^{\circ}C$. The HOMO (ca. -5.2~-5.3 eV) and LUMO (ca. -2.3~-2.4 eV) levels with a triplet energy of ca. 1.92 eV suggest that H1 and H2 are suitable for a host material for red emitters. The PhOLED devices based on H1 and H2 doped with a red emitter, $Ir(btp)_2$(acac) (btp = bis(2-(2'-benzothienyl)-pyridinato-N,$C^3$; acac = acetylacetonate) were fabricated by vacuum-deposition and solution process, respectively. The device based on vacuum-deposited H1 host displays high device performances in terms of brightness, luminous and quantum efficiencies comparable to those of the device based on a CBP (4,4'-bis(Ncarbazolyl) biphenyl) host while the solution-processed device with H2 host shows poor performance.

축광노면표시 시인성 개선에 따른 경제성 분석 및 적용방안 (Effectiveness Analysis and Application of Phosphorescent Pavement Markings for Improving Visibility)

  • 이용주;이규진;김상태;최기주
    • 대한토목학회논문집
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    • 제37권5호
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    • pp.815-825
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    • 2017
  • 야간 혹은 우천시에 노면표시의 시인성이 저하되어 교통안전에 위협을 초래하고 있는 가운데, 본 연구에서는 최근 소개된 차선도색 장비 성능개량에 따른 노면표시 수명 연장(1.5배), 생산성 향상(56.3%), 축광차선도료를 배합한 야광 노면표시의 시인성 개선(97.0%) 등 다양한 기대 편익과 종합적인 소요비용을 고려한 경제적 타당성을 제시하고자 하였다. 노면표시 시인성 개선에 따라 45.4%의 사고가 감소, 연간 2,463억원의 교통사고 절감편익이 발생하며, 재도색주기 증가에 따른 공사중 교통혼잡비용 절감 연간 123억원, 자율주행자동차 차선인식 성능 개선에 따른 장비 가격 절감으로 연간 453억원의 편익이 발생하여, 축광노면표시 도입에 따른 연간 총 편익은 3,039억원으로 산정되었다. 전국 도로 91,195km의 차로구분선, 중앙선 및 가장자리차선에 야광차선 도입시 총비용 증가분은 연간 1조 9,222억원으로 경제성(비용-편익비 0.16) 확보가 어려운 것으로 나타났다. 교통사고 잦은 곳의 지방부 분석 구간길이(400m)에 대한 도로유형별 차로수별 차선도색비용과 교통사고비용 원단위를 적용하여 축광 노면표시의 경제적 타당성이 확보되는 사고 규모를 산정한 결과, 노면표시가 직 간접적 원인인 사고로 유발된 사망자가 연간 1명 이상이거나, 부상자가 연간 2명 이상(단, 왕복 4차로 미만인 경우는 연간 1명 이상)인 경우 경제적 타당성이 확보되는 것으로 나타났다. 구체적으로, 관련 사고구간(5,697개)에 대한 야광 노면표시 설치비용을 사고감소편익과 비교한 결과, 충분한 경제성(비용-편익비 3.91)이 확보되었다. 연구의 한계와 향후 연구주제가 논문의 말미에 토의되었다.

Red Electrophosphorescence from Poly(BP-alt-BCV) Conjugated Polymer Doped with an Ir-Complex

  • Baek, Jeong-Ju;Jeong, Young-Chul;Han, Yoon-Soo;Jeong, Jeon-Woo;Kwon, Young-Hwan;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.599-601
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    • 2004
  • A new blue electroluminescent conjugated polymer, poly(BP-alt-BCV), was prepared by Hornor-Emmons polycondensation and used as a host polymer for the phosphorescent dopant, $(bsn)_2Ir(acac)$. Poly(N-vinylcarbazole) (PVK), known as a blue EL material, was also used for comparison with poly(BP-alt-BCV). Electrophosphorescence of PLEDs with these dopant/host systems was investigated in terms of luminescence, efficiency, emission color, and energy transfer.

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