• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.583-587
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• 2006

In this study, the phosphate adsorption characteristics of zirconium mesostructures synthesized under different conditions were estimated. X-ray diffraction analysis, phosphate adsorption isotherm test and kinetic test was performed for the zirconium mesostructures synthesized at different inorganic/surfactant molar ratio and with different surfactant templates. The test results were analyzed with adsorption models. From this work, it was found that at the inorganic/surfactant molar ratio of 1/0.50($0.013{\cdot}Zr(SO_4){_2}:0.068{\cdot}surfactant:5.55{\cdot}H_2O$), the meso-pores in the material could be most uniformly and clearly formed and thus the adsorption capacity and reaction rate of material could be maximized. And the pore size in the mesostructure increased with the chain length of surfactant template used, and maximum phosphate adsorption amount and reaction rate could be achieved with the zirconium mesostructure synthesized with the surfactant template of dodecyltrimethylammonium bromide.

• Nutritional Sciences
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• v.9 no.1
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• pp.48-54
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• 2006

Methods have been developed to evaluate the total antioxidant capacity of foods and plasma but limitations are associated with their ability to determine precisely the contribution of lipophilic antioxidants in a lipid milieu as well as interactions among them Thus, we modified the Oxygen Radical Absorbance Capacity (ORAC) assay to determine the peroxyradical scavenging ability of both hydrophilic and lipophilic compartments in plasma The hydrophilic ORAC assay was performed in a phosphate buffer system utilizing 2,2'-azobis (2-amidinopropane) dihydrochloride as a peroxyradical generator and fluorescein as the target The lipophilic ORAC assay was carried out in a dimethylsulfoxide :butyronitrile (DMSO/BN, 9:1 v/v) system using 2,2'-azobis (2,4-dimethyl valeronitrile) as a peroxyradical generator and BODIPY C11 581/591 as the target Analyses were conducted in bovine serum supplemented with water - and lipid - soluble antioxidants and in human plasma. Albumin (0.5$\sim$5 g/dL) and uric acid (0.1$\sim$0.5 $\mu$mol/L) increased hydrophilic ORAC values in a dose-dependent fashion ($R^{2}$=0.97 and 0.98, respectively) but had no impact on lipophilic ORAC values. $\alpha$-Tocopherol (15$\sim$200 $\mu$mol/L) increased lipophilic ORAC values in a dose-dependent fashion ($R^{2}$=0.94); neither $\alpha$-tocopherol nor $\beta$-carotene had an impact on hydrophilic ORAC values. However, addition of $\beta$-carotene at physiological concentration (0.23$\sim$1.86 $\mu$mol/L), either alone or in combination with other carotenoids, had no significant impact on lipophilic ORAC values. Thus, while assays of 'total antioxidant capacity' in biological matrices would be a useful research and clinical tool, existing methods are limited by the lack of complete responsiveness to the full range of dietary antioxidants.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.8
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• pp.909-914
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• 2007

Fluorine compounds are the essential chemicals for wet processes of semiconductor and LCD production line. Problems of conventional treatments for fluoride wastewater are their high operation costs and low fluoride removal capacity. In this study, cement paste containing various Ca-bearing hydrates such as portlandite, calcium silicate hydrate(CSH), and ettringite was investigated for fluoride removal. The objectives of this study are to assess the feasibility of using cement paste cured mixture of cement and water as an alternative agent for treatment of fluoride wastewater and to investigate fluoride removal capacity of the cement paste. The performance of cement paste was comparable to that of lime in the kinetic test. In column experiment where the effluent fluoride concentrations were below 0.5 mg/L. Then the leached calcium reached the maximum level of 800 mg/L. The nitrate reduced to the level of less than 10 mg/L. Nitrate in the wastewater was exchanged with interlayer sulfate of these cement hydrate LDHs. Phosphate concentration could be reduced to 10 mg/L by forming calcium phosphate. These results indicate that the cement paste generally has advantageous characteristics as an economical and viable substitute for lime to remove fluoride.

• Korean Journal of Environment and Ecology
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• v.29 no.5
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• pp.777-784
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• 2015

This study verified the correlations between vegetation factors, such as the number of individual species and species diversity, and soil factors in Chamaecyparis obtusa (CO) stands in Jeollanam-do. Also, the site environmental factors that affect the annual growth of CO ring width were analyzed. Positive correlations were found between the species diversity index and Cation Exchange Capacity (CEC), available phosphate, and exchangeable $K^+$ (P<0.01). In addition, strong positive correlations were also found between the number of species that appeared in the study site and CEC, available phosphorus, exchangeable $K^+$ and exchangeable $Mg^{2+}$ (P<0.01). Tree ring growth showed strong correlations with the nutrient holding capacity and fertility of soil, including available phosphate, exchangeable $K^+$, CEC, and electrical conductivity (P<0.01). The explanatory variables of tree ring growth in CO were composed of exchangeable $K^+$, organic matter content, and soil pH. The regression model had a high level of explanatory power, 74.4%. In this model, the annual growth of CO ring width increased when exchangeable $K^+$ and organic matter content were higher but decreased when soil pH was lower. According to the analysis, it is found that the annual growth of CO ring width was significantly affected by soil fertility, including available phosphate, exchangeable $K^+$, CEC, and electrical conductivity. In addition, the soil fertility of CO stands seems to be significantly affected by the supply of fallen leaves from the understory vegetation of CO.

• Applied Chemistry for Engineering
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• v.34 no.6
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• pp.596-602
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• 2023

Chromium-based metal-organic frameworks (MIL-101(Cr)) were synthesized, and their potential use as a filling material for gas masks or protective clothing was assessed through adsorption experiments using diisopropyl methyl phosphate (DIMP) as a simulant for chemical warfare agents. MIL-101(Cr) was prepared using acetic acid (MIL-101(Cr)-A) and sodium hydroxide (MIL-101(Cr)-N) as modulators. The use of acetic acid as a modulator resulted in a larger specific surface area and a higher DIMP adsorption capacity. MIL-101(Cr)-A absorbed approximately 160% of its own weight of moisture when exposed to an environment with a relative humidity of 90% for 10 days, surpassing other adsorbents such as activated carbon. The DIMP adsorption capacity of MIL-101(Cr)-A decreased to about 40% of its initial adsorption capacity after 24 hours of exposure to an environment with a relative humidity of 90%. However, this capacity is still higher compared to that of activated carbon used in commercial gas masks, suggesting a high potential for future use as a filling material for gas masks or protective clothing.

• Journal of Periodontal and Implant Science
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• v.39 no.sup2
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• pp.223-230
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• 2009

Purpose: Synthetic bone products such as biphasic calcium phosphate (BCP) are mixtures of hydroxyapatite (HA) and ${\beta}$-tricalcium phosphate (${\beta}$- TCP). In periodontal therapies and implant treatments, BCP provides to be a good bone reconstructive material since it has a similar chemical composition to biological bone apatites. The purpose of this study was to compare bone regeneration capacity of two commercially available BCP. Methods: Calvarial defects were prepared in sixteen 9-20 months old New Zealand White male rabbits. BCP with HA and ${\beta}$- TCP (70:30) and BCP with Silicon-substituted hydroxyapatite (Si-HA) and ${\beta}$-TCP (60:40) particles were filled in each defect. Control defects were filled with only blood clots. Animals were sacrificed at 4 and 8 week postoperatively. Histomorphometric analysis was performed. Results: BCP with HAand ${\beta}$- TCP 8 weeks group and BCP with Si-HA and ${\beta}$- TCP 4 and 8 weeks groups showed statistically significant in crease (P <0.05) in augmented area than control group. Newly formed bone area after 4 and 8 weeks was similar among all the groups. Residual materials were slightly more evident in BCP with HA and ${\beta}$- TCP 8 weeks group. Conclusions: Based on histological results, BCP with HA and ${\beta}$- TCP and BCP with Si-HA and ${\beta}$- TCP appears to demonstrate acceptable space maintaining capacity and elicit significant new bone formation when compared to natural bone healing in 4 and 8 week periods.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.713-721
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• 2012

In many instances phosphorus is a limiting factor for eutrophication in streams, and lakes. Because wastewater treatment plant itself may be the main phosphorus source in a natural water body, removal of phosphorus in final effluent of wastewater treatment processes is required. Amongst various technologies for phosphorus removal in wastewater, adsorption technology was investigated using activated Ca-loess complex. Ca was added in loess to enhance adsorption capacity and intensity of phosphorus. Ca added loess was activated at a high temperature of $400^{\circ}C$ which turned out to be the optimum temperature. Activated Ca-loess complex below $400^{\circ}C$ had not enough strength to be applied as an activated Ca-loess pallet column in wastewater treatment process. Ca-loess complex which activated above $400^{\circ}C$ lost its adsorption capacity as the loess surface was glassified when the activation temperature reached above $400^{\circ}C$20. Even if adsorption capacity of activated Ca-loess was not very high due to the lack of abundant pores on its surface, adsorption intensity was still high because it was activated with added Ca in loess. Activated loess was made by pallets. The activated loess pallets were filled in a column, and were applied in wastewater treatment process. Using an activated Ca-loess pallet column, total phosphorus (T-P) was reduced from about 0.5 mg/l to lower than 0.1 mg/l in wastewater treatment, and ionic phosphorus (phosphate) was completely removed for the four months of pilot plant operation.

• Food Science and Biotechnology
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• v.16 no.3
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• pp.444-450
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• 2007

The antioxidant activity and isoflavone content of chokong, Rhynchosia nolubilis seeds pickled in vinegar at $4^{\circ}C$ for 2 weeks, were investigated. The polyphenol content and 2,2-diphenyl-1-pycrylhydrazyl (DPPH) radical-scavenging capacity were lower in chokong than in raw seeds. Based on isoflavone analysis, the aglycone (daidzein and genistein) content was high in chokong while the content of the corresponding glucosides (daidzin and genistin) was similar to that in raw seeds. Thermal processing, in which seeds were heated in vinegar at $121^{\circ}C$ for 20 min, reduced the polyphenol content but did not affect the DPPH radical-scavenging capacity compared to the pickling process. The heated seeds had a 2.6 to 2.7 times higher glucoside content and 51 to 55% lower aglycone content than chokong, depending on the kind of vinegar used. During pickling and thermal processing, vinegars were more effective at eluting antioxidants and isoflavones from seeds than other solutions such as acetic acid, citric acid and HCl solutions, distilled water, and phosphate buffer (pH 7.0).

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.182-186
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• 2001

An acid forest surface soil as a land farming medium was treated with a water plant alum sludge at 0 to 18%. Indian mustard was grown in the treated soil in a greenhouse for 5 weeks and watered with pH 4 tap water adjusted with a mixed acid (1HNO$_3$: 2H$_2$SO$_4$) during plant growth. Changes in soil property, leachate chemistry, plant growth, and plant uptake of elements by the sludge treatment were determined. The alum sludge treatment increased buffer capacity to acidity, hydraulic conductivity, water holding capacity, and phosphate adsorption of the soil and decreased bulk density and mobility of small particles. The sludge treatment reduced leaching of Al, Mg, K, Na, and root elongation. Plant did uptake less amount of the cations and P but more Ca with the sludge treatment.

• Journal of Electrochemical Science and Technology
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• v.5 no.4
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• pp.109-114
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• 2014

The $Li_3V_2(PO_4)_3$/graphene nano-particles composite was successfully synthesized by a facile sol-gel method. The addition of a graphene in $Li_3V_2(PO_4)_3(LVP)$(LVP) showed the high crystallinity and influenced the morphology of the $Li_3V_2(PO_4)_3$ particles observed in X-ray diffraction (XRD) and scanning electron microscopy (SEM). The LVP/graphene samples were well connected, resulting in fast charge transfer. The effect of the addition graphene nano-particles on electrochemical performance of the materials was investigated. Compared with the pristine LVP, the LVP/graphene composite delivered a higher discharge capacity of $122mAh\;g^{-1}$ at 0.1 C-rate, better rate capability and cyclability in the potential range of 3.0-4.3 V. The electrochemical impedance spectra (EIS) measurement showed the improved electronic conductivity for the LVP/graphene composite, which can ensure the high specific capacity and rate capability.