• Journal of the Korean Ceramic Society
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• v.37 no.3
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• pp.280-287
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• 2000

Adsorption behavior and amount of phenolic resin followed silica (SiO2) formation onto silicon nitride(Si3N4) surface were investigated using electrokinetic sonic amplitude (ESA) technique and with UV spectrometer, to fabricate Si3N4/SiC nano-composite based on reaction between SiO2 formed and phenolic resin absorbed onto Si3N4 particle. The amount of SiO2 formed and carbon from phenolic resin absorbed onto Si3N4 surface were calculated quantitatively to adjust the reaction between SiO2 and phenolic resin, resulting in no residual SiO2 and carbon. As a result, pre-heated tempeature for optimized reaction was below 25$0^{\circ}C$, in which there was no residual SiO2 and carbon.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.77-82
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• 1999

탄소 fabric 표면을 각기 다른 농도의 인산용액으로 표면처리함으로써 2-D 카본/페놀릭 복합 재료에 미치는 물성과 내 산화성, Arc plasma Torch test를 통하여 내열성등을 알아보았으며 ESCA를 통하여 인산 표면 처리에 의한 표면 functionality를 측정하였다.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.160-163
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• 1999

The mechanical properties and failure behaviour of carbon/phenolic composites were inverstigated by tension and compression. Carbon/phenolic composites were fabricated by infiltration of matrix into 8 harness satin woven fabric of PAN-based carbon fibers. The tensile and compressive tests were performed at 25℃ under air atmosphere and, at 400℃ and 700℃ under N₂ atmosphere. The tensile strengths of carbon/phenolic composites in with-laminar/0° warp direction were about 10 times higher than those in with-laminar/45° warp direction, which was analyzed due to a change of fracture mode from fiber pull-out by shear to tensile fracture of fibers. The fracture of carbon/phenolic composites in with-laminar/45° direction was analyzed due to delamination by buckling. Tensile and compressive strength of carbon/phenolic composites decreased to about 50% at 400℃, and to about 10% at 700℃ compared to that at room temperature. The main reason for the decrease of tensile or compressive strength with increasing temperature was analyzed due to a reduction of bond strength between fibers and matrix resulting from thermal degradation of phenolic resin.

• Composites Research
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• v.16 no.3
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• pp.49-57
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• 2003

This paper presents the tensile characteristics for carbon/epoxy, carbon/phenolic and silica/phenolic composites under elevated temperature, which are considered for vehicle structure or thermal protection materials. The tensile test was conducted with servo-hydraulic testing machine and high temperature furnace, and the mechanical properties such as tensile strength, elastic modulus and Poisson's ratio were evaluated by using high temperature strain gages. Also, they were compared each other with respect to fiber orientation and temperature effect. These test results were used for designing and analyzing some airframe structures with these composites.

• Composites Research
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• v.18 no.3
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• pp.47-52
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• 2005

Pultrusion process of phenolic foam composite is investigated. Phenolic foam composites provide heat and flame resistance with less weight. When made into foam, a variety of properties can be obtained with different bubble size and number density. In this study, effect of process variables on the foaming characteristics of phenolic resin composites during pultrusion process has been studied experimentally. The process variables considered are the heating temperature and the pulling speed as well as the mass fraction of blowing agent. Experiments were performed using a laboratory scale pultrusion apparatus. Optimal process condition was found by observing the micro-morphology.

• Journal of Adhesion and Interface
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• v.13 no.2
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• pp.58-63
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• 2012

CFRP chip is the byproduct from carbon fiber reinforced plastic (CFRP) processing. CFRP chip is not simply a waste mainly composed of fine carbon fiber and epoxy resin. CFRP chip keeps matrix to maximize their reinforcing effect. To obtain a uniform length of carbon fiber in CFRP chip, chip was chopped ina mortar. CFRP chip should be purified to get better interface adhesion. Epoxy resin on the carbon fiber was removed by $H_2O_2$ surface etching treatment. Optimal dispersion and fabrication conditions of CFRP chip embedded in phenolic resin were determined by thermal stability for fire retardant applications. CFRP chip-phenolic composite exhibits better mechanical and thermal properties than neat phenolic resin. Surface condition of CFRP chip-phenolic composite was evaluated by static contact angle measurement. Contact angle of CFRP chip-phenolic composite was greater than neat phenolic due to heterogeneous condition of fine carbon fibers. From the evaluation for fire retardant (ASTM D635-06) test, thermal stability of CFRP chip-phenolic composite was found to be improved with higher concentration of CFRP chip.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.11a
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• pp.219-223
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• 2005

In this work, a hybrid composite proceeding bearing (HCJB) composed of carbon/phenolic laminated composite bush and steel housing was designed for marine vessels because the composite proceeding bearing reduces the possibility of the seizure problem between the proceeding and bearing. The two components of bearing were assembled by interference fit joining method and a series of durability tests were conducted using the laboratory bench with the lubricants of SAE 30 oil, water, and sea water. That the HCJB was found reliable under the interference fitting loads and environmental temperature change.

• Composites Research
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• v.12 no.3
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• pp.75-83
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• 1999

The thermal properties of carbon/phenolic and silica/phenolic ablative composites were investigated by measuring the heat capacity, thermal diffusivity and thermal conductivity. The heat capacities of carbon/ phenolic and silica/phenolic composites were calculated from differential scanning calorimeter curve. The thermal diffusivities of carbon/phenolic and silica/phenolic composites were measured by the laser flash method with varying laminated direction, i.e., with laminar direction and across laminar direction. The thermal diffusivities decreased with increasing temperature. The thermal conductivities of carbon/phenolic and silica/phenolic composites were calculated using the heat capacity, density and thermal diffusivity. The thermal conductivities increased with increasing temperature. The thermal conductivity of with laminar direction is two times higher than that of across-laminar direction in carbon/phenolic composite due to the directionality of thermal conductivity of carbon fiber. The thermal conductivities of two dimensional fiber reinforced composites were analyzed using the conductivities of constituents and volume fraction of each constituent. The thermal conductivities of carbon fiber and silica fiber were calculated from thermal conductivities of carbon/phenolic and silica/phenolic composites. The thermal conductivities of carbon/phenolic and silica/phenolic composites at RT were predicted from thermal conductivities of fiber and resin with varying the volume fraction of fiber.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.130-133
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• 2005

An experimental and theoretical study was carried out to estimate the foaming characteristics in the pultrusion process of phenolic foam composite. For the experimental study, a lab-scale pultrusion apparatus was constructed. Methylene chloride(CH2Cl2) was used as a physical blowing agent, glass fiber roving was used as reinforcement and the polymer used was a resol type phenolic resin. Pultruded products were observed to count bubble size by a SEM(Scanning Electron Microscopy). For the theoretical study, a model for bubble growth in a gradually hardening resin was considered and solved for a few foaming conditions.

• Composites Research
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• v.22 no.2
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• pp.18-23
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• 2009

Failure of Kevlar29/Phenolic composite plate under high velocity impact of FSP(Fragment Simulation Projectile) is investigated using a non-linear explicit finite element code, LS-DYNA. Composite laminate and impactor are idealized by solid element and interface between laminas are modeled by tied-break element in LS-DYNA. Interaction between impactor and laminate is simulated face-to-face eroding contact algorithm. When the stress level meets a failure criteria, the layer in the element is eroded. Numerical results are verified by existing test results.