• Title/Summary/Keyword: phenolic composite

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Deflection Characteristics of Permanent Formwork Using Multi-layer Insulation (다층형 단열재를 사용한 영구거푸집의 처짐 특성)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Song, Sung-Yong;Kim, Deuck Mo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.130-131
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    • 2019
  • As part of recent low-energy policies, thermal insulation standards for buildings are being tightened every year. In addition, the conventional styrofoam insulating material has a problem that the thickness of the heat insulating material to achieve a standard heat permeability is rapidly increased. Due to the thick insulation, there is a high risk of spreading vulnerable structures such as fire due to lack of space between buildings. On the other hand, the method of using the insulation as a formwork is known to be excellent cost saving effect through the reduction of the formwork usage and the simplification of the external insulation work. In order to solve this problem, this study aims to fabricate a multi-layered insulator that combines high-performance phenolic foam insulation and styrofoam insulation and evaluate the deflection characteristics for use as formwork.

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Electrochemical Characteristics of Silicon/Carbon Composites with CNT for Anode Material (CNT를 첨가한 Silicon/Carbon 음극소재의 전기화학적 특성)

  • Jung, Min zy;Park, Ji Yong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.16-21
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    • 2016
  • Silicon/Carbon/CNT composites as anode materials for lithium-ion batteries were synthesized to overcome the large volume change during lithium alloying-de alloying process and low electrical conductivity. Silicon/Carbon/CNT composites were prepared by the fabrication processes including the synthesis of SBA-15, magnesiothermic reduction of SBA-15 to obtain Si/MgO by ball milling, carbonization of phenolic resin with CNT and HCl etching. The prepared Silicon/Carbon/CNT composites were analysed by XRD, SEM, BET and EDS. In this study, the electrochemical effect of CNT content to improve the capacity and cycle performance was investigated by charge/discharge, cycle, cyclic voltammetry and impedance tests. The coin cell using Silicon/Carbon/CNT composite (Si:CNT=93:7 in weight) in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC:DMC:EMC=1:1:1 vol%) has better capacity (1718 mAh/g) than those of other composition coin cells. The cycle performance of coin cell was improved as CNT content was increased. It is found that the coin cell (Si:CNT=89:11 in weight) has best capacity retension (83%) after 2nd cycle.

How Phenolic Composites were chosen - In Case of England (7) (페놀 컴포지트 실용화의 길 - 영국의 경우 (CASE STUDY 7))

  • Nomaguchi Kanemasa;Forsdyke Ken L.
    • Composites Research
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    • v.18 no.1
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    • pp.55-66
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    • 2005
  • Beside fire resistance, for Phenolic Composites(here-in-after PCs), in actual, moisture resistance are also needed when they are applied to components in wet uses such as in Naval vessels and in off-shore operations where direct water contact may be expected. PCs have so-called 'Micro-porous' when they are made by normal GRP manufacturing techniques, which causes much larger amounts of water absorption in them to higher level of around $7\%$. So, this figure, which indicate impending disaster in a polyester matrix laminate, has made some specifiers suspicious of the effect of the water on mechanical performance of PC in 'wet' service. To solve this problem, a large amount work has been carried out by workers in UK and US. This paper is an attempt to explain that the effect of the high water absorption of PCs is not the disaster that some 'prophets' may foretell. Let's open our next door fur better society much safetyfied by our own efforts with PCs. like in UK.

How Phenolic Composites were chosen - In Case of England (5) (페놀 컴포지트 실용화의 길 - 영국의 경우 (CASE STUDY 5))

  • Nomaguchi, Kanemasa;Forsdyke, Ken L.;Brown, Denver E.
    • Composites Research
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    • v.17 no.5
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    • pp.85-95
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    • 2004
  • Other than in the fields of rolling stock and marine, in England, UK, Phenolic Composites (herein after, PCs) have been significantly utilized to fire protecting panels in construction, in particular, in architectures. In general, indeed, so-called "Plastic" or "Synthesized Resins" have been applied successfully in our societies all over the world, however, once, when ignited from somewhat reason, they burn much easily generating large amount of "SMOKE" from their nature of petroleum-borne materials as a matter of fact, people have forgotten about it. "SMOKE" caused many fire accidents horror tragedies as everyday people know today. The experts in this field such as PC engineers, researchers and others can take their responsibilities to explain it, persuade it and realize "Safer Environment for People" with well-experienced and technology innovated PCs. In this paper, the co-authors, collaborating UK and Japan, are making efforts to report how the PCs work good jobs to our societies showing some successful track records in construction or architecture fields in UK. How about on this matter in Japan\ulcorner "SMOKE fire" is always waiting fur us. We should stop smoking and SMOKE fire, in our public places.We should stop smoking and SMOKE fire, in our public places.

Optimization of Alcalase for Krill Byproduct Hydrolysis and Antioxidative Activities by Response Surface Methodology

  • Kim, Kyoung-Myo;Lee, Da-Sun;Nam, Min-Hee;Yoo, Hong-Seok;Kim, Seon-Bong;Chun, Byung-Soo;Lee, Yang-Bong
    • Preventive Nutrition and Food Science
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    • v.15 no.4
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    • pp.316-321
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    • 2010
  • Krill byproduct was hydrolyzed with Alcalase 2.4L to produce functional ingredients for high antioxidative activities against 1,1-dimethyl-2-picryl-hydrazyl (DPPH) radical and Fe. The objective of this study was to investigate the optimum condition for degree of hydrolysis and antioxidative activity of enzymatic hydrolysate produced with the commercial Alcalase using response surface methodology (RSM) with a central composite rotatable design (CCRD). The ranges of independent variables were pH 7.6~10.4 for initial pH and $50.9{\sim}79.1^{\circ}C$ for hydrolysis temperature and their dependent variables were degree of hydrolysis, Brix, amount of phenolic compounds, DPPH-scavenging activity and Fe-chelating activity. RSM with CCRD was well designed to investigate the optimum condition for functional ingredients with high antioxidative activities using Alcalase 2.4L because of their high $R^2$ values of the range of 0.93~0.99 except the $R^2$ value of 0.50 for the amount of total phenolic compounds. The optimum hydrolysis conditions were pH 9.5 and $62^{\circ}C$ for degree of hydrolysis (DH) and pH 9.1 and $64^{\circ}C$ for DPPH-scavenging activity by response surface methodology. The yield of DH and DPPH-scavenging activity were $14.1{\pm}0.5%$ and $10.5{\pm}0.2%$, respectively. It is advantageous to determine the optimum hydrolysis conditions of krill and its by-products for the creation of different kinds of food products, as well as to increase the usage of marine protein sources.

Development of an Onion Vinegar Beverage Containing Yuza (Citrus junos Sieb ex Tanaka) and Its Biological Activity (유자 첨가 양파발효음료의 제조 및 생리활성)

  • Jeong, Eun-Jeong;Cha, Yong-Jun
    • Journal of Life Science
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    • v.26 no.5
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    • pp.563-570
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    • 2016
  • Onion vinegar has an undesirable flavor and taste that results from alcohol and acetic acid production from fermentation. In this study, we have used onion vinegar to develop an onion vinegar beverage with better sensory quality. The objective of this study was to determine the optimum blending ratio by using response surface methods to produce an onion vinegar beverage containing Yuza (Citrus junos Sieb ex Tanaka). The optimal formula for a fermented onion beverage was determined using a central composite design by the response surface methodology. The independent variables were obtained by regression analysis of the reaction surface of brown sugar, apple extracts and Yuza extracts. The optimum mixing ratio for onion vinegar:water:brown sugar:apple extracts:Yuza extracts was 6.0:77.6:4.9:9.2:2.3 (w/w). The actual overall acceptance was 7.08 under optimum conditions, which was close to the maximum predicted value of 6.96. The concentration of phenolic compounds, total flavonoids, and quercetin present in the onion vinegar beverage was 14.8 mg/100 g, 2.6 mg/100 g and 1.4 mg/100 g, respectively. The onion vinegar beverage showed antimicrobial activity against Staphylococcus aureus, Escherichia coli, Salmonella typhimurium and Enterobacter aerogenes. It also showed antioxidant effects, with a DPPH radical inhibition rate of 18.2% and superoxide dismutase (SOD)-like activity of 11.5%. In conclusion, the onion vinegar beverage described here seems to have nutritional value and potential biological activity.

Effect of HTT on Bending and Tensile Properties of 2D C/C Composites

  • Dhakate, S.R.;Aoki, T.;Ogasawara, T.
    • Carbon letters
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    • v.6 no.4
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    • pp.234-242
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    • 2005
  • Bending and tensile properties of 2D cross-ply C/C composites with processing heat treatment temperature (HTT) are evaluated. C/C composites used are made from two types of PAN based T700 and M40 carbon fibers with phenolic resin as carbon matrix precursor. Both the types of composites are heat treated at different temperatures (ranging from 750 to $2800^{\circ}C$) and characterized for bending and tensile properties. It is observed that, real density and open porosity increases with HTT, however, bulk density does show remarkable change. The real density and open porosity are higher in case T-700 carbon fiber composites at $2800^{\circ}C$, even though the density of M40 carbon fiber is higher. Bending strength is considerably greater than tensile strength through out the processing HTT due to the different mode of fracture. The bending and tensile strength decreases in both composites on $1000^{\circ}C$ which attributed to decrease in bulk density, thereafter with increase in HTT, bending and tensile strength increases. The maximum strength is in T700 fiber based composites at HTT $1500^{\circ}C$ and in M40 fiber based composites at HTT $2500^{\circ}C$. After attending the maximum value of strength in both types of composite at deflection HTT, after that strength decreases continuously. Decrease in strength is due to the degradation of fiber properties and in-situ fiber damages in the composite. The maximum carbon fiber strength realization in C/C composites is possible at a temperature that is same of fiber HTT. It has been found first time that the bending strength more or less 1.55 times higher in T700 fiber composites and in M40 fiber composites bending strength is 1.2 times higher than that of tensile strength of C/C composites.

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Optimization of spray drying conditions of soft persimmon and milk mixture using response surface methodology (반응표면분석법을 이용한 홍시와 우유혼합물의 최적 분무건조 조건)

  • Park, Mi-Jeong;Kim, Sang-Bum;Kim, Sook-Jin;Kim, Kyung-Mi;Choi, Song-Yi;Chang, Mi;Kim, Gi-Chang
    • Food Science and Preservation
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    • v.24 no.7
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    • pp.957-964
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    • 2017
  • The purpose of this study was to determine the optimum spray drying conditions of soft persimmon latte using response surface methodology that is a statistical procedure used for optimization studies. A central composite design was applied to investigate the effects of independent variables, inlet temperature ($X_1$), air flow rate ($X_2$), and feed flow rate ($X_3$), on responses such as yield, water absorption index, and total phenolic compounds. Statistical analysis revealed that independent variables significantly affected all the responses. A maximum yield of 8.11 g was obtained at $90^{\circ}C$ of $X_1$, 51.82 mL/min of $X_2$ and 7.00 mL/min of $X_3$. A minimum water absorption index of 0.58 was obtained at $101^{\circ}C$ of $X_1$, 60.00 mL/min of $X_2$ and 17.00 mL/min of $X_3$. A maximum total phenolic compounds of $298.02{\mu}g/mL$ was obtained at $90^{\circ}C$ of $X_1$, 43.33 mL/min of $X_2$ and 17.00 mL/min of $X_3$. In conclusion, the best spray drying conditions were as follows: $X_1$, $90^{\circ}C$; $X_2$, 53 mL/min; $X_3$, 17 mL/min. Under those optimal conditions, the powder's yield (7.46 g), water absorption index (0.54), and the content of total phenolic compounds ($294.75{\mu}g/mL$) were estimated.

A Novel Route to Realise High Degree of Graphitization in Carbon-carbon Composites Derived from Hard Carbons

  • Mathur, R.B.;Bahl, O.P.;Dhami, T.L.;Chauhan, S.K.
    • Carbon letters
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    • v.4 no.3
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    • pp.111-116
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    • 2003
  • Carbon/carbon composites were developed using PAN based carbon fibres and phenolic resin as matrix in different volume fractions and heat treated to temperatures between $1000^{\circ}C$ to $2500^{\circ}C$. Although both the starting precursors are nongraphitizing hard carbons individually, their composites lead to very interesting properties e.g. x-ray diffractograms show the development of graphitic phase for composites having fibre volume fractions of 30~40%. Consequently the electrical resistivity of such composites reaches a value of $0.8\;m{\Omega}cm$, very close to highly graphitic material. However, it was found that by increasing the fibre volume fraction to 50~60%, the trend is reversed. Optical microscopy of the composites also reveals the development of strong columnar type microstructure at the fibre (matrix interface due to stress graphitization of the matrix. The study forcasts a unique possibility of producing high thermal conductivity carbon/carbon composites starting with carbon fibres in the chopped form only.

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Quality Characteristics and Storage Stability of Bread with Allium hookeri Powder (삼채가루 첨가 식빵의 제조조건 최적화 및 저장성 연구)

  • Lee, HeeJeong;Baik, Jae-Eun;Joo, Nami
    • The Korean Journal of Food And Nutrition
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    • v.27 no.2
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    • pp.318-329
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    • 2014
  • The purpose of this study was to determine the optimal mixing ratio of Allium hookeri powder and butter in the preparation of bread. The experiment was designed according to the central composite design for estimating the response surface, which demonstrated 10 experimental points, including 2 replicates for Allium hookeri powder and butter. Further, the mechanical and sensory properties of test materials were measured. A canonical form and perturbation plot conveyed the influence of each ingredient on the final product mixture. Overall, the measurement results of the mechanical properties showed a significant increase or decrease in dough pH, sweetness, volume, weight, height, specific volume, a & b-value of crumb and, springiness (p<0.05). Moreover, the sensory measurements demonstrated a significant improvement in color, appearance, texture, moistness and, overall quality. As a result, the optimum formulation from the numerical and graphical methods was calculated as 22.65 g of Allium hookeri powder and 47.77 g butter. After optimization, DPPH free radical scavenging activity, total phenolic content, and total plate counts over 10 days were evaluated. In sum, the results revealed the antioxidant and antibiotic actions of bread with Allium hookeri powder.