• Title/Summary/Keyword: phase transition behavior

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Effect of GaGe Sputtering Power on Ga Doping in Phase Change Memory Materials (상 변화 메모리 재료 내의 Ga 주입에 미치는 GaGe 스퍼터링 전력의 영향)

  • Jung, Soon-Won;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.5
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    • pp.285-290
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    • 2015
  • The phase change memory material is an active element in phase change memory and exhibits reversible phase transition behavior by thermal energy input. The doping of the phase change memory material with Ga leads to the increase of its crystallization temperature and the improvement of its amorphous stability. In this study, we investigated the effect of GaGe sputtering power on the formation of the phase change memory material including Ga. The deposition rate linearly increased to a maximum of 127 nm and the surface roughness remained uniform as the GaGe sputtering power increased in the range from 0 to 75 W. The Ga concentration in the thin film material abruptly increased at the critical sputtering power of 60 W. This influence of GaGe sputtering power was confirmed to result from a combined sputtering-evaporation process of Ga occurring due to the low melting point of Ga ($29.77^{\circ}C$).

Experimental study on single- and two-phase flow behaviors within porous particle beds

  • Jong Seok Oh;Sang Mo An;Hwan Yeol Kim;Dong Eok Kim
    • Nuclear Engineering and Technology
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    • v.55 no.3
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    • pp.1105-1117
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    • 2023
  • In this study, the pressure drop behavior of single- and two-phase flows of air and water through the porous beds filled with uniform and non-uniform sized spherical particles was examined. The pressure drop data in the single-phase flow experiments for the uniform particle beds agreed well with the original Ergun correlation. The results from the two-phase flow experiments were analyzed using numerical results based on three types of previous models. In the experiments for the uniform particle beds, the data on the two-phase pressure drop clearly showed the effect of the flow regime transition with a variation in the gas flow rate under stagnant liquid condition. The numerical analyses indicated that the predictability of the previous models for the experimental data relied mainly on the sub-models of the flow regime transitions and interfacial drag. In the experiments for the non-uniform particle beds, the two-phase pressure loss could be predicted well with numerical calculations based on the effective particle diameter. However, the previous models failed to accurately predict the counter-current flooding limit observed in the experiments. Finally, we propose a relation of falling liquid velocity into the particle bed by gravity to appropriately simulate the CCFL phenomenon.

Multichannel Quantum-Defect Study of q reversals in Overlapping Resonances in Systems involving 1 Open and 2 Closed Channels

  • Cho, Byung-Hoon;Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.315-326
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    • 2010
  • This study examined the overlapping resonances in the systems involving 1 open and 2 closed channels using the phase-shifted version of multichannel quantum-defect theory (MQDT). The results showed that 21 patterns for the q reversals in the autoionization spectra are possible depending on the relative arrangements of the two simple poles and roots of the quadratic equations. Complete cases could be generated easily using the q zero planes determined using only 3 asymmetric spectral line profile indices. The transition of the spectra of the coarse interloper Rydberg series from the lines into a structured continuum by being dispersed onto the entire Rydberg series was found. The overall behavior of the time delays was found to be governed by the dense Rydberg series, which is quite different from the one of the autoionization cross sections that is governed by an interloper, indicating that different dynamics prevail for them. This is in contrast to the two channel system where both quantities behave similarly. The dynamics obtained in the presence of overlapping resonances is as follows. The absorption process is instant and dominated by a transition to the interloper line. This process is followed by rapid leakage into the dense Rydberg series, which has a longer residence time before ionization than that of the interloper state. This is because the orbiting period is proportional to $\upsilon^3$ so that an excited electron has a shorter lifetime in the interloper state belonging to a lower member of the Rydberg series.

EFFECT Of PYRROLIDONE DERIVATIVES ON MULTILAMELLAR LIPOSOMES OF STRATUM CORNEUM LIPID: A STUDY BY UV SPECTROSCOPY AND DIFFERENTIAL SCANNING CALORIMERY

  • Hong, Myo-Sook;Kim, Chong-Kook
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1996.04a
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    • pp.286-286
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    • 1996
  • In order to elucidate the mechanism of action of transdermal absorption-enhancing compounds, i.e., pyrrolidone derivatives (2-pyrrolidone, 1-methyl-2-pyrrolidone, 1-ethyl-2-pyrrolidone, 1,5-dimethyl-pyrrolidone and 5-methyl-2-pyrrolidone), multilamellar liposome was prepared from the simulated stratum corneum lipid and employed as a model system for the barrier function of the stratum corneum. The liposomal membrane of the stratum corneum lipid liposome (SCLL) behaves as an osmometer and has an excellent barrier function. In addition, its phase transition temperatures are similar to those of human stratum corneum intercellular lipid region. Therefore, SCLL seems to be a useful skin model. To estimate the barrier function of SCLL, the osmotic behavior of SCLL was measured in the presence of pyrrolidone derivatives and the effect on the phase transition temperature of SCLL was also investigated using differential calorimetry. Above a certain concentration (MLAC), enhances perturb the barrier function of the liposome. The relationship between MLACs and the partition coefficient of the pyrrolidone derivatives was observed; the greater the partition coefficients, the smaller the MLAC. This suggests that the more hydrophobic enhancers penetrate into the lipid layer more easily and reduce the barrier function of membrane more effectively. The results of differential scanning thermograms of the SCLL suggest that the pyrrolidone derivatives had incorporated into the lipid layer in the liposome and increased the fluidity of the lipid layer in the liposome. Such activity might have some correlation with the transdermal absorption-enhancing activity these compounds.

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Numerical Analysis of Transitional Flow in a Stenosed Carotid Artery (협착된 경동맥내 천이 유동 수치 해석)

  • Kim, Dongmin;Hwang, Jinyul;Min, Too-Jae;Jo, Won-Min
    • Journal of the Korean Society of Visualization
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    • v.20 no.1
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    • pp.52-63
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    • 2022
  • Direct numerical simulation of blood flow in a stenosed, patient-specific carotid artery was conducted to explore the transient behavior of blood flow with special emphasis on the wall-shear stress distribution over the transition region. We assumed the blood as an incompressible Newtonian fluid, and the vessel was treated as a solid wall. The pulsatile boundary condition was applied at the inlet of the carotid. The Reynolds number is 884 based on the inlet diameter, and the maximum flow rate and the corresponding Womersley number is approximately 5.9. We found the transitional behavior during the acceleration and deceleration phases. In order to quantitatively examine the wall-shear stress distribution over the transition region, the probability density function of the wall-shear stress was computed. It showed that the negative wall-shear stress events frequently occur near peak systole. In addition, the oscillatory shear stress index was used to further analyze the relationship with the negative wall-shear stress appearing in the systolic phase.

The Formation Behavior and Thermal Stability of $E_6$ Eutectic Phase in Unidirectionally Solidified Al-Fe Alloys (일방향 응고시킨 Al-Fe계 합금에서 $E_6$ 공정상의 생성특성과 열적안정성)

  • Jung, Hae-Ryong
    • Journal of Korea Foundry Society
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    • v.19 no.1
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    • pp.71-76
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    • 1999
  • Eutectic and off-eutectic Al-Fe alloys were unidirectionally solidified at the solidification rate of $1{\sim}50\;mm/min$ under the temperature gradients $75{\sim}80^{\circ}C/cm$. The investigation has been carried out for the microstructural variation, phase transition, mechanical properties by means of detailed analyses of stress-strain, micro-Vickers hardness and scanning electron micrography. The thermal stability at elevated temperature has been studied on $Al-Al_6Fe$ eutectic alloy held at $600^{\circ}C$ for $0{\sim}150$ hours. When the solidification rate was less than 10mm/min, the X-ray diffraction and EDS analysis showed the presence of $Al_3Fe$ compound. As the solidification rate more than 20 mm/min, $Al-Al_3Fe$ eutectic phase was transfered into $Al-Al_6Fe$ eutectic phase. The mechanical properties of unidirectionally solidified off-eutectic Al-Fe alloy is better than those of unidirectionally solidified eutecic Al-Fe alloy Maximum ultimate tensile strength was obtained in Al-2.25% Fe alloy which was unidirectionally solidified at the solidification rate of 20 mm/min. The metastable $Al-Al_6Fe$ phase was transferred into stable $Al-Al_3Fe$ phase at $600^{\circ}C$ held for 150 hours.

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Phase Transitional Behavior and Piezoelectric Properties of 0.94(Na0.5K0.5NbO3-0.06Ba(Ti0.9Sn0.1)O3 Lead-free Ceramics (무연계 0.94(Na0.5K0.5NbO3-0.06Ba(Ti0.9Sn0.1)O3 세라믹의 상전이 거동과 압전 특성)

  • Cha, Yu-Joung;Nahm, Sahn;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.9
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    • pp.766-771
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    • 2009
  • Lead-free $0.94(Na_{0.5}K_{0.5})NbO_3$-0.06Ba$(Ti_{0.9}Sn_{0.1})O_3$ [0.94NKN-0.06BTS] ceramics doped with 1 mol% $MnO_2$ were synthesized by a conventional solid state method. The phase transitional behavior and piezoelectric properties of the ceramics sintered at various temperatures were investigated. The 0.94NKN-0.06BTS ceramics sintered at $1050^{\circ}C$, having morphotropic phase boundary of orthorhombic and tetragonal phases, exhibited a microstructure with abnormal grain growth. A diffused phase transition behavior for all the specimens was verified as high degree of diffuseness (${\gamma}$) values from 1.45 to 1.79. A high piezoelectric constant of $d_{33}=256$ pC/N and a satisfactory electromechanical coupling factor of $k_p=42%$ were obtained for the relatively dense 0.94NKN-0.06BTS ceramics sintered at $1050^{\circ}C$.

Effect of phase transformations on buckling behavior of subducting slab and tectonic implication (상전이가 섭입 슬랩의 좌굴에 미치는 영향과 지체구조적 암시)

  • Lee, Changyeol
    • Journal of the Geological Society of Korea
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    • v.54 no.6
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    • pp.657-675
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    • 2018
  • The apparent thickening of the subducting slab in the shallow lower mantle has been attributed to slab buckling. However, the scaling laws have not been quantitatively evaluated for the buckling behavior of the subducting slab when phase transformations are considered. Thus, two-dimensional dynamic subduction experiments are formulated to evaluate the effect of phase transformations on the buckling behavior of the subducting slab. The model calculations show that the phase transformation from olivine to wadsleyite at a depth of 410 km plays an important role in the development of slab buckling; increased slab pull due to the endothermic phase transformation accelerates slab sinking in the upper mantle and the subducting slab reaches the lower mantle in a shorter time than that of the experiments without the phase transformation. However, the phase transformation from ringwoodite to perovskite plus $magnesiow{\ddot{u}}stite$ at a depth of 660 km retards slab sinking into the lower mantle and the subducting slab tends to be accumulated in the transformation (transition) zone. Buckling analyses show that the scaling laws predict the buckling amplitude and period of the subducting slab with small relative errors even if the phase transformations are considered. The universal phenomenon of the slab buckling can explain apparent slab thickening in the shallow lower mantle and transformation zone under the subduction zones such as Java-Sunda and Northeast Japan. In addition, the buckling behavior of the subducting slab may be related to the periodic compressions and extensions in the Cretaceous Gyeongsang basin.

A Modeling about Penetration Behavior of Diesel Engine Liquid Fuel Spray (디젤기관의 분무선단 도달거리에 관한 모델링)

  • 안수길;배종욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.1
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    • pp.140-152
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    • 1989
  • The study on the penetration of sprays during the initial phase of injection period, i.e. ignition delay period, in high speed small D.I. diesel engines are strongly affected by such behavior. To investigate the penetration of the sprays injected through single cylinderical orifice, a mathematical model was developed and compared with experimental results. In this model, radial heterogeneity of fuel density in the spray, transiency of injection pressure difference, and spray outrunning phenomenon were considered simultaneously. Experiments on the behaviors of sprays in the high pressure air chamber were conducted at various injection pressure differences and different levels of back air pressure. The behaviors of sprays injected into the chamber through the conventional Bosch injection pump were visualized with side stroboscopic illumination. Comparison of the experimental results with predictions from the mathematical model confirmed the validity of the model. It was also found that during the initial phase of the injection period the penetration of sprays vs. time appeared to have two transition points; one corresponded to disintegration point of liquid fuel jet, the other to the beginning of steady state injection.