• Title/Summary/Keyword: permeation characteristics

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Gas Permeation Characteristics of PVC/PS Blend Laminated Membranes Prepared by Water Casting (PVC/PS 혼합 수면 전개 적층막의 기체투과 특성)

  • 남석태;최호상;김병식
    • Membrane Journal
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    • v.3 no.3
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    • pp.108-116
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    • 1993
  • In PVC/PS pelyblend laminated membranes, perrneabilities were increased as increasing the blend ratio of PS and selectivities were increased with increasing the blend ratio of PVC. The gas permeation mechanism was shifted from the combination of Poiseuille and Knudsen flow model to the solution-diffusion model as decreasing the PS blend ratio. The structure of polyblend laminated membranes showed series model, where PS rich phase was formed at air side and PVC rich phase was at water side. The model of permeation in the polyblend laminated membranes also showed series model structure.

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Preparation of Cellulose Acetate Containing Silver Nitrate as Oxygen Carrier (질산은을 산소 캐리어로 하는 CA막의 제조)

  • Ahn, Pil-Seong;Lee, Woo-Tai
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.83-90
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    • 1999
  • A cellulose acetate membrane containing silver nitrate was prepared by gelatinizing in water at $2^{\circ}C$ after evaporating solvent from the casting solution on a glass plate. Permeation experiments for oxygen and nitrogen were conducted in the ranges of temperature, $5-40^{\circ}C$ and pressure difference, $1-5kg/cm^2$ in order to investigate the effects of temperature and pressure difference on permeation characteristics of the membrane. When the evaporation time was increased, the permeability of oxygen decreased but the separation factor of oxygen against nitrogen increased since a more dense layer was formed on the membrane surface. When the silver nitrate was added, the permeation flux was doubled and the separation factor was improved from 3.0 to 3.3. This implies that silver nitrate acts as an oxygen carrier in the membrane.

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Pervaporation Separation of Trace VOCs from Water Through PDMS Membranes

  • Rhim, Ji-Won;Kwon, Young-Mann
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.73-80
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    • 1999
  • The removal of trace chlorinated and aromatic hydrocarbons from water by a pervaporation technique has been carried out through poly (dimethylsiloxane) membrane which had been fabricated by the addition crosslinking reaction. This study dealt with the swelling and permeation behaviors of the PDMS membranes with dichloroethane trichloroethane and toluene aqueous solutions. The swelling ratio in the toluene aqueous solution was much higher than those in the chloroethane solutions at all of the operating temperatures and concentrations. The solubility parameter theory was introduced to interpret the affinity between permeates and a membrane material and in all cases this approach seemed to be proper. It was suggested that the existence of water clusters in the membrane due to the hydrophobic characteristics of the membrane made the size of the permeating water larger resulting in suppressing water permeation and increasing enrichment of the organic components. The permeation behaviors at different membrane thicknesses were indirectly interpreted in terms of the effect of concentration polarization.

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Estimation of the Anisotropic Material Properties of Rock Masses with Permeation Grouting (그라우팅 강화터널의 설계 특성치 산정에 관한 연구)

  • Lee, Jun Seok;Bang, Chun Seok;Choe, Il Yun;Eom, Ju Hwan
    • Magazine of korean Tunnelling and Underground Space Association
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    • v.1 no.1
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    • pp.67-80
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    • 1999
  • The Grout-reinforcement technique which is widely used during the excavation of a shallow or an endangered tunnel can be classified into a couple of groups according to the properties and injection methods of the grout. The reinforcement design will, therefore, take a different approach based on the grouting method under consideration. However, the injection procedure is mainly performed by the experience of the foreman rather than engineering judgement , specifically the permeation grouting through the rock joints and its reinforcement effect Is not fully under-stood during the design stage, In this study, the anisotropic material properties of the grout-reinforced rock masses are derived from the concept of composite materials and the effect of intact rock, vertical grouting and permeation grouting is, therefore, fully accounted for. Through the parametric studies on the characteristics of rock joints, intact rock and grouting materials, various case studies have been considered. The results, illustrated via the design charts, can be directly used during the reinforcement design.

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Ex Vivo Permeability Characteristics of Porcine Buccal Mucosa to Drugs with Various Polarity

  • Lee, Jae-Hwi;Lee, Yoon-Jin;Yoon, Mi-Kyeong;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.35 no.2
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    • pp.71-74
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    • 2005
  • The aim of this study was to analyze characteristics of the barrier function of excised porcine buccal mucosa to the test compounds, estradiol, propranolol HCI, melatonin, and mannitol with a wide range of partition coefficient values. The permeability of melatonin was measured through frozen, stored, and fresh porcine buccal mucosa to examine the impact of storage conditions on the permeability of porcine buccal mucosa. The results demonstrated that the ex vivo permeability of the porcine buccal mucosa was greater for more lipophilic solutes, which was consistent with a series of molecules transported by passive transepithelial diffusion. The melatonin permeation profiles through frozen, stored, and fresh mucosa illustrated that damage was incurred by the freezing process of the mucosal tissue, leading to loss of the barrier function and thereby an increased permeation coefficient. It can be observed that the influence of compound lipophilicity on the association of the compounds with buccal mucosa was clear. The relationship between permeation coefficient and Log P values for the four compounds investigated demonstrated a proportional relationship, further confirming the importance of the lipophilicity of a compound to permeate the buccal mucosa. These results showed that the ex vivo porcine buccal mucosa model is a suitable tool to screen oral mucosal permeability.

Effect of Vibration on Grout Permeation Characteristics (진동주입이 그라우트재의 침투 특성에 미치는 영향 연구)

  • Lee, Mun-Seon;Kim, Jong-Sun;Lee, Sung-Dong;Choi, Young-Joon;Yang, Jae-Man;Lee, In-Mo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.267-278
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    • 2010
  • To improve the grout penetration characteristics, vibration method was adopted in this study. The grout material perturbed by cyclic vibration is injected into the ground. By applying the vibrating flow system, cement particles will become less adhesive and the clogging tendency will be decreased. A series of pilot-scale chamber tests were performed to verify the enhancement of the groutability by applying the vibratory grout injection; assessment on change of the lumped parameter $\theta$ which represents a barometer of clogging phenomenon was made. Moreover, the effect of vibratory grout injection through the joint was also investigated using artificially made rock joints. Experimental results as well as analytical results show that the grout penetration depth can be substantially improved by vibration grouting. Moreover, it was found that enhancement of the permeation grouting due to vibratory injection is more dominant at low grouting pressure of less than 400kPa.

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Permeation Characteristics of Air and Water Vapor through ABS/filler Hybrid Films (ABS 복합 필름의 공기 및 수증기 투과 특성)

  • Hong, Seong-Uk;Ko, Young-Deok
    • Membrane Journal
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    • v.18 no.3
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    • pp.256-259
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    • 2008
  • In this study, graphite or zeolite 4A was mixed with poly(acrylonitrile-butadiene-strene) (ABS) to make hybrid films, and permeation characteristics of air and water vapor through these films were investigated. In all cases, gas permeabilities of hybrid films were lower than that of pure ABS films. The permeability decrease of oxygen was slightly larger than that of nitrogen, resulting in the little decrease of $O_2/N_2$ selectivity. In addition, the water vapor transfer rates (WVTR) of hybrid films were about half of ABS film's. The decrease of permeabilities may be owing to the increase of tortuosity for diffusion in hybrid films.

Near surface characteristics of concrete: prediction of freeze/thaw resistance

  • Chan, Sammy Yin Nin;Dhir, Ravindra K.;Hewlett, Peter C.;Chang, Da Yong
    • Structural Engineering and Mechanics
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    • v.2 no.4
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    • pp.403-412
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    • 1994
  • The durability of concrete is related to the permeation characteristics of its near surface. An attempt was made to use the permeation characteristics namely, absorptivity, permeability and diffusivity, to predict the freeze/thaw resistance of concrete. Test results indicate that in general, there was a trend that freeze/thaw resistance of concrete was enhanced with improved absorptivity and diffusivity whilst the freeze/thaw resistance of normal concrete was found to have the best relationship with its intrinsic permeability. The latter method is therefore proposed to be adopted to predict freeze/thaw resistance of normal concrete. Since Figg air test is an inexpensive and simple test method that measures indirectly the intrinsic permeability of concrete, it is further proposed that it could be used as a quality control tool to assess, non-destructively, the freeze/thaw durability potential of in-situ concrete.

Rejection Characteristics of Various Heavy Metals by Low-pressure Nanofiltration (저압나노여과에 의한 각종 중금속의 제거 특성)

  • Oh, Jeong-Ik;Kim, Han-Seung;Kim, Chung-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.493-499
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    • 2004
  • Rejection characteristics of heavy metals by nanofiltration membranes were investigated. Nanofiltration membranes rejected heavy metals much better than chloride, sulfate and TOC, of which concentration in synthetic wastewater was higher than that of heavy metals. To consider rejection characteristics of various metals by nanofiltration membranes, separation coefficient, which is the ratio of the metal permeation rate to the chloride ion or TOC permeation rate, was introduced. In spite of different materials and different nominal salt rejection of nanofiltration membrane used, the separation coefficients of metals were nearly the same. In particular, the separation coefficient of arsenic against chloride ion and TOC was larger than any other separation coefficient of heavy metals. These phenomena were observed in the relationship between the molar conductivity and the separation coefficient for heavy metals.