• 제목/요약/키워드: permeability-controlled

검색결과 155건 처리시간 0.023초

Nafion-Sulfonated Poly(arylene ether sulfone) Composite Membrane for Direct Methanol Fuel Cell

  • Choi Jisu;Kim II Tae;Kim Sung Chul;Hong Young Taik
    • Macromolecular Research
    • /
    • 제13권6호
    • /
    • pp.514-520
    • /
    • 2005
  • Composite membranes of Nafion and sulfonated poly(arylene ether sulfone) were prepared. Sulfonated poly(arylene ether sulfone)s with different degrees of sulfonation were blended with Nafion to reduce the methanol crossover. The morphology, proton conductivity and methanol permeability of the resulting composite membranes were investigated by SEM, EDAX, AC impedance spectroscopy and permeability measuring instrument. The cross­sections of the composite membranes showed a phase separated morphology. The morphology and phase separation mechanism could be controlled by varying the blend ratio and the degree of sulfonation of poly(arylene ether sulfone). These complex morphologies can be applied for reducing methanol crossover. The methanol permeability and proton conductivity of the composite membranes were lower than those of Nafion 117 membrane since the development of an ionic pathway in the blend membrane was more difficult than that in Nafion itself.

Laboratory experiments on the improvement of rockfill materials with composite grout

  • Wang, Tao;Liu, Sihong;Lu, Yang
    • Geomechanics and Engineering
    • /
    • 제17권3호
    • /
    • pp.307-316
    • /
    • 2019
  • Dam deformation should be strictly controlled for the construction of 300 m-high rockfill dams, so the rockfill materials need to have low porosity. A method of using composite grout is proposed to reduce the porosity of rockfill materials for the construction of high rockfill dams. The composite grout is a mixture of fly ash, cement and sand with the properties of easy flow and post-hardening. During the process of rolling compaction, the grout admixture sprinkled on the rockfill surface will gradually infiltrate into the inter-granular voids of rockfill by the exciting force of vibratory roller to reduce the porosity of rockfill. A visible flowing test was firstly designed to explore the flow characteristics of composite grout in porous media. Then, the compressibility, shear strength, permeability and suffusion susceptibility properties of composite grout-modified rockfill are studied by a series of laboratory tests. Experimental results show that the flow characteristics of composite grout are closely related to the fly ash content, the water-to-binder ratio, the maximum sand size and the content of composite grout. The filling of composite grout can effectively reduce the porosity of rockfill materials, as well as increase the compression modulus of rockfill materials, especially for loose and gap-graded rockfill materials. Composite grout-modified rockfill tends to have greater shear strength, larger suffusion erosion resistance, and smaller permeability coefficient. The composite grout mainly plays the roles of filling, lubrication and cementation in rockfill materials.

Purification During Crossflow Electromicrofiltration of Fermentation Broth

  • Park Young G.
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제9권6호
    • /
    • pp.500-505
    • /
    • 2004
  • The present study was to investigate the purification of a fermentation broth by an electromicrofiltration membrane. Microfiltration runs with a crude and a centrifuged broth, with solution of particles recovered from centrifugation and with permeates from microfiltration experiments were thus compared. Microfiltration performances were governed by colloids and small particles that induced sharp initial flux declines. For these results, the evolution of the overall membrane resistance was increased by $80\%$ in comparison with the electromicrofiltration membrane. The main focus of this study was set on the enhancement of the filtrate flux by an electric field. This pressure electrofiltration leads to a drastic improvement of the filtration by $100\%$ and the filtration time was thereby reduced. Pressure electrofiltration serves as an inter­esting alternative to the cross-flow filtration and it effectively separates advantageous constitu­ents such as amino acids and biopolymers from a fermentation broth. They were equally main­tained during the microelectrofiltration, although they were significantly reduced by $45\%$ by the microfiltration without the application of an electric field. Accordingly, since the electrofiltration membrane was provided more permeability, this study experimentally demonstrates that the permeability inside a membrane can be controlled using an electric field.

용탕인출법으로 제조한 퍼말로이 박판의 Si 함량 및 열처리가 미세조직에 미치는 영향 (The effects of Si addition and annealing temperature on microstructure of permalloy fabricated by melt drag casting)

  • 임경묵;남궁정;강주석;김문철;박찬경
    • 한국소성가공학회:학술대회논문집
    • /
    • 한국소성가공학회 2004년도 춘계학술대회 논문집
    • /
    • pp.166-169
    • /
    • 2004
  • Permalloys were successfully fabricated by melt drag casting in the present study, and their variation of microstructure and consequent magnetic properties were investigated as a function of Si contents and annealing temperature. The increases in Si content and annealing temperature resulted in the increases of grain size and amount of $FeNi_3$ ordered phase. Both the grain size and $FeNi_3$ ordered phase controlled by Si and annealing temperature had a important role on permeability of permalloys.

  • PDF

RF Power Absorption Enhancement of Magnetic Composites with Conductive Grid

  • Nam, Baek-Il;Kim, Jin-U;Kim, Ki-Hyeon
    • Journal of Magnetics
    • /
    • 제17권2호
    • /
    • pp.129-132
    • /
    • 2012
  • To evaluate the electromagnetic power absorption in near field, the magnetic composites with the conductive grids were simulated using the typical permeability frequency profiles. The transmission power absorptions of the magnetic composites on microstrip line were extracted by the 3D FEM simulation program of HFSS. The magnitudes of power absorptions were greatly enhanced up to 98% and broadened the absorbing frequency band over 5 GHz by the insertion of a conductive grid in magnetic composite. The initial frequency of the power absorption can controlled by the change of the ferromagnetic resonance frequencies of the magnetic composite.

탈질 조건에서 투과매질 내 미생물 성장에 관한 연구

  • 최영화;오재일;배범한
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2002년도 추계학술발표회
    • /
    • pp.366-369
    • /
    • 2002
  • Subsurface biobarrier technology has potential applications to contain contaminated groundwater and/or to degrade toxic pollutants in groundwater. Most biobarrier studies were conducted under aerobic condition, however there were several obstacles to make aerobic condition. Thus, In this study, we examined biobarrier formation under denitrifying condition by using nitrate as an electron acceptor. Experiments were performed with a sand column inoculated with activated sludge from the nearby WWTP. The substrate medium was pumped to the sand column in an upflow mode. During the low substrate loading rate period, the extent of reduction rate in hydraulic conductivity was found similar throughout the column, and permeability became relatively stable after couple of days. However, during the high substrate loading rate period, the column demonstrated a gradient of permeability reduction, with the greatest reduction in sections nearest the column inlet. Rapid growth of microorganisms near the column inlet resulted in the unbalanced reduction of hydraulic conductivity throughout the sand column. As a result, at this denitrifying condition the thickness of biobarrier could be controlled by adjusting the medium conditions of microbial growth.

  • PDF

용탕인출법으로 제조한 퍼말로이 박판의 미세구조와 자기적 특성의 상관관계 (The Relationship between Microstructure and Magnetic Properties of Permalloys Fabricated by Melt Drag Casting)

  • 박성용;임경묵;남궁정;김문철;박찬경
    • 한국소성가공학회:학술대회논문집
    • /
    • 한국소성가공학회 2005년도 춘계학술대회 논문집
    • /
    • pp.475-478
    • /
    • 2005
  • Permalloys were successfully fabricated by melt drag casting in the present study, and their variation of microstructure and consequent magnetic properties were investigated as a function of Si contents and annealing temperature. The increases in Si content and annealing temperature resulted in the increases of grain size and amount of $Ni_3Fe$ ordered phase. Both the grain size and $Ni_3Fe$ ordered phase controlled by Si and annealing temperature had a important role on permeability of permalloys.

  • PDF

투과도 조절 폴리에틸렌 필름의 절임배추 보존기간 연장효과 (Effect of Permeability-Controlled Polyethylene Film on Extension of Shelf-life of Brined Baechu Cabbage)

  • 김영욱;정지강;이선미;강순아;이동선;김소희;박건영
    • 한국식품영양과학회지
    • /
    • 제38권12호
    • /
    • pp.1767-1772
    • /
    • 2009
  • 절임배추를 각각 다른 5종류의 필름에 sealing 한 다음 4주간 4${^{\circ}C}$로 저장하면서 품질 특성을 평가하였다. 기체투과도 조절 필름인 MF필름(US patent No. 5972815)으로 포장한 절임배추의 경우에는 미생물의 성장수가 가장 적었고 HDPE필름으로 포장한 절임배추의 경우가 미생물수가 가장 많았다. MF필름으로 포장한 절임배추의 경우 다른 필름으로 포장한 절임배추보다 pH가 천천히 감소하였고 산도의 경우에는 모든 필름에서 포장한 절임배추에서 4주 동안 점점 증가하지만 MF필름으로 포장한 절임배추의 산도가 가장 낮았다. MF필름으로 포장한 절임배추의 경우 탄력성의 감소율이 가장 낮았고 HDPE필름으로 포장한 절임배추의 경우에 탄력성의 감소율이 가장 높았다. MF필름에 절임배추를 포장한 경우 포장 필름의 투과성과 절임배추의 호흡에 의해 4${^{\circ}C}$에서 1주 후 필름 안에 $O_2$ 조성이 0.66%로 나타났는데, 이러한 필름 안의 $O_2$ 조성 결과와 미생물수, pH, 산도의 결과를 비교해보면 포장필름 안에 $O_2$ 조성이 1%에 가까울 때 절임배추의 품질특성이 가장 우수하게 유지되었다. 본 연구 결과로 절임배추의 저장성 증진과 품질특성의 유지를 위한 필름으로 MF필름이 가장 적합하였다. 그리고 LDPE필름 역시 MF필름보다는 저장성 증진과 품질특성 유지 면에서 성능은 떨어졌지만 가격 면이나 대중적인 면에서 고려해 보았을 때 LDPE필름의 사용도 가능하다고 하겠다.

가교도가 조절된 세공충진 이온교환막의 제조 및 전기화학적 응용: Part I. 전 바나듐 레독스 흐름전지 (Preparation and Electrochemical Applications of Pore-filled Ion-exchange Membranes with Well-adjusted Cross-linking Degrees: Part I. All Vanadium Redox Flow Battery)

  • 이지은;박예린;김도형;강문성
    • 멤브레인
    • /
    • 제27권5호
    • /
    • pp.406-414
    • /
    • 2017
  • 본 연구에서는 얇은 폴리에틸렌 계 다공성 필름(두께 = $25{\mu}m$)에 이오노머를 충진시킨 세공충진 이온교환막을 개발하였으며 이를 적용한 전 바나듐 레독스 흐름전지의 충방전 특성을 고찰하였다. 특히 분자 크기가 다른 가교제를 혼합함으로써 이온교환막의 가교도 및 자유체적을 적절히 제어하여 저저항 및 저 바나듐 투과도를 나타내는 이온교환막을 제조하고자 하였다. 실험 결과, 제조된 세공충진 이온교환막은 상용막 대비하여 동등 수준의 우수한 전기화학적 특성을 나타내었다. 또한 바나듐 이온 투과도 및 전 바나듐 레독스 흐름전지 성능 평가 실험을 통해 얇은 막 두께에도 불구하고 상용막 대비하여 낮은 바나듐 이온 투과도와 높은 충방전 효율을 나타냄을 확인하였다.

The Effect of Glasthma Syrup in Asthma: a study protocol for a triple-blind randomized controlled trial

  • Derakhshan, Ali Reza;Saeidinejat, Shahin;Khadem-Rezaiyan, Majid;Asnaashari, Amir-Mohammad-Hashem;Mirsadraee, Majid;Salari, Roshanak;Jabbari-Azad, Farahzad;Jalali, Shima;Jalali, Shabnam
    • 대한약침학회지
    • /
    • 제25권3호
    • /
    • pp.233-241
    • /
    • 2022
  • Objectives: Asthma is a chronic disease, and the demand for herbal medicines in this field has increased in recent years. The new findings highlight the role of the gut-lung axis in the pathophysiology of asthma. Hence, this study will evaluate the safety and efficacy of Glasthma syrup, an herbal formula based on Persian medicine, in improving asthma and regulating intestinal permeability. The formula consists of five herbal ingredients that have anti-inflammatory effects on the respiratory tract, also known as gut tonics. Methods: The study will be conducted as a placebo-controlled, triple-blind, randomized trial. It will consist of a 4-week intervention followed by a 4-week follow-up period. The target sample size is 20 patients with moderate asthma aged 18 to 60 years. Eligible participants will be randomly assigned to either the experimental group or the control group in equal numbers. Patients in the experimental group will take Glasthma syrup (7.5 mL, twice a day), while patients in the control group will take a matching placebo. Both groups will receive a 4-week combination of a long-acting beta2 agonist and a leukotriene modulator as standard of care. Inhaled corticosteroids can be used as rescue medication as needed. Results: The primary outcomes are asthma symptom scale, lung function, and intestinal permeability. Secondary outcomes include quality of life, symptom recurrence rates, and blood tests. A safety assessment will also be conducted during the trial. Conclusion: In this trial, the effects of Glasthma syrup in patients with moderate asthma will be examined. The study will also assess the effects of the formulation on the gut-lung axis by simultaneously monitoring the gut permeability index, asthma symptoms, and lung function.