• Journal of the Institute of Electronics Engineers of Korea TE
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• v.37 no.1
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• pp.63-69
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• 2000

The high-$T_c$ Superconducting (HTS) antenna which consists of "H" type resonator has the benefits for the miniaturization of antenna in comparison with the microstrip antenna of the similar dimension. To fabricate the "H" type antenna, HTS $YBa_2Cu_3O_{7-x}$ (YBCO) thin films were deposited on MgO substrates using rf-magnetron sputtering. Standard etching processes were performed for the patterning of the "H" type antenna. For comparison between normal conducting antennas and superconducting antennas, the gold antennas with the same dimension were also fabricated. An aperture coupling was used for impedance matching between $50{\Omega}$ feed line and HTS radiating patch. The diverse experimental results were reported in terms of the resonant frequency, the return loss and the characteristics impedance. The "H" type superconducting antenna showed the performance of 1.36 in SWR, 24% in efficiency, and 14.6 dB in the return loss superior of the normal conducting counterpart.

• Bulletin of the Korean Chemical Society
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• v.34 no.8
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• pp.2461-2465
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• 2013

Pd-$Ce/{\gamma}-Al_2O_3-TiO_2$ catalysts were prepared by combined sol-gel and impregnation methods. Transmission electron microscopy, X-ray diffraction, $H_2$-temperature-programmed reduction, $O_2$-temperature-programmed desorption, and ethanol oxidation experiments were conducted to determine the properties of the catalysts. Addition of an optimal amount of Ce improved the performance of the $Pd/{\gamma}-Al_2O_3-TiO_2$ catalyst in promoting the complete oxidation of ethanol. The catalyst with 1% Ce exhibited the highest activity, and catalyzed complete oxidation of ethanol at $175^{\circ}C$; its selectivity to $CO_2$ reached 87%. Characterization results show that addition of appropriate amount of Ce could enrich the PdO species, and weaken the Pd-O bonds, thus enhancing oxidation ability of the catalyst. Meanwhile, the introduction of $CeO_2$ could make PdO better dispersed on ${\gamma}-Al_2O_3-TiO_2$, which is beneficial for the improvement of the catalytic oxidation activity.

• Bulletin of the Korean Chemical Society
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• v.34 no.8
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• pp.2408-2412
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• 2013

We demonstrate herein the synthesis and modification of magnetic nanoparticles and its use in the immobilization of the lipase. Magnetic $Fe_3O_4$ nanoparticles (MNPs) were prepared by simple co-precipitation method in aqueous medium and then subsequently modified with tetraethyl orthosilicate (TEOS) and 3-aminopropyl triethylenesilane (APTES). Silanization magnetic nanoparticles (SMNP) and amino magnetic nanomicrosphere (AMNP) were synthesized successfully. The morphology, structure, magnetic property and chemical composition of the synthetic MNP and its derivatives were characterized using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) analysis, X-ray diffraction, superconducting quantum interference device (SQUID) and thermogravimetric analyses (TGA). All of these three nanoparticles exhibited good crystallization performance, apparent superparamagnetism, and the saturation magnetization of MNP, SMNP, AMNP were 47.9 emu/g, 33.0 emu/g and 19.5 emu/g, respectively. The amino content was 5.66%. The AMNP was used to immobilize lipase, and the maximum adsorption capacity of the protein was 26.3 mg/g. The maximum maintained activity (88 percent) was achieved while the amount of immobilized lipase was 23.7 mg $g^{-1}$. Immobilization of enzyme on the magnetic nanoparticles can facilitate the isolation of reaction products from reaction mixture and thus lowers the cost of enzyme application.

• Journal of Radiation Protection and Research
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• v.31 no.3
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• pp.123-128
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• 2006

A small radiation detection system is necessary for the direct characterization of alpha/beta-ray contamination inside pipes generated during the decommission of a nuclear facility. In this work, the new type phoswich detector consisting of the ZnS(Ag) and plastic scintillator for ${\alpha}/{\beta}$ simultaneous counting was designed as part of a development of a equipment capable of monitoring radiological contamination inside pipes. The optimum counting conditions in dimensions of scintillator and a detection system were experimentally confirmed and a performance of alpha/beta-ray discrimination was evaluated. As a result, optimum conditions of a detector suitable for monitoring radiological contamination inside pipes and a feasibility of application to pipe-inside were confirmed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.547-553
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• 2017

Thermal analysis of three energetic materials used in pyroelectric device was performed using Differential Scanning Calorimetry (DSC). The theoretical method for extracting the reaction rate equation of energetic materials using DSC experimental data is proposed and the reaction rate extraction is performed. The results of the DSC were analyzed by the conversion method such as Friedman. Activation energy and frequency factor according to mass fraction were extracted to complete the reaction rate equation. The extracted reaction rate equation has a form that represents the entire chemical reaction process, not the assumption that the chemical reaction process of the high energy material is a main step in several stages. It has considerable advantages in terms of theoretical and accuracy as compared with the chemical reaction rate form extracted through conventional thermal analysis experiments. Using the derived reaction rate equation, we predicted the performance change of three energetic materials operating on actual storage condition over 20 years.

• Earthquakes and Structures
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• v.8 no.4
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• pp.859-887
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• 2015

Structural health monitoring (SHM) has gained in popularity in recent years since it can assess the performance and condition of instrumented structures in real time and provide valuable information to the asset's manager and owner. Operational modal analysis plays an important role in SHM and it involves the determination of natural frequencies, damping ratios and mode shapes of a constructed structure based on measured dynamic data. This paper presents the operational modal analysis and seismic response characterization of the Tsing Ma Suspension Bridge of 2,160 m long subjected to different earthquake events. Three kinds of events, i.e., short-distance, middle-distance and long-distance earthquakes are taken into account. A fast Bayesian modal identification method is used to carry out the operational modal analysis. The modal properties of the bridge are identified and compared by use of the field monitoring data acquired before and after the earthquake for each type of the events. Research emphasis is given on identifying the predominant modes of the seismic responses in the deck during short-distance, middle-distance and long-distance earthquakes, respectively, and characterizing the response pattern of various structural portions (deck, towers, main cables, etc.) under different types of earthquakes. Since the bridge is over 2,000 m long, the seismic wave would arrive at the tower/anchorage basements of the two side spans at different time instants. The behaviors of structural dynamic responses on the Tsing Yi side span and on the Ma Wan side span under each type of the earthquake events are compared. The results obtained from this study would be beneficial to the seismic design of future long-span bridges to be built around Hong Kong (e.g., the Hong Kong-Zhuhai-Macau Bridge).

• Korean Journal of Materials Research
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• v.24 no.1
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• pp.6-12
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• 2014

In the present work, $WO_3$ and $WO_3-TiO_2$ were prepared by the chemical deposition method. Structural variations, surface state and elemental compositions were investigated for preparation of $WO_3-TiO_2$ sonocatalyst. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and transmission electron microscopy (TEM) were employed for characterization of these new photocatalysts. A rhodamine B (Rh.B) solution under ultrasonic irradiation was used to determine the catalytic activity. Excellent catalytic degradation of an Rh.B solution was observed using the $WO_3-TiO_2$ composites under ultrasonic irradiation. Sonocatalytic degradation is a novel technology of treating wastewater. During the ultrasonic treatment of aqueous solutions sonoluminescence, cavitaties and "hot spot" occurred, leading to the dissociation of water molecules. In case of a $WO_3$ coupled system, a semiconductor coupled with two components has a beneficial role in improving charge separation and enhancing $TiO_2$ response to ultrasonic radiations. In case of the addition of $WO_3$ as new matter, the excited electrons from the $WO_3$ particles are quickly transferred to $TiO_2$ particle, as the conduction band of $WO_3$ is 0.74 eV which is -0.5 eV more than that of $TiO_2$. This transfer of charge should enhance the oxidation of the adsorbed organic substrate. The result shows that the photocatalytic performance of $TiO_2$ nanoparticles was improved by loading $WO_3$.

• Journal of Wetlands Research
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• v.11 no.2
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• pp.55-66
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• 2009

The increase of pollutant loadings from nonpoint sources affect the water quality of the major rivers in Korea. Consequently, the need for managing the nonpoint source (NPS) pollution becomes the main concern of the Korean Ministry of Environment (MOE). Recently, the policy was changed from pollutant concentration-restricting approach to the total maximum daily load (TMDL) approach to improve the water quality and protect the aquatic ecosystem. Part of the program is the construction of Best Management Practice (BMP) pilot facilities basically to control NPS. Most of the BMPs adopted were foreign technologies which could not be properly employed in the country due to some limitations such as climate, watershed characteristics, etc. In other words, to be able to apply the BMPs, research on its applicability is necessary. In this study, a three-year monitoring has been conducted to assess the treatment performance of the BMP installed in highway toll plaza and parking lot. The data gathered aid in the characterization of NPS pollutants in runoff and estimation of the pollutant removal efficiency of the BMP. The results will be used for the future implementation of BMP in different land uses as well as for the determination of optimum operation and maintenance.

• Food Science and Biotechnology
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• v.16 no.1
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• pp.127-132
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• 2007

[ ${\alpha},\;{\alpha}$ ]-Trehalose was efficiently modified by a transgalactosylation reaction of Escherichia coli ${\beta}-galactosidase$ using lactose as a donor to yield two galactosyl trehalose trisaccharides. The reaction products of trehalose by the enzyme were observed by thin layer chromatography (TLC) and high performance anion exchange chromatography (HPAEC) and were purified by BioGel P2 gel permeation chromatography and recycling preparative HPLC. Liquid chromatography-mass spectrometry (LC-MS) and ^{13}C$ nuclear magnetic resonance (NMR) analyses revealed that the structures of the main products were $6^2-{\beta}-D-galactosyl$ trehalose (1) and $4^2-{\beta}-D-galactosyl$ trehalose (2). A reaction of 30%(w/v) trehalose and 15%(w/v) lactose at pH 7.5 and $45^{\circ}C$ resulted in a total yield of approximately 27-30% based on the amount of trehalose used. The galactosyl trehalose products were not hydrolyzed by trehalose. In addition the mixture of transfer products (9:1 ratio of 1 to 2) showed higher thermal stability than glucose, lactose, and maltose, but less than trehalose, against heat treatment over $100^{\circ}C$ at pH 4 and 7. It also exhibited better thermal stability than sucrose at pH 4 alone.

• Journal of Hydrogen and New Energy
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• v.25 no.4
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• pp.436-442
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• 2014

$LaCoO_3$ powders synthesized by Pechini process were pulverized by planetary ball-milling to decrease particle size and characterized as a catalyst in alkaline solution for oxygen reduction and evolution reaction (ORR & OER). The changes of physical properties, such as particle size distribution, surface area and electric conductivity, were analyzed as a function of ball-milling time. Also, the variations of the crystal structure and surface morphology of ball-milled powders were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The electrochemically catalytic activities of the intrinsic $LaCoO_3$ powders decreased with increasing ball-milling time, but their electrochemical performance as an electrode improved by the increase of the surface area of the powder.