• Title/Summary/Keyword: performance characterization

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Preparation and characterization of TiO2 anti-reflective layer for textured Si (100)

  • Choe, Jin-U;Nam, Sang-Hun;Jo, Sang-Jin;Bu, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.322-322
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    • 2010
  • Recently, anti-reflective films (AR) are one of the most studied parts of a solar cell since these films improve the efficiency of photovoltaic devices. Also, anti-reflection films on the textured silicon solar cells reduce the amount of reflection of the incident light, which improves the device performance due to light trapping of incident light into the cell. Therefore, we preformed two step processes to get textured Si (100) substrate in this experiment. Pyramid size of textured silicon had approximately $2{\sim}9\;{\mu}m$. A well-textured silicon surface can lower the reflectance to 10%. For more reduced reflection, TiO2 anti-reflection films on the textured silicon were deposited at $600^{\circ}C$ using titanium tetra-isopropoxide (TTIP) as a precursor by metal-organic chemical vapor deposition (MOCVD), and the deposited TiO2 layers were then treated by annealing for 2 h in air at 600 and $1000^{\circ}C$, respectively. In this process, the treated samples by annealing showed anatase and rutile phases, respectively. The thickness of TiO2 films was about $75{\pm}5\;nm$. The reflectance at specific wavelength can be reduced to 3% in optimum layer.

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The Characterization of Crosslinked SPEEK Based Ion Exchange Membranes Prepared by EB Irradiation Method (전자선을 이용해 가교된 SPEEK 기본 물질로 하는 이온 교환막의 특성 분석)

  • Song, Ju-Myung;Shin, Junhwa;Sohn, Joon-Yong;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.151-157
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    • 2011
  • Crosslinked SPEEK/PVDF membrane were prepared by EB radiation method with various contents of PVDF. The prepared membranes were subjected to a comparative study of proton exchange membranes for fuel cell appreciations. The crosslinked SPEEK/PVDF membranes were characterized by using DMA, DSC and SAXS. The DMA data indicate that the ionic modulus values and cluster $T_g$ decrease with increasing PVDF content. Thus, it was suggested that the number of clustering in the crosslinked membranes can be reduced with increasing PVDF content. The DSC results were shown that the degree of crystalline of the membrane increased with increasing PVDF content. The morphology of the crosslinkied membranes was shown that with increasing PVDF content, the number of crystalline domain of the SPEEK/PVDF membranes increased but ionic aggregation of the membranes decreased. The water uptake behavior, ionic exchange capacity (IEC) and proton conductivity were decreased with increasing PVDF content. The overall findings suggest that the crosslinked membranes offer the possibility for improving the performance of PEMFC, provided that the membranes have thermal and hydration stability.

A Study of the Retention Behavior of Proteins in High-Performance Liquid Chromatography(Ⅰ): The Effect of Solvent and Temperature on Retention Behavior of Proteins in Reversed-Phase Chromatography

  • Dai Woon Lee;Byung Yun Cho
    • Bulletin of the Korean Chemical Society
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    • v.14 no.4
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    • pp.510-514
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    • 1993
  • The retention behavior of proteins was investigated by using reversed-phase chromatography (RPC), comparing to the retention behavior of small molecules in RPC. The evaluation was carried out on a SynChropak RP-P($C_{18}$) column with 0.1% aq. TFA-organic solvent modifier such as acetonitrile, isopropanol, and ethanol. The Z value (the number of solvent molecules required to displace the solute from the surface) was a general index for the characterization of protein retention as a function of organic concentration over a range of temperature between 5 and 70$^{\circ}C$. Van't Hoff plots provided the basis for evaluating the enthalpic and entropic changes associated with the interaction between protein and the stationary phase. Z values did not change significantly at the range of temperature showing the consistent ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ values. From these investigation, it was concluded that the retention behavior of proteins in RPC was able to be predicted by the retention parameters applied to small molecules. Furthermore, myoglobin and hemoglobin in RPC as stated above showed a similar retention behavior regardless of their molecular weights.

Development of monocular video deflectometer based on inclination sensors

  • Wang, Shuo;Zhang, Shuiqiang;Li, Xiaodong;Zou, Yu;Zhang, Dongsheng
    • Smart Structures and Systems
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    • v.24 no.5
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    • pp.607-616
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    • 2019
  • The video deflectometer based on digital image correlation is a non-contacting optical measurement method which has become a useful tool for characterization of the vertical deflections of large structures. In this study, a novel imaging model has been established which considers the variations of pitch angles in the full image. The new model allows deflection measurement at a wide working distance with high accuracy. A monocular video deflectometer has been accordingly developed with an inclination sensor, which facilitates dynamic determination of the orientations and rotation of the optical axis of the camera. This layout has advantages over the video deflectometers based on theodolites with respect to convenience. Experiments have been presented to show the accuracy of the new imaging model and the performance of the monocular video deflectometer in outdoor applications. Finally, this equipment has been applied to the measurement of the vertical deflection of Yingwuzhou Yangtze River Bridge in real time at a distance of hundreds of meters. The results show good agreement with the embedded GPS outputs.

Biochemical Characterization of a Putative Calcium Influx Factor as a Diffusible Messenger in Jurkat Cells, Xenopis Oocytes, and Yeast

  • Kim, Hak-Yong
    • Animal cells and systems
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    • v.7 no.1
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    • pp.75-79
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    • 2003
  • Highly purified high performance thin layer chromatography (HPTLC) fractions containing a putative calcium influx factor (CIF) were prepared from the Jurkat cells and Xenopus oocytes in which $Ca^{2+}$ stores were depleted by thapsigargin treatment and from the yeast in which intracellular $Ca^{2+}$ stores were also depleted by genetic means. Microinjection of the fractions has been shown to elicit $Ca^{2+}$ dependent currents in Xenopus oocytes. The nature of the membrane currents evoked by the putative CIF appeared to be carried by chloride ions since the current was blocked by the selective chloride channel blocker 1 mM niflumic acid and its reversal potential was about -24 mV. Injection of the calcium chelator 1,2-bis(2-aminophenoxy)ethane-N, N, N',N'-tetraacetic acid (BAPTA) eradicated the current activities, suggesting the current responses are entirely $Ca^2$-dependent. Moreover, the currents were sensitive to the removal of extracellular calcium, indicating the dependence on calcium entry through the plasma membrane calcium entry channels. CIF activities were insensitive to protease, heat, and acid treatments and to Dische-reaction whereas the activities were sensitive to nucleotide pyrophosphatase and hydrazynolysis. The fraction might have a sugar because it was sensitive to Molisch test and Seliwaniff's resorcinol reaction. From the above results, CIF as a small and stable molecule seems to have pyrimidine, pyrophosphate, and a sugar moiety.oiety.

SHIELDED LASER ABLATION ICP-MS SYSTEM FOR THE CHARACTERIZATION OF HIGH BURNUP FUEL

  • Ha, Yeong-Keong;Han, Sun-Ho;Kim, Hyun-Gyum;Kim, Won-Ho;Jee, Kwang-Yong
    • Nuclear Engineering and Technology
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    • v.40 no.4
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    • pp.311-318
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    • 2008
  • In modem power reactors, nuclear fuels have recently reached 55,000 MWd/MtU from the initial average burnup of 35,000 MWd/MtU to reduce the fuel cycle cost and waste volume. At such high burnups, a fuel pellet produces fission products proportional to the burnup and creates a typical high burnup structure around the periphery region of the pellet, producing the so called 'rim effect'. This rim region of a highly burnt fuel is known to be ca. $200\;{\mu}m$ in width and is known to affect the fuel integrity. To characterize the local burnup in the rim region, solid sampling in the micro meter region by laser ablation is needed so that the distribution of isotopes can be determined by ICP-MS. For this procedure, special radiation shielding is required for personnel safety. In this study, we installed a radiation shielded laser ablation ICP-MS system, and a performance test of the developed system was conducted to evaluate the safe operation of instruments.

Charge Transport Characterization of PbS Quantum Dot Solids for High Efficiency Solar Cells

  • Jeong, Young Jin;Jang, Jihoon;Song, Jung Hoon;Choi, Hyekyoung;Jeong, Sohee;Baik, Seung Jae
    • Journal of the Optical Society of Korea
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    • v.19 no.3
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    • pp.272-276
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    • 2015
  • The PbS quantum dot is an emerging photovoltaic material, which may provide high efficiency breakthroughs. The most crucial element for the high efficiency solar cells's development is to understand charge transport characteristics of PbS quantum dot solids, which are also important in planning strategic research. We have investigated charge transport characteristics of PbS quantum dot solids thin films using space charge limited conduction analysis and assessed thickness dependent photovoltaic performances. The extracted carrier drift mobility was $low-10^{-2}cm^2/Vs$ with the estimated diffusion length about 50 nm. These and recently reported values were compared with those from a commercial photovoltaic material, and we present an essential element in further development of PbS quantum dot solids materials.

Preparation and Characterization of Poly(vinyl alcohol)/bentonite Nanocomposites Films with Modified Bentonites (개질된 벤토나이트가 혼입된 폴리비닐알코올/벤토나이트 나노복합 필름의 제조 및 특성분석)

  • Ji, Byung Chul;Yang, Seong Baek;Lee, Jungeon;Park, Jae Min;Han, Myung-Dong;Kim, Ui Ju;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.161-167
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    • 2021
  • Polymer nanocomposite is considered a great alternative to solve the limitations that exist in a simple combination material, as well as to produce multifunctional and high-performance results. In this research, PVA/bentonite nanocomposite films were prepared based on the presence or absence of modification of nano-clay(bentonite) a SUPERGEL® product, modification conditions and content, and the structural variation of the prepared PVA/bentonite nanocomposite films were examined. The effect of variations in the internal structure of the nanocomposite on mechanical and thermal properties was investigated. As a result of evaluating the thermal characteristics of the PVA/bentonite nanocomposite film based on the concentration of the modified bentonite, it was verified that the thermal characteristics and stability were improved because of interaction between the polymer and the modified nano-clay.

Synthesis and Characterization of Nb, Mo-doped and Nb/Mo-codoped Monoclinic VO2 Nanoparticles and Their Thin Films by Hydrothermal/Post-Thermal Transformation and Wet-Coating Method

  • Kim, Jongmin;Jung, Young Hee;Kwak, Jun Young;Kim, Yeong Il
    • Journal of the Korean Chemical Society
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    • v.63 no.2
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    • pp.94-101
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    • 2019
  • Nb, Mo-doped and Nb/Mo-codoped $VO_2(M)$ nanocrystallites with various doping levels were synthesized for the first time by a hydrothermal and post thermal transformation method. The reversible phase transition characteristics of those doped $VO_2(M)$ was comparatively investigated. Nb-doping of $VO_2(M)$ by this method resulted in a very efficient lowering of the transition temperature ($T_c$) with a rate of $-16.7^{\circ}C/at.%$ that is comparable to W-doping, while Mo-doping did not give a serious reduction of $T_c$ with only a rate of $-5.1^{\circ}C/at.%$. Nb/Mo-codoping gave a similar result to Nb-doping without a noticeable difference. The thin films of Nb-doped and Nb/Mo-codoped $VO_2(M)$ with a thickness of ca. 120 nm were prepared by a wet-coating of the nanoparticle-dispersed solutions. Those films showed a good thermochromic modulation of near infrared radiation with 30-35% for Nb-doped $VO_2(M)$ and 37-40% for Nb/Mo-codoped ones. Nb/Mo-codoped $VO_2(M)$ film showed slightly enhanced thermochromic performance compared with Nb-doped $VO_2(M)$ film.

Development of Portable Measurement Unit with Wireless Transmission by Wireless LAN for Long-term Monitoring (장기간 소자 모니터링이 용이한 소형 무선랜 무선송신 계측장치 개발)

  • Park, So Jeong;Park, Il-Hoo;Moon, Young-Sun;Lee, Kook Jin;Kim, Gyu-Tae
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.1
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    • pp.45-49
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    • 2018
  • Portable microcontroller based measurement unit is demonstrated using digital-to-analog convertor module, analog-to-digital convertor module and additional preamplifier circuit with low-budget but excellent performances. Using the designed measurement unit, the measurement of current below 1 nA with applying voltage up to 5 V is successfully carried out. With the WiFi module in microcontroller, measured data is transferred to the user's computer. To evaluate the performance of the measurement unit, the transfer curve of a commercial N-type field effect transistor was measured with the measurement unit and the results is well consistent with that measured using commercial characterization system.