• Korean Chemical Engineering Research
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• v.54 no.3
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• pp.387-393
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• 2016

Fluorinated polyurethane coating solutions were synthesized from perfluoroalkyl alcohol, toluene diisocyanate, and polycarbonate diol as starting materials. Next, coating films were prepared by spin-coating the fluorinated polyurethane coating solutions on the PC substrates, followed by thermal curing at $120^{\circ}C$. The obtained fluorinated polyurethane coating films were characterized by FT-IR spectroscopy, UV-Vis spectrometer, contact angle tester and pencil hardness tester. Contact angle measurements of water on the coating films showed that the addition of perfluoroalkyl alcohol improved the water repellency and increased the contact angle from $81^{\circ}C$ to $111^{\circ}C$. However, the pencil hardness of coating films exhibited a constant grade of H, irrespective of the addition of perfluoroalkyl alcohol.

• Korean Chemical Engineering Research
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• v.52 no.4
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• pp.451-458
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• 2014

Waterborne polyurethane dispersion (WPUD) was prepared from polycarbonate diol (PCD), isophorone diisocyanate (IPDI) and dimethylol propionic acid (DMPA) as starting materials. Then, waterborne acrylic polyurethane dispersion (AUD) was synthesized by reacting the WPUD with different types of acrylate monomers, such as methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA) and butyl acrylate (BA). Subsequently, the AUD was mixed with multi-walled carbon nanotube (MWCNT) to yield a conductive coating solution, and the mixture was coated on the polycarbonate substrate. The pencil hardness, abrasion resistance and chemical resistance of the coating films from AUD were improved than those from WPUD, while the electrical conductivity of the coating films from AUD was decreased than that of WPUD. Also, the effect of acrylate types on the properties of coating films was investigated. The AUD obtained from HEMA showed the strongest pencil hardness, while the AUD obtained from MMA exhibited the strongest abrasion resistance, chemical resistance and electrical conductivity among several types of acrylate monomers.

• Polymer(Korea)
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• v.31 no.6
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• pp.485-490
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• 2007

Hard coating was made on a polycarbonate plate using a sol-gel process with a melamine derivative and silicates, and examined as potential substitutes for automobile glass. Methylated poly(melamine-co-formaldehyde), tetraethoxysilane, and phenyltriethoxysilane were used to form a coating solution. The coatings on the polycarbonate plate were deposited using a sol-gel process. Poly(methyl methacrylate) was coated on the surface of polycarbonate in order to improve adhesion property. The optimum conditions and formulation to obtain excellent physical properties of the coating were determined. Adding the melamine derivative to the coating solution, the pencil hardness of the coating was improved. The hardness of a 3H class pencil, excellent abrasion resistance, and surface uniformity were found in the coated polycarbonate surface.

• Spatial Information Research
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• v.14 no.4 s.39
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• pp.433-449
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• 2006

Two primary objectives of this study were to determine important personal factors in performing cognitive distance mapping, and to understand how human's cognitive distance mapping capabilities were influenced by reference and subjects' locations using Global Positioning System (GPS). Undergraduate and graduate students at the University of Kansas, USA were interviewed and surveyed throughout the campus area giving them a paper-and-pencil test. Study results showed that females had more accurate cognitive mapping capability than males regardless of ethnic background and academic levels. Generally, subjects with longer affiliation with the university, higher ages and academic levels had less variability in their mapping accuracy. Subjects tended to more accurately map the target locations closer to the reference points than those located farther away, and subjects who were closer to a reference point performed their distance mapping better than those farther away. A correlation analysis reported that male subjects used reference-to-target and subject-to-reference distances more sensitively than females to estimate the locations of the targets. This result indicates that males might have used the reference point-based map scale more strenuously than females.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.274-278
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• 2008

Hard coating solutions were prepared from glycidoxypropyl trimethoxysilane (GPTMS) and methacryloxypropyl trimethoxysilane (MPTMS) precursors with different molar ratios of 10:0, 9:1, 7:3, 5:5, 3:7, and 0:10, respectively, by the sol-gel method. The polycarbonate (PC) sheets were spin-coated, and cured at $130^{\circ}C$ for 3 h. The effect of the GPTMS:MPTMS molar ratios of the mixture was investigated on the properties of coating films. The highest pencil hardness and adhesion to PC sheets of coating films were found for solution with GPTMS:MPTMS molar ratio of 5:5. Also, the pencil hardness of coating films was increased with increasing the $H_2O$ content in the coating solutions.

• Korean Chemical Engineering Research
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• v.54 no.6
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• pp.767-774
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• 2016

Three different alumina sols were prepared by hydrolyzing aluminum isopropoxide as a starting material in methanol solvent, followed by peptizing with acetic acid, nitric acid or hydrochloric acid as a peptizing agent by the Sol-Gel Method. Also, coating solutions were obtained by adding a silane coupling agent, (3-glycidyloxypropyl) trimethoxysilane to the alumina sols, deposited on polycarbonate substrates by dip-coating and densified by thermal curing. The effect of types of peptizing agents was studied on the properties of coating films. As a result, coating films, prepared with hydrochloric acid or nitric acid as a peptizing agent, showed excellent properties of pencil hardness of H or 2H and adhesion of 5B. On the other hand, coating films, prepared with acetic acid as a peptizing agent, exhibited poor properties of pencil hardness of HB and adhesion of 3B.

• Korean Chemical Engineering Research
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• v.52 no.3
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• pp.388-394
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• 2014

Inorganic-organic hybrid coating solutions were synthesized using titania sol from titanium isopropoxide (TTIP) as an inorganic component and mixture of two or three types of silane coupling agents, such as methacryloxypropyl trimethoxysilane (MPTMS), aminopropyl triethoxysilane (APS), glycidoxypropyl trimethoxysilane (GPTMS) and vinyltriethoxysilane (VTES) as an organic component. The hard coating films were obtained by spin-coating on the polycarbonate sheets and curing the inorganic-organic hybrid coating solutions. The coating films made from the mixture of two types of silane coupling agents showed poor pencil hardness and adhesion, while those from the mixture of three types of silane coupling agents exhibited an improved pencil hardness of 2H~4H and adhesion of 5B. The refractive indexes of coating films were increased from 1.56 to 1.63 at 550 nm by increasing the content of titania sols from 20 to 30 g.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.73-79
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• 2013

Waterborne polyurethane dispersion (WPUD) was synthesized from polycarbonate diol (PCD), isophorone diisocyanate (IPDI) and dimethylol propionic acid (DMPA) as starting materials. Then, waterborne acrylic polyurethane dispersion (AUD) was synthesized by reacting the WPUD with an acrylate monomer, methyl methacrylate (MMA). Subsequently, the AUD was mixed with multi-walled carbon nanotube (MWCNT) to yield a conductive coating solution, and the mixture was coated on the polycarbonate substrate. With increasing the amount of MMA in the AUD, the pencil hardness, abrasion resistance and chemical resistance of the coating films were improved, but the electrical conductivity of the coating films was decreased. On the other hand, the pencil hardness, abrasion resistance and chemical resistance of coating films were decreased, but the electrical conductivity was enhanced with increasing the amount of MWCNT in the conductive coating solutions.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.27 no.8
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• pp.766-773
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• 2016

This paper proposes an aircraft-installed compact offset-parabolic-reflector antenna for the spinning direction-finding applications. The feeder of the reflector antenna is a LPDA antenna that has the ultra-wideband characteristics and the $45^{\circ}$ slant linear polarization. The reflector is designed to be slanted by $5^{\circ}$ in the elevation and to be small in size on the basis of the reference parabolic shape for the purpose of the high gain and mounting on the underside of aircraft fuselage. Over the ultra-wideband 20:1 bandwidth from S to Ka band, the measured average gain of the proposed antenna is 27.97 dBi, and the average half-power beam width is $4.55^{\circ}$ in the azimuth and $4.3^{\circ}$ in the elevation which is the pencil-beam radiation pattern. All the measured data are similar to the simulation results. The designed compact offset-parabolic-reflector antenna that is installed in the limited area has the ultra-wideband and high-gain characteristics. We expect that the newly designed antenna can be applied to the spinning direction-finding antenna system installed in an aircraft.

• Education of Primary School Mathematics
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• v.1 no.2
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• pp.85-95
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• 1997

Recently, by the popularization of computers and the development of many kinds of information transmission software, the living pattern in business offices and in home-life have changed rapidly. Because of the great progression of today's science technology, the influence of social education on the children is larger than that of the traditional school.. By a rapid change in the social atmosphere, there are some people who insist the traditional school education system is of no use any more. There have been many calls for reform of traditional schooling and in particular there has been major rethinking of school mathematics. The initial demand for change in elementary school mathematics is because of the poor achievement of students. There are even more compelling reasons for change. For example today's science technology society requires a different mathematical literacy for its citizens than that of the past. The importance of problem-solving based on interest and progress is more important than just paper-pencil computation in elementary schools. And also the increasing information wave of today's society demands that the school accept the long-distance education which could not be imagined in the past. Taking account of this variety, school education in the future should willingly introduce and apply the open education system to keep pace with today's society. To accept society demands actively, today's schools are going to accept and apply the idea of the open education. In this viewpoint, the purpose of the paper is to analyze the causes of under-achievement in mathematics teaming, the directions of school mathematics education, the system of textbooks and the problems of teaching-learning programs and paper-pencil test.