• Title/Summary/Keyword: pellet binder

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Investigation of Selective $CO_2$ Adsorption performance in Landfill Gas with pre-treated Zeolite 13X (매립지 가스 중 $CO_2$$CH_4$ 분리를 위한 흡착제 제조 공정 연구)

  • Yoon, Sang-Phil;Jung, Dong-Ha;Jeon, Young-Shin;Kim, Hyung-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.172.1-172.1
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    • 2011
  • 본 연구에서는 매립지에서 발생하는 주요한 가스인 $CO_2$(47~55%)와 $CH_4$(47~55%)가스를 분리하기 위하여 여러 $CO_2$ capture 방법 중 Zeolite를 사용한 흡착법을 이용하였다. 국내에서 시판되고 있는 powder형 Zeolite 13X에 Inorganic binder와 organic binder를 최적의 비율로 혼합한 후 증류수를 이용하여 Pellet type 흡착제를 제조하였다. 또한 최종적으로 $CO_2$의 흡착능을 높이기 위하여 양이온(1M의 KCl, NaCl, $CaCl_2$, $LiCl_2$)으로 이온교환을 하였다. 매립지 모사가스($CO_2$:40%, $CH_4$:60%)를 이용하여 실시간 분석기(Delta1600S)를 이용 두 가스의 분리와 $CO_2$ 흡착성능(mg-CO2/g-흡착제)을 확인하였다. 개발된 흡착제(AjouEpl 13X)는 ICP, XRD, XRF, BET 분석으로 제올라이트의 구조와 성분을 분석하였다.

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Effects of a Practical Korean Rockfish (Sebastes schlegeli) Diet ; Comparison with Raw Fish and Moist Pellet Diet (조피볼락의 배합사료 개발을 위한 대조사료 효과; 생사료 및 moist pellet과의 비교)

  • Lee Jong-Yun;Lee Sang-Min;Jeon Im-Gi
    • Journal of Aquaculture
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    • v.8 no.4
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    • pp.261-269
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    • 1995
  • A practical control diet was prepared and compared with raw fish ($80\%$ frozen horse mackerel + $20\%$ commercial binder meal) and moist pellet ($50\%$ frozen horse mackerel + $50\%$commercial binder meal) diets to develop a practical diet formulation for Korean rockfish (Sebastes schlegeli). Korean rockfish averaging 68.5g were fed with the three experimental diets for 11 months. Final average body weight was approximately 330g and showed no significant difference between fish groups (P>0.05). Feed efficiency of fish from control diet was significantly lower than those of fish from raw fish and moist pellet diets (P<0.05). Protein and lipid retention efficiency of fish ranged $26.9-28.8\%$ and $86.5-110.2\%$, respectively, without any significant difference between the different diets. At the end of the experiment, chemical composition for the various parts of fish body and flesh quality of the raw fish were examined. The data showed that there was no significant difference between fish from the different diet groups for moisture, protein and lipid contents of whole body, liver, and dorsal muscle. Also, thirty three panelists did not find any difference in color, smell, texture, and taste of the raw fish flesh. These results suggest that Korean rockfish can be cultured with a laboratory practical feed without any negative effects on growth, nutrient utilization, chemical composition of fish, and quality of raw fish. Therefore, the next step in developing practical feed is to modify the control diet for improving fish performance and reducing feed cost.

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Growth of the Juvenile 01ive Flounder (Paralichthys olivaceus) Fed the Diets at Different Feeding Frequencies (사료 공급 횟수가 넙치 치어의 성장에 미치는 영향)

  • LEE Sang-Min;SEO Chong-Hyun;CHO Young-Sik
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.1
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    • pp.18-21
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    • 1999
  • A feeding experiment was conducted to determine the effects of feeding frequency on growth and body composition in juvenile olive flounder (Paralichthys olivaceus). Triplicate groups of the 40 fish averaging 1.6 g were fed the 2 different commercial diets (D-1 and D-2) and moist pellet (MP) contained frozen horse mackerel and commercial binder meal at different feeding frequencies of 4 times daily, 3 times daily, 2 times daily, once a day or once in 2 days. Growth and feed intake of fish were affected by diets and feeding frequencies (P<0.05). Feed intake ($\%$ of body wt.) in the all diet groups was significantly decreased according to feeding frequency decreased (P<0.05). Weight gain of fish fed the each diet were increased according to feeding frequency increased, although no significant differences were observed between 3 times and 4 times daily (P>0,05). If the same feeding frequency, feed intake and growth of fish fed the moist pellet were lower (P<0.05) than those of commercial diets (D-1 or D-2), probably due to the relatively high moisture content or unbalanced nutrients. Whole body lipid content of fish fed the each diet at once in 2 days was the lowest among feeding frequencies. These results indicate that 3 times daily feeding regimen may be more effective than that of 4 times daily and moist pellet in this study will not be used as a practical type of diet for juvenile olive flounder weighing between 1,6 g and 4 g.

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Commercial Scale Evaluation of Practical Extruded Pellet Feed for the Olive Flounder (Paralichthys olivaceus) (넙치 실용배합사료개발을 위한 현장적용시험)

  • Kim Kang-Woong;Kang Yong-Jin;Lee Hae-Young;Kim Kyoung-Duck;Choi Se-Min;C. Bai Sung-Chul;Park Hung-Sik
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.2
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    • pp.100-105
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    • 2006
  • This study was conducted to evaluate the effects of extruded pellet (EP) diets, as compared to a raw fish moist pellet (MP) diet for olive flounder, Paralichthys olivaceus, grown in commercial-scale aquaculture for 1 year. Four diets with duplication per diet were formulated for this experiment: two experimental EP diets (EP1 and EP2), one commercial EP diet (CEP), and a raw fish MP diet (MP). The MP diet consisted of 80% frozen horse mackerel and 20% commercial binder meal. Fish weighing $30.1{\pm}0.1 g$ ($mean{\pm}SD$) were distributed randomly to each aquarium as a group of 2,600 fish. Weight gain (WG) and feed efficiency ratio (FER) of fish fed EP2 and MP were higher (P<0.05) than those of fish fed CEP, while those of fish fed EP1 did not differ (P>0.05) from those fed EP2 and MP. However, fish fed the MP diet had a higher survival rate than fish fed the other diets. Fish fed EP2 had higher serum, phospholipids and total protein levels, and lower levels of serum glutamic-oxaloacetic transaminase (GOT), glutamic-pyruvic transaminase (GPT), and total cholesterol than fish fed MP (P<0.05). Dorsal muscle and liver proteins and lipid of fish fed EP1 were higher (P<0.05) than those of fish fed CEP, while those of fish fed EP1 and MP did not differ from those of fish fed EP2 (P>0.05). These results strongly suggest that EP1 could be developed to replace MP for grow-out stage production of olive flounder without adverse effects on growth performance.

Decomposition of Eco-friendly Liquid Propellants over Platinum/Hexaaluminate Pellet Catalysts (백금/헥사알루미네이트 펠렛 촉매를 이용한 친환경 액체 추진제 분해)

  • Jo, Hyeonmin;You, Dalsan;Kim, Munjeong;Woo, Jaegyu;Jung, Kyeong Youl;Jo, Young Min;Jeon, Jong-Ki
    • Clean Technology
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    • v.24 no.4
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    • pp.371-379
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    • 2018
  • The objective of this study is to develop a platinum/hexaaluminate pellet catalyst for the decomposition of eco-friendly liquid propellant. Pellet catalysts using hexaaluminate prepared by ultrasonic spray pyrolysis as a support and platinum as an active metal were prepared by two methods. In the case of the pellet catalyst formed by loading the platinum precursor onto the hexaaluminate powder and then adding the binder (M1 method catalyst), the mesopores were well developed in the catalyst after calcination at $550^{\circ}C$. However, when this catalyst was calcined at $1,200^{\circ}C$, the mesopores almost collapsed and only a few macropores existed. On the other hand, in the case of a catalyst in which platinum was supported on pellets after the pellet was produced by extrusion of hexaaluminate (M2 method catalyst), the surface area and the mesopores were well maintained even after calcination at $1,200^{\circ}C$. Also, the catalyst prepared by the M2 method showed better heat resistance in terms of platinum dispersion. The effects of preparation method and calcination temperature of Pt/hexaaluminate pellet catalysts on the decomposition of liquid propellant composed mainly of ammonium dinitramide (ADN) or hydroxyl ammonium nitrate (HAN) were investigated. It was confirmed that the decomposition onset temperature during the decomposition of ADN- or HAN- based liquid propellant could be reduced significantly by using Pt/hexaaluminate pellet catalysts. Especially, in the case of the catalyst prepared by the M2 method, the decomposition onset temperature did not show a large change even when the calcination temperature was raised at $1,200^{\circ}C$. Therefore, it was confirmed that Pt/ hexaaluminate pellet catalyst prepared by M2 method has heat resistance and potential as a catalyst for the decomposition of the eco-friendly liquid propellants.

Evaluation of Experimental Formulated Diets and Commercial Diets for Growing Korean Rockfish (Sebastes schlegeli) (조피볼락 육석용 배합사료와 시판사료의 사육효과 비교)

  • Lee Sang-Min;Jeon Im-Gi
    • Journal of Aquaculture
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    • v.9 no.4
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    • pp.377-384
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    • 1996
  • A 15-week of growth trial was conducted to evaluate practical diets for growing Korean rockfish (Sebastes schlegeli). Two replicate groups of the fish average weighing 125 g were fed one of four experimental diets containing $41\~45\%$ protein and $6\~8\%$ lipid. A control diet with $58\%$ fish meal as protein source was included and practical form diets with $40\%$ fish meal and various practical ingredients such as meat meal, blood meal, soybean meal, and corn gluten meal were included. These experimental dry pellet diets were compared with commercial diets containing $51\~53\%$ protein and $5\~13\%$ lipid for marine fish or raw fish-based moist pellet (RMP) diet containing $58\%$ protein and $9\%$ lipid consisted of $50\%$ frozen horse mackerel and $50\%$ commercial binder meal. Weight gain, feed efficiency, daily feed intake and protein efficiency ratio in the fish fed the experimental diets and commercial diets were not significantly different to those in the fish fed the control diet. However weight gain, feed efficiency and protein efficiency ratio in the fish fed the RMP diet were significantly higher than those in the fish fed the experimental diets and commercial diets. These differences of growth performance between experimental diets and RMP diet may be reason for different dietary protein and energy levels. The experimental diet can save up to $20\%$ cost of fish production compare with control diet, whereas RMP diet is more expensive than other diets in the fish production.

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Germination and Physical Characteristics of Pelleted Sesame Seed with Different Materials (참깨종자의 과위화 재료에 따른 발아 및 물리적 특성)

  • 오명규;김종태;유숙종;고종철;박문수;이중용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.5
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    • pp.497-502
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    • 1997
  • A seed pelleting technique was developed for easy handling of small sesame seeds (Chinbaeckkae) and for direct seeding in field. The mixture of pelleting material, binder(sodium alginate) and seeds were dropped in 100mM CaCl$_2$ solution. Charcoal was appeared as a best material among all to make pellets with the characters of hardness, breakdown, destruction rate and germination percentage. Zeolite formed the hardest pellet seeds among the materials and 1~3 seeds contained in a pellet on the treatment of 87g of sesame seeds mixed in 1$\ell$ CaCl$_2$ solution was estimated optimum rate of seed mixure with few appearance of seedless pellet. The moisture absorption rate was greater in the order of peat+charcoal > peat > charcoal > zeolite. Germination percentage of pelleted seeds with charcoal was the best and similar to that of common non-treated seeds. Germination percentage of pelleted seeds by sowing depth of exposing a quarter of pellet seeds on the surface of vermiculite germination test box and were 92% in charcoal treatment and was the best among all released materials.

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Synthesis of $CaCrO_4$Powders for the Cathode Material of Thermal Battery by GNP and Electrochemical Properties of Ca/LiCl-KCl/$CaCrO_4$Thermal Battery System (GNP 방법에 의한 Thermal Battery용 양극 재료 $CaCrO_4$분말 합성 및 Ca/LiCl-KCl/$CaCrO_4$전지계의 전기 화학적인 특성 평가)

  • 이현주;김영석;김선재;이창규;김홍회;김길무
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.143-151
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    • 2001
  • Ca/LiCl-KCl/CaCrO$_4$열 전지계의 양극재료로서 BCT(Body-Centered Tetragonal) 결정구조를 갖는 CaCrO$_4$분말을 GNP로 합성하고, SEM, TEM, XRD를 이용하여 그 미세구조를 분석하였다. GNP 공정에 의한 CaCrO$_4$분말은 단일상으로 0.5$mu extrm{m}$ 이하의 입자 크기를 가지며 균일하게 분포한 반면, 기존의 분말 혼합법은 높은 하수 온도 및 장시간의 하소 조건을 필요하므로 미세한 분말 합성이 어렵고 pellet 형태로 만들었을 때 GNP 분말에 비해 비표면적이 현저하게 작기 때문에 전극 재료로써 유리하지 못하다. Ca/LiCl-KCl/CaCrO$_4$계의 전기 화학적인 특성을 평가해본 결과 전지셀을 Ca/DEB(LiCl-KCl+CaCrO$_4$+SiO$_2$)와 같은 DEB 형태로 만들었을 때 $600^{\circ}C$의 온도에서 2.0 V이상 (<100 mA/㎤)의 안정한 전압이 5분 이상 유지되었다. 그러나 3층 전극 셀(Ca/LiCl/KCl/ CaCrO$_4$)에서는 동일한 온도에서 2.0 V이상 (<100 mA/㎤)의 전압이 7분 이상 유지되었으나 불안정한 전압 변동 및 낮은 peak voltage로 인해 DEB 셀의 전지 특성이 더 우수한 것으로 생각된다. 양극 재료의 제조 방법의 관점에서 볼 때, 동일한 DEB(Depolarizer : Electrolyte : Binder=25 : 70 : 5 wt%) 조성의 셀 구성시, GNP 분말은 분말 혼합법에 의한 분말보다 반응 표면적이 훨씬 크기 때문에 GNP 양극 활 물질의 DEB 셀에서의 전지 수명이 더 길었다.

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Preparation of Pelletized Porous Adsorbent with Pyrolysis Temperature and Its Toluene Gas Adsorption Characteristics (열분해 조건에 따른 펠렛형 다공성 흡착재의 제조 및 톨루엔 가스 흡착 특성)

  • Kim, Do Young;Kim, Yesol;Cho, Seho;Jung, Jin-Young;Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.587-592
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    • 2013
  • In this study, we prepared pelletized porous carbon adsorbent (PCA) according to the different pyrolysis temperature using activated carbon and polyvinyl alcohol (PVA) as a binder for the removal of toluene, which is one of the representative volatile organic compounds (VOCs). We investigated physical characteristics of PCA using FE-SEM, BET, TGA and evaluated their adsorption capacity for toluene using GC. It was confirmed that the formability of pellets composed of the activated carbon, PVA and solvent of mass mixing ratio was 1 : 0.2 : 0.8 was the most outstanding. Toluene adsorption capacity was evaluated by measuring the maximum time when more than 99% of toluene adsorbed on the pellet. The specific surface area of the adsorbent pyrolyzed at $300^{\circ}C$ was measured as 4.7 times in $941.9m^2/g$ compared to that of the unpyrolyzed pellet. Micropore volume and toluene adsorption capacity of PCA increased fivefold to be 0.30 cc/g and thirteenfold to be 26 hours compared to that of the unpyrolyzed pellet, respectively. These results were attributed to the change of pore size and specific surface area due to the PVA content and the different pyrolysis temperature.

Effect of different binders on cold-bonded artificial lightweight aggregate properties

  • Vali, Kolimi Shaiksha;Murugan, S. Bala
    • Advances in concrete construction
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    • v.9 no.2
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    • pp.183-193
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    • 2020
  • The present investigation is to identify an optimum mix combination amongst 28 different types of artificial lightweight aggregates by pelletization method with aggregate properties. Artificial aggregates with different combinations were manufactured from fly ash, cement, hydrated lime, ground granulated blast furnace slag (GGBFS), silica fume, metakaolin, sodium bentonite and calcium bentonite, at a standard 17 minutes pelletization time, with 28% of water content on a weight basis. Further, the artificial aggregates were air-dried for 24 hours, followed by hardening through the cold-bonding (water curing) process for 28 days and then testing with different physical and mechanical properties. The results found the lowest impact strength value of 16.5% with a cement-hydrated lime (FCH) mix combination. Moreover, the lowest water absorption of 16.5% and highest individual pellet crushing strength of 36.7 MPa for 12 mm aggregate with a hydrated lime-GGBFS (FHG) mix combination. The results, attained from different binder materials, could be helpful for manufacturing high strength artificial aggregates.