• Journal of the Korean Society of Clothing and Textiles
• /
• 제35권10호
• /
• pp.1242-1251
• /
• 2011

This study investigates the effect of mixed characteristics of oily soil such as mixed ratio, polarity of oily soil on contact angle of fabric, removal of oily and particulate soil from PET fabric in oily/particulate soil mixed system. The contact angle of fabric in the surfactant solution with suspended oily soil was examined as a fundamental environment of detergency of soil from fabrics. Detergency was investigated as function of mixed ratios of oily/ particulate soil, type of oily soil, surfactants concentration, surfactant type and temperature of detergency in surfactant solution. The contact angle of fabric in surfactant solution sharply increased with mixing nonpolar oily soil; in addition, the contact angle slightly increased with increasing contents of oily soil and decreased with increasing surfactant concentration. The removal of oily and particulate soil from fabric was higher in the solution mixed with polar versus nonpolar oily soil. The detergency increased with increasing surfactant concentration and the increased temperature of surfactants solution that were relatively improved in NPE compared to DBS solutions, The results indicated that the detergency of oily and particulate soil showed a similar trend in oily/ particulate mixed soil systems. The general contact angle of fabric was well related with the detergency of oily and particulate soil in oily/particulate mixed soil system, therefore, the primary factor determining the detergency of soil in oily/particulate mixed soil system may be the contact angle of fabric caused by wettability.

• Journal of the Korean Society of Clothing and Textiles
• /
• 제13권3호
• /
• pp.286-294
• /
• 1989

This Study has treated the effects of fiber, surfactants, temperature, surfactant concentration, pH, electrolyte, fatty acid contents and mechanical force on the removal of particulate soil from fabric, vacuum cleaner dirt was used as model particulate soil. The fabrics were soiled with mixture of vacuum cleaner dirt and fatty soil, and washed in Terg-O-tometer. The detergency was evaluated by measuring reflectance of a fabric before and after washing. The results were as follows. 1. The fiber type showed a different pattern of soil removal with surfactants. In general, particulate soil removal increased in the following order Acetate>PET. Nylon>Cotton. Particulate soil removal, which is affected by the surfactant type, increased in the following order NPE $(EO)_{10}\leqq$Soap>SLS>DBS>Tween 80. 2. The influence of temperature on the particulate soil removal was very complex because efficiency of removal was varied with surfactant and fiber types. The washing efficiency of NPE $(EO)_{10}$ was highest at around $40^{\circ}C\;and\;60^{\circ}C$ with cotton and PET but the washing efficiency of DBS was the highest at $60^{\circ}C$ with cotton, decreased monotonously with increasing temperature with PET 3. The detergency of particulate soil increased with increasing surfactant concentration at relatively low concentration and then levelled off above some optimum concentration. 4. The removal of particulate soil increased with increasing pH and mechanical force. 5. Effect of electrolyte on the particulate soil removal was depended on the concentration of the surfactant. At low concentration of surfactant, addition of electrolytes improved soil removal but above the some concentration no effect was observed. At high concentration of surfactant, Vie., $0.6\%$ , the maximum washing effect is reached without added electrolyte. These result indicate that added electrolyte only influence the adsorption of surfactant on the soil and fiber 6. Fatty acid content in the soil did not influence on particulate soil removal without regard to surfactants.

• Fashion & Textile Research Journal
• /
• 제13권5호
• /
• pp.790-796
• /
• 2011

This study was designed to investigate the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil under various solutions. The detergency of the particulate soil was determined by adhesion of particle to fabric and its removal from fabric separately. The PET fabric and ${\alpha}-Fe_2O_3$were used as materials of textile and model of particulate soil, respectively. The detergency was investigated as a function of surfactants concentration, ionic strength, kinds of electrolyte and mole numbers of oxyethylene ether of nonionic surfactant in different ratio of anionic/nonionic surfactant mixture. Although some deviations exist, the adhesion of particle to fabric generally increased with decreasing its removal from fabric. The detergency of particulate soil on PET fabric was relatively higher in anionic/nonionic surfactant mixed solution than in each single surfactant solution, but the influence of ratio of anionic/nonionic surfactant mixture on detergency of particulate soil was low. Generally the detergency of particulate soil on fabric was at its maximum at 0.1% surfactant concentration, $1{\times}10^{-3}$ ionic strength, $Na_5P_3O_{10}$ electrolytes and 10 mole numbers of oxyethylene ether of nonionic surfactant, regardless of ratio of anionic/nonionic surfactant mixture.

• Journal of the Korean Society of Clothing and Textiles
• /
• 제36권11호
• /
• pp.1237-1245
• /
• 2012

The effect of hydrophilicity and hydrophobicity of PET fabric on the detergency of particulate soil were investigated as functions of the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. The detergency of the particulate soil was determined by the adhesion of particles to and their removal from fabric, the PET fabric and ${\alpha}-Fe_2O_3$ were used as textile materials and for the model of particulate soil, respectively. The hydrophilic and hydrophobic finish for PET fabric was treated with a polyester, silicone and fluorine organic compound of resin respectively. The adhesion of particulate soil to fabric treated with hydrophobic chemicals were slightly higher but its removal from fabric treated with hydrophobic chemicals was largely higher than fabric treated with a hydrophilic chemical regardless of solution conditions such as the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. Therefore, hydrophobic treatment for fabric had a more positive effect than the hydrophilic treatment on the detergency of particulate soil.

• Journal of the Korean Society of Clothing and Textiles
• /
• 제6권2호
• /
• pp.33-40
• /
• 1982

The removal and redeposition of particulate soil occur simultaneously during the washing process. In order to investigate variables which affect on the redeposition of particulate soil, cotton lawn was soiled in the ion oxide black suspension using Launder-O meter. The amount of deposited soil was estimated by means of the spectrometric analysis of iron on the fabric after soiled. The results are as follows: 1. The presence of surfactants b suspension decreased the deposition of particulate soil and the most effective surfactant was soap and the descending order was NaDBS>CTAB>PONPE. 2. The influnce of temperature on soil deposition was considerable, soil deposition was gradually increased with elevating temperature in ionic surfactants solution such as NaDBS and CTAB but that was decreased above $40^{\circ}C$ in nonionic surfactant solution. 3. The tendency of soil deposition was dwindled by adding electrolytes especially in case of polyvalent anions. 4. From the results of the experiments redeposition of particulate soil was related with suspending power of surfactants and was influenced by factors varing zeta potential.

• Journal of the Korean Society of Clothing and Textiles
• /
• 제34권7호
• /
• pp.1175-1183
• /
• 2010

This study investigates the effect of polarity of oily soil on adhesion of oily and particulate soil to PET fabric in oily/particulate mixed soil systems. The potential energy of interaction between two particles was examined as a fundamental environment of adhesion of soil to fabrics. The ${\zeta}$-potential of ${\alpha}-Fe_2O_3$ particles was measured by a microelectrophoresis method, and the potential energy of interaction between two particles was calculated by using the Verwey-Overbeek theory. The ${\zeta}$-potential of particle and the potential energy of interaction between two particles was slightly influenced by the polarity and type of oily soil, but increased with the increased anionic surfactant concentration and amount of oily soil. The adhesion of oily soil to fabric increased with the additional amount of polarity of oily soil and decreased surfactant concentration that was relatively high at a temperature of $60^{\circ}C$ surfactants solution. The adhesion of ${\alpha}-Fe_2O_3$ particle to PET fabric decreased with an increased amount and polarity of oily soil and increased surfactant concentration Although some similarity exists, the general trend of the adhesion to fabric by particulate soil differ from oily soil.

• Korean Journal of Soil Science and Fertilizer
• /
• 제42권Spc호
• /
• pp.47-50
• /
• 2009

Nutrient losses, especially nitrogen and phosphorus, in agricultural runoff can contaminate surface and ground water, leading to eutrophication. Thus, erosion control is crucial to minimizing nutrient losses from agricultural land. Assessments of various erosion control practices were carried out under various cropping system, soil management practices, and slope conditions by means of a lysimeter study and under artificial rainfall. Soil and nutrient losses were monitored in a small agricultural field to evaluate the soil conservation practices. Nutrient losses occur in runoff and leachate (dissolved nutrient) and in sediments (particulate nutrient). Dissolved nitrates accounted for the majority (about 90%) of nitrate transport within the soil. Particulate phosphate in sediments represented the majority (60% to 67%) of phosphate transport. Recently, engineering and agronomic erosion-control practices haver been used to reduce erosion problems in fields on slopes. These practices reduced soil loss, runoff, and nutrient loss to 1/6, 1/2,and 1/3 their original levels, respectively. Bioavailable particulate phosphate in sediments represents a variable but longterm source of phosphate for algae. Dissolved nitrate and phosphate are immediately available for algal uptake, so reducing fluxes of these nutrients should also reduce the risk of eutrophication.

• Fashion & Textile Research Journal
• /
• 제7권6호
• /
• pp.680-688
• /
• 2005

This study was carried out to investigate on the removal of oily and particulate soils from silk fabrics. Various kinds of solvents were used on the removal of two kinds of soils treated into the silk fabrics. The removal of oily soil was analyzed by liquid scintillation counting method, and the removal of oil and carbon particulate mixed soils was evaluated by measuring of reflectance on the surface of soiled fabrics with/without drysoap in solvent washing by Terg-o-tometer. The surfaces of fabrics were also observed by SEM before and after washing. The results obtained were as follows : oily soils were removed efficiently by various kinds of solvents regardless of kinds of silk fabrics in short washing time. The removal effect of solvents from the soiled silk fabrics were high in the order of isopropyl alcohol>trichloroethane>monochlorobenzene>ethylether>perchloroethylene. Oil and carbon particulate mixed soils could be efficiently removed by adding of drysoap in solvent washing. The removal of mixed soils were increased drastically with rinsing and increased drysoap. The removal of soils was more efficiently removed from degummed silk fabrics than from the raw silk fabrics.

• Journal of the Korean Society of Clothing and Textiles
• /
• 제25권8호
• /
• pp.1465-1474
• /
• 2001

The dispersion stability of particles and the adsorption of surfactant were examined as a fundamental environment to adhesion of particulate soil to fabric. The adsorption of surfactant on the PEF fabrics decreased with the addition of electrolytes and decreased with increasing the ionic strengths showed similar tendency to PET fabric. And the dispersion force of $\alpha$-Fe$_2$O$_3$particles decreased with the addition of electrolyte. The adhesion of particulate soil to fabric, increased with decreasing the adsorption of surfactant the correlation between the two was high at low ionic strength. The correlation between the adsorption of surfactants on $\alpha$-Fe$_2$O$_3$ particles and the adhesion of particles to fabric was smaller as shown in the correlation between the adsorption of surfactants on fiber substrate and the adhesion of particles on fabric. However, the correlation between the adhesion of particles to fabric and the stability of particle dispersion was relatively more significant.

• Journal of Korean Society for Atmospheric Environment
• /
• 제2권2호
• /
• pp.9-18
• /
• 1986

For identification and apportionment of sources emitting particulate matters in environment, the multi-elemental characterization of size-density fractionated particulate matters was carried out. Eight types of samples were tested; soil, flyash released from burning of bunker-Coil, diesel oil, coal, and soft coal, urban road-way dust, urban dust fall, and airborne particulate matter. The fractions of particulate matters obtained by heavy liquid separation methos with a series of dichloromethane-bromoform were then analyzed using atomic absorption spectrophotometry for Ni, Cr, Cu, An, Fe, Al, and Mg. Each sample showed a different concentration profile as a function of density, and a number of useful conclusions concerning characterization of elemental distribution were obtained. From the density distributions of elements in soil, the maximum value was found for all elements in the density range of 2.2 $\sim 2.9g.cm^{-3}$, including the density of $SiO_2$. However, the distribution of metallic compounds with the density lower than $2.2g.cm^{-3}$ was prevalent in urban roadway dust, urban dust fall, and airborne particulate matter. And the density distribution curves of these urban dusts also have the higher distribution at the density of 2.2 - 2.9g.cm^{-3}$, including the density of wind-blown silica. This tendency generally was prevalent in the natural source elements, such as Al, Fe, Mn, and Mg. The maximum values were found in the density ranges of 1.3 $\sim 2.2g.cm^{-3}$ from the density distribution of elements in oil fired flyash. These distributions of anthropogenic source elements, such as Zn, Ni, Cu, and Cr were higher predominately than those of natural source elements. And the higher distribution was found in the density range of $2.2 \sim 2.9g.cm^{-3}$ from the density distribution of elements in coal and soft-coal fired flyash. These distributions showed similar patterns to soil. But anthropogenic source elements somewhat predominated at the density ranges of $1.3 \sim 2.2g.cm{-3} and 2.9g.cm^{-3}$ to soil. Therefore the higher distribution of anthropogenic source elements in the density ranges of $1.3 \sim 2.2g.cm^{-3} and 2.9g.cm^{-3}$ was considered as anthropogenic origin.