• Title/Summary/Keyword: particulate organic carbon

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Estimation of Transport and Mass balance of Tributyltin in Masan Bay (마산만의 Tributyltin 거동 및 물질수지 산정)

  • Kim Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.5 no.4
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    • pp.48-56
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    • 2002
  • It was peformed to estimate the sensitivity analyses and mass balance for tributyltin in Masan Bay, using the model builded by stella program. The results of the sensitivity analysis for dissolved tributyltin and tributyltin in the particulate organic carbon showed that not only organic carbon partition coefficient but also settling rate is important. In the case of tributyltin in phytoplankton, bioconcentration factor of phytoplankton is most important. The results of the mass balance showed that standing stocks of tributyltin in water, in phytoplankton and in particulate organic carbon are 3.29×10⁴g, 1.16×10²g and 3.17×10³g, respectively. In the case of flux, partition to particulate organic carbon showed most high value, 1.64×10³g/4ay, and next were deposition to sediment, 1.64×10³g/day and transportation to open sea by tide, 1.64×10³g/day.

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Distribution and Inter-annual Variation of Nutrients (N, P, Si) and Organic Carbon (DOC, POC) in the Equatorial Thermocline Ridge, Northeast Pacific (북동태평양 적도 Thermocline Ridge 해역에서 영양염(질소, 인, 규소)과 유기탄소(용존 및 입자)의 분포 특성 및 연간 변화)

  • Son, Ju-Won;Kim, Kyeong-Hong;Kim, Mi-Jin;Son, Seung-Kyu;Chi, Sang-Bum
    • Ocean and Polar Research
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    • v.33 no.1
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    • pp.55-68
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    • 2011
  • The distribution and inter-annual variation of nutrients (N, P, Si) and dissolved/particulate organic carbon were investigated in the equatorial thermocline ridge ($7^{\circ}{\sim}11.5^{\circ}N$, $131.5^{\circ}W$) of the northeast Pacific. From the Oceanic Nino Index and Multivariate ENSO Index provided by NOAA, normal condition was observed in July 2003 and August 2005 on the aspect of global climate/ocean change. However, La Ni$\~{n}$a and El Ni$\~{n}$o episodes occurred in July 2007 and August 2009, respectively. Thermocline ridge in the study area was located at $9^{\circ}N$ in July 2003, $8^{\circ}N$ in August 2005, $10^{\circ}N$ in July 2007, and $10.5^{\circ}N$ in August 2009 under the influence of global climate/ocean change and surface current system (North Equatorial Counter Current and North Equatorial Current) of the northeast Pacific. Maximum depth integrated values (DIV) of nutrients in the upper layer (0~100 m depth range) were shown in July 2007 (mean 21.12 gN/$m^2$, 4.27 gP/$m^2$, 33.72 gSi/$m^2$) and higher variability of DIV in the equatorial thermocline ridge was observed at $10^{\circ}N$ during the study periods. Also, maximum concentration of dissolved organic carbon (DOC) in the upper 50 m depth layer was observed in July 2007 (mean $107.48{\pm}14.58\;{\mu}M$), and particulate organic carbon (POC, mean $9.42{\pm}3.02\;{\mu}M$) was similar to that of DOC. Nutrient concentration in the surface layer increased with effect of upwelling phenomenon in the equatorial thermocline ridge and La Ni$\~{n}$a episode, which had formed in the central Pacific. This process also resulted in the increasing of organic carbon concentration (DOC and POC) in the surface layer. From these results, it is suggested that spatial and temporal variation of chemical and biological factors were generated by physical processes in the equatorial thermocline ridge.

Characteristics of Organic Carbon and Apparent Oxygen Utilization in the NE Pacific KODOS Area (북동태평양 KODOS 해역의 유기탄소 및 겉보기산소량 특성)

  • Son, Ju-Won;Son, Seung-Kyu;Kim, Kyeong-Hong;Kim, Ki-Hyune;Park, Yong-Chul;Kim, Dong-Hwa;Kim, Tae-Ha
    • Ocean and Polar Research
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    • v.27 no.1
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    • pp.1-13
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    • 2005
  • The samples for organic carbon analysis were collected between $5^{\circ}\;and\;17^{\circ}N$ along $131.5^{\circ}W$ in the northeast Pacific KODOS (Korea Deep Ocean Study) area. The mean concentration of total organic carbon (TOC) in the surface mixed layer $({\sim}50 m)$ was $100.13{\pm}2.05{\mu}M-C$, while the mean concentration of TOC in the lower 500m of the water column was $50.19{\pm}4.23{\mu}M-C$. A strong linear regression between TOC and temperature $(r^2=0.70)$ showed that TOC distribution was controlled by physical process. Results from the linear regression between chlorophyll-a and TOC, and between chlorophyll-a and particulate organic carbon (POC), decreasing of dissolved organic carbon (DOC) in the surface layer caused by non-biological photo-oxidation process. Below the surface layer, biological production and consumption occurred. DOC accumulation dominated in the depth range of $30{\sim}50m$ and DOC consumption occurred in the depth range of $50{\sim}200m$. TOC was inversely correlated with apparent oxygen utilization (AOU) and TOC/AOU molar ratios ranged from -0.077 to -0.21. These ratios indicated that TOC oxidation was responsible fur $10.9{\sim}30.1%$ (mean 20.2%) of oxygen consumption in the NE Pacific KODOS area. In the euphotic zone, distributions of dissolved and particulate organic matter were controlled by photo-chemical, chemical, biological and physical processes.

Spatial and Temporal Variations of Satellite-derived 10-year Surface Particulate Organic Carbon (POC) in the East China Sea (동중국해에서 위성에서 추정된 10년 동안의 표층 입자성 유기 탄소의 시/공간적 변화)

  • Son, Young-Baek;Lee, Tae-Hee;Choi, Dong-Lim;Jang, Sung-Tae;Kim, Cheol-Ho;Ahn, Yu-Hwan;Ryu, Joo-Hyung;Kim, Moon-Koo;Jung, Seom-Kyu;Ishizaka, Joji
    • Korean Journal of Remote Sensing
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    • v.26 no.4
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    • pp.421-437
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    • 2010
  • Surface particulate organic carbon (POC) concentration estimated from Maximum Normalized Difference Carbon Index (MNDCI) algorithm using SeaWiFS data is used to determine spatial and temporal variations of the Changjiang Diluted Water (CDW) in the East China Sea. 10-year monthly POC concentrations (1997-2007) show clearly seasonal variations. Inter-annual variation of POC in whole and three different areas separated by standard deviation is not linearly correlated with the Changjiang River discharge that has decreased after 1998. To determine more detailed spatial and temporal POC variations, we used empirical orthogonal function (EOF) analysis in summer (Jun.-Sep.) from 2000 to 2007. First mode is spatially and temporally correlated with the area influenced by the Changjiang River discharge. Second mode is temporally less sensitive with the Changjiang River discharge but spatially correlated with north-south patterns. Relatively higher POC variations during 2000 and 2003 were shown in the southern East China Sea. These patterns during 2004 and 2007 moved to the northern East China Sea. This phenomenon is better related to spatial variations of wind-direction than the amount of Changjiang River discharge, which is verified from in-situ measurement.

Use of Stable Carbon Isotope Ratios (${\delta}^{13}$C) for Identification of the Origin Organic Carbon in Benthic Food Webs in Youngil Bay, Korea

  • Lee, Won-Chan;Choi, Woo-Jeung;Lee, Pil-Yong;Kang, Chang-Keun
    • Journal of the korean society of oceanography
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    • v.35 no.2
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    • pp.124-127
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    • 2000
  • The analysis of stable carbon isotope ratios for benthic fauna was applied to identify the source of carbon in benthic food webs in Youngil Bay, Korea. The ${\delta}^{13}$C values of 9 invertebrate species collected in this area showed a narrow range between -20.5 and -16.3%$_o$ with a mean of-18.1 (${\pm}$1.1)"%$_o$. The results suggest that the major source of organic carbon for the benthic fauna of the lower estuarine reaches and the oceanic sites is autochthonous marine particulate organic matter. The contribution of organic matter from terrestrial and riverine sources to the diet of the benthic fauna in this area appears to be minor, despite the considerable inflow of riverine waters.

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Seasonal characteristics of Elemental and Orgainc Carbon (미세입자 ($PM_{2.5}$) 에 포함된 탄소농도계절 특성)

  • 강병욱
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.2
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    • pp.103-112
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    • 2000
  • Elemental carbon(EC) and organic carbon(OC) in fine particles (PM2.5) were collected from October 1995 through August 1996 in the Chongju area. The annual mean concentrations of EC and OC were 4.44 and 4.99 $\mu\textrm{g}$/m3 respectively. EC showed seasonal variation (p<0.01) The magnitude of the seasonal mean EC concen-tration progresses in the following manner : fall>winter>spring>summer. However OC was not statistically seasonal difference(p=0.20) The annual average OC/EC ratio was 1.12 suggesting that organic carbon measured may by emitted directly in particulate form(primary aerosol) The contribution of EC to PM2.5 mass follows a general pattern in which fall(14.6%) > winter (9.8%) >spring(7.8%) =summer(7.8%) and the contribution of OC to the PM2.5 mass varies in order fall(13.8%) >winter(11.3%) >spring(10.5%) >summer (9.4%) Total carbona-ceous particles(EC and OC) accounted for 17-28% of the PM2.5 mass.

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Organic Matter in the Sediments of Youngsan River Estuary : Distribution and Sources (영산강 하구역 퇴적물의 유기물 분포와 기원)

  • Woo, Jun-Sik;Choi, Heeseon;Lee, Hyo-Jin;Kim, Tae-Ha
    • Journal of Environmental Science International
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    • v.23 no.7
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    • pp.1375-1383
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    • 2014
  • Total organic carbon(TOC), Total nitrogen(TN), and carbon and nitrogen stable isotopes were measured in the sediment and suspended parties in fresh lake water and saline estuarine water to determine the sources of Particulate organic matter(POM) in the sediments of the Youngsan river estuary. POM in the freshwater discharge water was mostly phytoplankton origin with little trace of terrestrial plants. POM from phytoplankton blooms formed in estuarine water in response to the nutrient enriched freshwater discharges was the most important sources of POM in the sediment near the dike, comprising more than 40% of the total organic matter. POM from freshwater phytoplankton and oceanic phytoplankton were also important sources of the sediment POM, and their contributions varied with the distances from the dike. Contribution of freshwater phytoplankton to sediment POM decreased from the dike to the outside of the estuary.

Soil Carbon Dioxide Flux and Organic Carbon in Grassland after Manure and Ammonium Nitrate Application

  • Lee, Do-Kyoung;Doolittle, James J.
    • Korean Journal of Environmental Agriculture
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    • v.24 no.3
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    • pp.238-244
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    • 2005
  • Fertilization effects on changes in soil $CO_2$ flux and organic C in switchgrass (Panicum virgatum L.) land managed for biomass production were investigated. The mean daily soil $CO_2$ flux in the manure treatment was 5.63 g $CO_2-C\;m^{-2}\;d^{-1}$, and this was significantly higher than the mean value of 3.36 g $CO_2-C\;m^{-2}\;d^{-1}$ in the control. The mean daily $CO_2$ fluxes in N and P fertilizer treatments plots were not different when compared to the value in the control plots. Potentially mineralizable C (PMC), soil microbial biomass C (SMBC), and particulate organic C (POC) were highest at the 0 to 10 cm depth of the manure treatment. Potentially mineralizable C had the strongest correlation with SMBC (r = 0.91) and POC (r = 0.84). There was also a strong correlation between SMBC and POC (r = 0.90). Our results indicated that for the N and P levels studied, fertilization had no impact on temporal changes in soil organic C, but manure application had a significant impact on temporal changes in soil $CO_2$ evolution and active C constituents such as PMC, SMBC, and POC.

Particulate Organic Carbon (POC) Algorithms for the southwestern part of the East Sea during spring-summer period using MODIS Aqua (MODIS를 이용한 춘.하계 동해 서남부 해역의 해수 중 입자성 유기탄소 함량 추정 알고리즘 개선)

  • Hong, Gi-Hoon;Ahn, Yu-Hwan;Son, Young-Baek;Ryu, Joo-Hyung;Kim, Chang-Joon;Yang, Dong-Beom;Kim, Young-Il;Chung, Chang-Soo
    • Korean Journal of Remote Sensing
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    • v.27 no.2
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    • pp.107-120
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    • 2011
  • Several MODIS AQUA products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in the surface waters of the East Sea. A total of 30 POC profiles obtained in spring and summer seasons of the years of 2006~2010 were compared with remote sensing reflectance at various wavelengths and diffuse attenuation coefficient at 490 nm observed by MODIS AQUA. The algorithm thus established was $POC=266.85^*[R_{rs}(488)/R_{rs}(555)]^{-1.447}$ ($R^2=0.924$) with root mean square error of 20.9 mg $m^{-3}$. Remotely sensed POC contents derived using our algorithm appeared also not to be affected by the presence of non-POC component in suspended particulate matter. Therefore this algorithm could be applied to obtain POC concentration over the East Sea using MODIS Aqua observation.

Runoff Characteristics of Refractory Organic Matters from Han River Basin during Dry Days (비강우시 한강수계 하천의 연간 난분해성 물질 유출특성)

  • Heo, Sanghoi;Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.19 no.3
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    • pp.353-358
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    • 2017
  • As a drinking water source of 26 millions people of Seoul metropolitan region, Han river is one of the most important basin. Managing the Non-point source pollution which is regarded as the main cause of water pollution including refractory organic matter is important thing. This research investigates the runoff characteristics of organic matters from main 3 rivers (South Han, North Han, Kyungan). Water quality measurement items include not only carbon-based TOC (Total Organic Carbon), DOC (Dissolved Organic Carbon), POC (Particulate Organic Carbon) but also R-TOC (Refractory Total Organic Carbon), R-DOC (Refractory Dissolved Organic Carbon), R-POC (Refractory Particulate Organic Carbon) is researched. The research shows that R-TOC takes approximately 61~83% of TOC. Most of the R-TOC is consist of R-DOC (72~77%). Refractory organic matter have a stable runoff characteristics compared to other organic matter. The organic matter concentrations of South Han river and Kyungan river are the highest in spring time and show a gradual decline. The concentrations of Kyunan river is the highest. Kyungan river's small area and the high city land use ratio seem to be the reason. Loading of organic matter in summer time takes the most loading (62~84%). TOC loadings per unit area of each river is Kyungan river ($1.22ton/km^2$), South Han river ($1.01ton/km^2$), North Han river ($0.91ton/km^2$).