• 제목/요약/키워드: particulate matters

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노후 특수·화물 차량 PM/NOx 저감을 위한 SDPF 촉매 및 코팅 기술 연구 (A Study on Selective Catalytic Reduction on Diesel Particulate Filter Catalyst and Coating Technology the Removal of Particulate Matters and NOx for Old Special Cargo Vehicles)

  • 정관형;서필원;오형석;김종국;강소연;강정호;김현준;신병선
    • 공업화학
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    • 제32권6호
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    • pp.695-699
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    • 2021
  • 본 연구에서는, 노후된 엔진을 사용하는 트럭 및 특수차량에서 배출되는 NOx 및 PM을 동시에 제거하기 위해 SDPF 후처리 시스템 연구를 수행하였다. 우선, SDPF의 SCR 촉매를 선정하기 위해서, V/TiO2와 Cu-zeolite 촉매의 de-NOx 성능을 비교하였으며, SCR 촉매특성분석은 BET, XRD 및 NH3-TPD를 통해 분석하였다. 촉매 활성시험 결과, Cu-zeolite 촉매가 가장 우수한 내열성을 보여주었다. 최적의 SDPF 코팅을 위해서, 목표로 설정된 입자 크기에 맞추어 슬러리를 제조하였다. SCR 코팅량에 따른 SDPF의 코팅안정성과 배압 결과, SDPF 촉매를 로딩량별로 A, B, C 샘플을 제작하여 코팅안정성과 배압 및 de-NOx 성능을 비교한 결과 B 샘플에서에서 가장 우수한 결과를 보였다. 최적 SDPF 후처리시스템에 대해 엔진동력계 시험을 실시하였으며, 시험결과 Eu-5 규제를 만족하였다.

서울시 지하상가 공기중 다환방향족 탄화수소의 농도조사에 관한 연구 (Measurements of Polycyclic Aromatic Hydrocarbons(PAHs) Concentration in Air of the Seoul Underground Shopping Stores)

  • 전준민;김윤신
    • 한국대기환경학회지
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    • 제9권1호
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    • pp.81-92
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    • 1993
  • A purpose of this study was carried out to investigate the concentrations of four elements of PAHs(Polycyclic Aromatic Hydrocarbons) in suspended particulate matters of underground shopping stores in Seoul city. The particulate matters were collected at five underground shopping stores(Yongdungpo, Myongdong, Ulchiro, Express Terminal, Chamshil) in the Seoul area during February-October, 1992. Samples were collected using cascade impactor of low volumn air sampler and were analysed using High Performance Liquid Chromatography(HPLC) with fluorescence detector. Calibration on HPLC analyse is nearly accord with retention time between the standard solution and the samples. Analysed results obtained favorable analysing recovery rate of 97.3% and coefficient of variation of 1.60%. Mean concentrations of suspended particulate matters in five underground shopping stores wre 216.3 g/$m^3$ and observed higher at fine particles(117.2 g/$m^3$) which is respirable particulates than coarse particles(99.2 g/$m^3$). Concentrations of four species PAH were determined with anthracene of 16.8ng/$m^3$, fluoranthene of 72.3ng/$m^3$, benzo(a)pyrene of 0.54ng/$m^3$, and benzo(k)fluoranthene of 0.29ng/$m^3$, respectively. Fluoranthene levels were significantly higher than those levels in other components. PAHs concen-tration at shopping areas showed 21.3ng/$m^3$ in Yongdungpo, 35.1ng/$m^3$ in Myongdong, 23.4ng/$m^3$ in Ulchiro, 11.1ng/$m^3$ in Express Terminal, and 21.4ng/$m^3$ in Chamshil, respectively. Particularly, benzo(a)pyrene and benzo(k)-fluoranthene were detected over 83 percentage in fine particles, while fluoranthene wre highly detected in coarse particles. Also, higher concentrations of benzo(a)pyrene, benzo(k)fluoranthene were found in winter while levels of anthracene and fluoranthene were found higher in summer than other seasons.

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수원지역 분진의 입경별 이온성분 분포특성에 관한 연구 (Characteristics of Ionic Components in Size-resolved Particulate Matters in Suwon Area)

  • 오미석;이태정;김동술
    • 한국대기환경학회지
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    • 제25권1호
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    • pp.46-56
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    • 2009
  • The main purpose of this study was to investigate air quality trends of ambient aerosol with obtaining size-fractionated information. The suspended particulate matters were continuously collected on membrane filters and glass fiber filters by an 8-stage cascade impactor for 2 years (Sep. 2005 $\sim$ Sep. 2007) in Kyung Hee University-Global Campus. 8 ionic species ($Na^+$, ${NH_4}^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were analyzed by an IC after performing proper pretreatments of each sample filter. The average concentration levels of each ion were $9.24{\mu}g/m^3$ of ${SO_4}^{2-}$, $7.35{\mu}g/m^3$ of ${NO_3}^-$, $2.81{\mu}g/m^3$ of ${NH_4}^+$, $2.11{\mu}g/m^3$ of $Ca^{2+}$, $1.65{\mu}g/m^3$ of $Cl^-$, $1.87{\mu}g/m^3$ of $Na^+$, $0.80{\mu}g/m^3$ of $Mg^{2+}$, and $0.54{\mu}g/m^3$ of $K^+$, respectively. The distribution pattern of $Na^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, and ${NO_3}^-$ was bi-modal and two peaks appeared in the range of $0.4{\sim}0.7{\mu}m$ and $3.3{\sim}4.7{\mu}m$, respectively. On the other hand, ${SO_4}^{2-}$, ${NH_4}^+$, and $K^+$ showed patterns of uni-modal distribution, mostly abounded in the fine mode group.

생물성연소에서 발생하는 미세먼지의 장치별 집진 특성: 고기구이를 중심으로 (Collection Characteristics of Particulate Matters from Biomass Burning by Control Devices: Mainly Commercial Meat Cooking)

  • 박성규;최상진;박건진;김진윤;봉춘근;박성진;김종호;황의현
    • 한국대기환경학회지
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    • 제27권6호
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    • pp.641-649
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    • 2011
  • The aim of this study is to understand the characteristics of exhausting particulate matters (PM) and to control emitted PM from meat cooking restaurants. We found that $PM_{2.5}$, $PM_{5.0}$ occupy 69.2% and 98.6% of total PM from pork cooking, respectively. Therefore, we can see that it is not easy to remove PM generated from a pork cooking process. The collection efficiencies of various control devices, which are a condensing scrubber, a cyclone, an impactor, an oil filter and an electrostatic precipitator (ESP), were measured and compared. ESP had the highest collection efficiency (88.6%) and condensing scrubber had the lowest one (68.0%). However, the system recovering property should be considered to choose a control device because PM from meat cooking process are extremely stickiness. Therefore, we can recommend that ESP following an impactor or a cyclone is the best combination to remove PM generated from meat cooking restaurants.

반도체 제조공정 미세먼지-질소산화물 동시 저감을 위한 오존 고속산화공정 최적화 연구 (Optimization of an Ozone-based Advanced Oxidation Process for the Simultaneous Removal of Particulate Matters and Nitrogen Oxides in a Semiconductor Fabrication Process)

  • 엄성현;이승준;고은하;홍기훈;황상연
    • 공업화학
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    • 제32권6호
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    • pp.659-663
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    • 2021
  • 반도체 제조공정에서 발생하는 미세먼지와 질소산화물 동시처리를 위하여 오존산화, 습식중화 및 습식전기집진 기술들을 직접화한 10 CMM급 복합오염물질 제거시스템을 개발하였으며, NOx 제거효율 증대를 위한 공정변수 제어 및 최적화를 진행하였다. 특히, 전원공급장치를 포함한 습식전기집진장치 핵심부품 안정성 평가를 위해 30일 동안의 장기운전도 병행하였다. 오존산화 기반 DeNOx 공정에서 가장 중요한 운전변수인 O3/NO 비율은 1.5 부근에서 최적화하였으며, 습식중화 공정의 운전변수를 최적화하여 중화반응에 의한 제거효율 기여도를 확인하였다.

A Study on the Enhancement of Inventories for Precursors (NOx, SOx) Released from Open Burning of Agricultural Waste Vinyl Causing the Secondary Generation of Particulate Matters

  • Kim, Tae-Han;Choi, Boo-Hun
    • 인간식물환경학회지
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    • 제24권2호
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    • pp.195-207
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    • 2021
  • Background and objective: While response measures to particulate matters in rural areas are limited due to poor inventory record keeping in the agricultural sector, it is necessary to control agricultural waste vinyl and the emission of precursors released from open burning and the secondary generation of particulate matters. Currently, the open burning emission calculation method uses the definition prescribed in CAPSS by the National Institute of Environmental Research. Methods: This study presented an open burning emission calculation formula for agricultural waste vinyl, which is included as agricultural waste. As for activity data, the open burning ratio of agricultural waste vinyl, and the annual incineration volume provided in the Status Survey by the Ministry of Agriculture, Food, and Rural Affairs were applied. The emission factor was generated through incineration tests on three agricultural plastic film samples collected by the Korea Environment Corporation. Results: Among precursors, SOx and NOx were selected and their emission features were monitored with incineration experiment infrastructure based on the EPA 5G method. The highest emission concentration by agricultural waste type was concentrated in the first and second quarters. As for emission factor of SO2, it was calculated at 98.25 g/kg for mulching-use LDPE, 52.31 g/kg for greenhouse-use LDPE, and 14.40 g/kg for HDPE. As for NOx, it was calculated at 18.21 g/kg for mulching-use LDPE, 16.49 g/kg for greenhouse-use LDPE, and 10.67 g/kg for HDPE. Conclusion: This test confirmed the incineration features of PE-based plastics, ascertained the SOx emission factor that had not been included in open burning in the past, and established that low NOx emission concentration is interfered by soil mixed with livestock excretions. The findings from this study are expected to contribute to improving the system for controlling air pollutants in rural environments.